Hostname: page-component-76fb5796d-45l2p Total loading time: 0 Render date: 2024-04-26T13:33:26.857Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of CeO2 doped with Sm2O3 and Eu2O3 for the use in SOFCs

Published online by Cambridge University Press:  07 May 2018

Alena Borisovna Kharissova ,
Moisés Hinojosa Rivera  and
Oxana V. Kharissova
Alena Borisovna Kharissova
Affiliation:
FIMEUniversidad Autónoma de Nuevo León, Monterrey, México UANL
Moisés Hinojosa Rivera
Affiliation:
FIMEUniversidad Autónoma de Nuevo León, Monterrey, México UANL
Oxana V. Kharissova*
Affiliation:
FCFM Universidad Autónoma de Nuevo León, Monterrey, México UANL
*
*(Email: okhariss@mail.ru)
Get access

Abstract

To free ourselves from the use of fossil fuels that are highly polluting, life-threatening and not easily regenerated, new technologies are being developed to obtain alternative energy sources more efficiently. Among these technologies, there is the option to improve the performance of solid oxide fuel cells (SOFCs) to make them highly energy efficient. Solid oxide fuel cells (SOFCs) have attracted much attention because they are environmentally benign, sustainable, generate low emissions and have relative low cost. However, conventional SOFCs with yttria-stabilized zirconia (YSZ) electrolyte require high operating temperatures (800-1000°C), which often lead to material degradation problems. Given that the greatest disadvantage of SOFCs is their high operating temperature, samples of CeO2 were synthesized by spray pyrolysis method and doped with Sm2O3 and Eu2O3 to improve the ionic conductivity of the electrolyte so that it can operate at lower temperatures without losing its efficiency. The samples were analyzed using SEM, EDS, TEM. Further research will be made by small angle DRX, AFM, EIS and a prototype will be built to test the working temperature of the electrolyte.

Keywords

Cespray pyrolysisEu
Type
Articles
Information
MRS Advances , Volume 3 , Issue 32: Energy and Sustainability , 2018 , pp. 1855 - 1861
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Mendoza Muñiz, D. A., & Hinojosa Rivera, M. (2016). Síntesis y caracterización de CeO2 para posibles usos en celdas de combustible de óxido sólido (PhD thesis, UANL-FIME) (p. 4–30). San Nicolás de los Garza, Mexico.Google Scholar
Sriubas, Mantas, Iaukaitis, Giedrius. The Influence of the Technological Parameters on the Ionic Conductivity of Samarium Doped Ceria Thin Films Materials Science (MEDŽIAGOTYRA). Vol. 21, No. 1. 2015 ISSN 1392–1320.CrossRefGoogle Scholar
Shiqiang, H., Roller, J., Yick, S., Zhang, X., Decès-Petit, C., Xie, Y., Maric, R., Ghosh, D. A Brief Review of the Ionic Conductivity Enhancement for Selected Oxide Electrolytes Journal of Power Sources 172 (2) 2007: pp. 493–502.CrossRefGoogle Scholar
Tatsumi Ishihara Nanomaterials for Advanced Electrode of Low Temperature Solid Oxide Fuel Cells (SOFCs) J. Korean Ceram. Soc. 2016;53 (5): 469–477.CrossRefGoogle Scholar
Ma, Ying, Ceria-based Nanocomposite Electrolyte for Low-Temperature Solid Oxide Fuel cells. Licentiate Thesis Stockholm 2009 ISSN 1653–7610.Google Scholar
Sriubas, Mantas, Iaukaitis, Giedrius The Influence of the Technological Parameters on the Ionic Conductivity of Samarium Doped Ceria Thin Films Materials Science (MEDŽIAGOTYRA). Vol. 21, No. 1. 2015 ISSN 1392–1320.CrossRefGoogle Scholar
Wachsman, Eric D. and Lee, Kang Taek (2011) Lowering the Temperature of Solid Oxide Fuel Cells. Science Vol. 334 no. 6058 pp. 935–939.CrossRefGoogle Scholar