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The Effect of Silver Ion Occupancy on Hollandite Lattice Structure

Published online by Cambridge University Press:  26 February 2018

Alexander B. Brady ,
Jianping Huang ,
Jessica L. Durham ,
Paul F. Smith ,
Jianming Bai ,
Esther S. Takeuchi ,
Amy C. Marschilok  and
Kenneth J. Takeuchi
Alexander B. Brady
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, N.Y, 11794.
Jianping Huang
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794.
Jessica L. Durham
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794.
Paul F. Smith
Affiliation:
Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794.
Jianming Bai
Affiliation:
Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, N.Y., 11973.
Esther S. Takeuchi
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, N.Y, 11794. Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794. Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, N.Y., 11973.
Amy C. Marschilok*
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, N.Y, 11794. Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794. Energy and Photon Sciences Directorate, Brookhaven National Laboratory, Upton, N.Y., 11973.
Kenneth J. Takeuchi*
Affiliation:
Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, N.Y, 11794. Department of Chemistry, Stony Brook University, Stony Brook, N.Y., 11794.
*
*corresponding authors: amy.marschilok@stonybrook.edu, kenneth.takeuchi.1@stonybrook.edu
*corresponding authors: amy.marschilok@stonybrook.edu, kenneth.takeuchi.1@stonybrook.edu
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Abstract

The effect of tunnel cations on tunnel size in α-MnO2 structured (hollandite, cryptomelane) materials has long been of interest, as the tunnel size effects catalytic and transport properties. Previous research on the tunnel size has focused on potassium cryptomelane (KxMn8O16). This paper uses synthetic control of silver content in AgxMn8O16 to investigate the effect that tunnel silver occupancy has on the lattice parameters. Materials with silver (x) content between 1.14 and 1.66 were synthesized, synchrotron diffraction and Rietveld Refinement was used to determine lattice parameters. The lattice parameters were found to contract as silver content increases (from 9.774 Å to 9.738 Å), in contrast to previous investigations of other tunnel cations.

Keywords

AgMnenergy storage
Type
Articles
Information
MRS Advances , Volume 3 , Issue 10: Theory, Characterization and Modeling , 2018 , pp. 547 - 552
Copyright
Copyright © Materials Research Society 2018 

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