Hostname: page-component-54dcc4c588-64p75 Total loading time: 0 Render date: 2025-10-06T14:33:47.921Z Has data issue: false hasContentIssue false
  • English
  • Français

Surface Modification of Nanocrystalline Cellulose toward a TunableOptical Polarizer

Published online by Cambridge University Press:  28 December 2015

Martin Bolduc ,
Michel Poirier ,
Gregory Chauve ,
Hassane Oulachgar ,
Tom Tiwald ,
Pierre Laperle ,
David Gay ,
Patrick Beaupre ,
Myriam Methot  and
Melanie Leclerc
...Show all authors
Martin Bolduc*
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
Michel Poirier
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
Gregory Chauve
Affiliation:
FPInnovation, 570, Blvd Saint-Jean, Pointe-Claire, QC, H9R 3J9 Canada
Hassane Oulachgar
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
Tom Tiwald
Affiliation:
J.A. Woollam Co., Inc., 645 M Street, Lincoln, NE, 68508 USA
Pierre Laperle
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
David Gay
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
Patrick Beaupre
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
Myriam Methot
Affiliation:
FPInnovation, 570, Blvd Saint-Jean, Pointe-Claire, QC, H9R 3J9 Canada
Melanie Leclerc
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
Sebastien Deshaies
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
Martin Briand
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
Jean Bouchard
Affiliation:
FPInnovation, 570, Blvd Saint-Jean, Pointe-Claire, QC, H9R 3J9 Canada
Pierre Galarneau
Affiliation:
INO - Institut National d'Optique, 2740 Einstein, Québec City, QC, G1P 4S4 Canada
*
*(Email: martin.bolduc@ino.ca)
Get access

Abstract

Nanocrystalline cellulose (NCC) solid films obtained from evaporated aqueousheterogeneous mixtures retain the self-assembled chiral nematic order formed inthe suspension. These semi-translucent films are iridescent and reflect ortransmit circularly polarized visible light (400-700nm) due to the chiralproperties of the self-assembled nanostructure. This effect occurs at differentwavelengths depending on the pitch of the helical structure. In this paper, NCCfilms have been fabricated from different recipes to produce various helixpitches. The corresponding red-shift in the optical wavelength has been obtainedby means of Spectrophotometry measurements. Preliminary experiments have beenperformed to investigate optical polarization effects as function of angles ofincidence using ellipsometry. Finally, laser micromachining results on NCC filmsmay suggest feasibility for integration as tunable light polarizercomponents.

Keywords

nanostructureinfrared (IR) spectroscopylaser

Information

Type
Articles
Information
MRS Advances , Volume 1 , Issue 10: Biomaterials and Soft Materials , 2016 , pp. 651 - 657
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

Marchessault, R.H., Morehead, F.F., and Koch, M.J., Colloid Sci. 16, 327 (1961).CrossRefGoogle Scholar
Revol, J.F., Bradford, H. Giasson, J., Marchessault, R.H., and Gray, D.G., Int. J. Biol. Macromol. 14, 170 (1992).Google Scholar
Dong, X.M., Revol, J.F., and Gray, D., Cellulose 5, 19 (1998).CrossRefGoogle Scholar
Marchessault, R.H., Morehead, F.F., and Walter, N.M., Nature 184, 632 (1959).Google Scholar
Beck, S., Bouchard, J., Chauve, G., and Berry, R., Cellulose 20, 1401 (2013).CrossRefGoogle Scholar
Revol, J.F., Godboult, L., and Gray, D.G., J. Pulp. Pap. Sci. 24, 146 (1998).Google Scholar
Beck-Candanedo, S., Roman, M., and Gray, D.G., Biomacromol. 6, 1048 (2005).Google Scholar
Habibi, Y., Lucia, L.A., and Rojas, O.J., Chemical Reviews 110, 3479 (2010).CrossRefGoogle Scholar
Dong, X.M., Kimura, T., Revol, J.F., and Gray, D.G., Langmuir 12, 2076 (1996).Google Scholar
Beck, S., Bouchard, J., and Berry, R., Biomacromolecule 12, 167 (2011).CrossRefGoogle Scholar
Souza Lima, M.M. and Borsali, R., Macromolecular Rapid Communications 25, 771 (2004).CrossRefGoogle Scholar
de Nooy, A. E. J., Besemer, A. and Bekkum, H., Recl. Trav. Chim. Pays-Bas 113, 165 (1994).Google Scholar
Habibi, Y., Chanzy, H. and Vignon, M. Cellulose 13, 679 (2006).Google Scholar
Sihvola, A.H., EEE Transactions on Microwave Theory and Techniques, 43, 2160 (1995).CrossRefGoogle Scholar
Magnusson, R., Hsiao, C., Birch, J., and Järrendahl, K., Opt. Mater. Express 4, 1389 (2014).Google Scholar
Gay, D., Cournoyer, A., Deladurantaye, P., Briand, M., Roy, V., Labranche, B., Levesque, M., and Taillon, Y., Proc. SPIE 7386, art. no. 73860Ra (2009).Google Scholar