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In situ and operando transmissionelectron microscopy of catalytic materials

Published online by Cambridge University Press:  13 January 2015

Peter A. Crozier  and
Thomas W. Hansen
Peter A. Crozier
Affiliation:
School of Engineering of Matter, Transport and Energy, Arizona State University, USA; crozier@asu.edu
Thomas W. Hansen
Affiliation:
Center for Electron Nanoscopy, Technical University of Denmark, Denmark; twh@cen.dtu.dk
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Abstract

Catalytic nanomaterials play a major role in chemical conversions and energytransformations. Understanding how materials control and regulate surfacereactions is a major objective for fundamental research on heterogeneouscatalysts. In situ environmental transmission electronmicroscopy (ETEM) is a powerful technique for revealing the atomic structures ofmaterials at elevated temperatures in the presence of reactive gases. Thisapproach can allow the structure–reactivity relations underlyingcatalyst functionality to be investigated. Thus far, ETEM has been limited bythe absence of in situ measurements of gas-phase catalyticproducts. To overcome this deficiency, operando TEM techniquesare being developed that combine atomic characterization with the simultaneousmeasurement of catalytic products. This article provides a short review of thecurrent status and major developments in the application of ETEM to gas-phasecatalysis over the past 10 years.

Keywords

transmission electron microscopy (TEM)catalysisnanoscalein situoperando

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Type
Research Article
Information
MRS Bulletin , Volume 40 , Issue 1: Frontiers of in situ electron microscopy , January 2015 , pp. 38 - 45
Copyright
Copyright © Materials Research Society 2015 

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