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Elastic strain engineering of ferroic oxides

  • Darrell G. Schlom (a1), Long-Qing Chen (a2), Craig J. Fennie (a3), Venkatraman Gopalan (a4), David A. Muller (a5), Xiaoqing Pan (a6), Ramamoorthy Ramesh (a7) and Reinhard Uecker (a8)...
Abstract

Using epitaxy and the misfit strain imposed by an underlying substrate, it is possible to elastically strain oxide thin films to percent levels—far beyond where they would crack in bulk. Under such strains, the properties of oxides can be dramatically altered. In this article, we review the use of elastic strain to enhance ferroics, materials containing domains that can be moved through the application of an electric field (ferroelectric), a magnetic field (ferromagnetic), or stress (ferroelastic). We describe examples of transmuting oxides that are neither ferroelectric nor ferromagnetic in their unstrained state into ferroelectrics, ferromagnets, or materials that are both at the same time (multiferroics). Elastic strain can also be used to enhance the properties of known ferroic oxides or to create new tunable microwave dielectrics with performance that rivals that of existing materials. Results show that for thin films of ferroic oxides, elastic strain is a viable alternative to the traditional method of chemical substitution to lower the energy of a desired ground state relative to that of competing ground states to create materials with superior properties.

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1.Lindh, A.E., in Nobel Lectures in Physics 1942–1962 (World Scientific, Singapore, 1998), pp. 4952.
2.Lock, J.M., Philos. Trans. R. Soc. London, Ser. A 208, 391 (1951).
3.Forsbergh, P.W. Jr., Phys. Rev. 93, 686 (1954).
4.Nguyen, L.D., Brown, A.S., Thompson, M.A., Jelloian, L.M., IEEE Trans. Electron Devices 39, 2007 (1992).
5.Welser, J., Hoyt, J.L., Gibbons, J.F., IEEE Electron Device Lett. 15, 100 (1994).
6.Shockley, W., Bardeen, J., Phys. Rev. 77, 407 (1950).
7.Sato, H., Naito, M., Physica C 274, 221 (1997).
8.Bozovic, I., Logvenov, G., Belca, I., Narimbetov, B., Sveklo, I., Phys. Rev. Lett. 89, 107001 (2002).
9.Beach, R.S., Borchers, J.A., Matheny, A., Erwin, R.W., Salamon, M.B., Everitt, B., Pettit, K., Rhyne, J.J., Flynn, C.P., Phys. Rev. Lett. 70, 3502 (1993).
10.Gan, Q., Rao, R.A., Eom, C.B., Garrett, J.L., Lee, M., Appl. Phys. Lett. 72, 978 (1998).
11.Fuchs, D., Arac, E., Pinta, C., Schuppler, S., Schneider, R., Löhneysen, H.v., Phys. Rev. B. 77, 014434 (2008).
12.Haeni, J.H., Irvin, P., Chang, W., Uecker, R., Reiche, P., Li, Y.L., Choudhury, S., Tian, W., Hawley, M.E., Craigo, B., Tagantsev, A.K., Pan, X.Q., Streiffer, S.K., Chen, L.Q., Kirchoefer, S.W., Levy, J., Schlom, D.G., Nature 430, 758 (2004).
13.Choi, K.J., Biegalski, M.D., Li, Y.L., Sharan, A., Schubert, J., Uecker, R., Reiche, P., Chen, Y.B., Pan, X.Q., Gopalan, V., Chen, L.-Q., Schlom, D.G., Eom, C.B., Science 306, 1005 (2004).
14.Schlom, D.G., Chen, L.Q., Eom, C.B., Rabe, K.M., Streiffer, S.K., Triscone, J.-M., Annu. Rev. Mater. Res. 37, 589 (2007).
15.Warusawithana, M.P., Cen, C., Sleasman, C.R., Woicik, J.C., Li, Y.L., Kourkoutis, L.F., Klug, J.A., Li, H., Ryan, P., Wang, L.-P., Bedzyk, M., Muller, D.A., Chen, L.Q., Levy, J., Schlom, D.G., Science 324, 367 (2009).
16.Lee, J.H., Fang, L., Vlahos, E., Ke, X., Jung, Y.W., Kourkoutis, L.F., Kim, J.-W., Ryan, P.J., Heeg, T., Roeckerath, M., Goian, V., Bernhagen, M., Uecker, R., Hammel, P.C., Rabe, K.M., Kamba, S., Schubert, J., Freeland, J.W., Muller, D.A., Fennie, C.J., Schiffer, P., Gopalan, V., Johnston-Halperin, E., Schlom, D.G., Nature 466, 954 (2010).
17.Adamo, C., Ke, X., Wang, H.Q., Xin, H.L., Heeg, T., Hawley, M.E., Zander, W., Schubert, J., Schiffer, P., Muller, D.A., Maritato, L., Schlom, D.G., Appl. Phys. Lett. 95, 112504 (2009).
18.Béa, H., Dupé, B., Fusil, S., Mattana, R., Jacquet, E., Warot-Fonrose, B., Wilhelm, F., Rogalev, A., Petit, S., Cros, V., Anane, A., Petroff, F., Bouzehouane, K., Geneste, G., Dkhil, B., Lisenkov, S., Ponomareva, I., Bellaiche, L., Bibes, M., Barthélémy, A., Phys. Rev. Lett. 102, 217603 (2009).
19.Infante, I.C., Lisenkov, S., Dupé, B., Bibes, M., Fusil, S., Jacquet, E., Geneste, G., Petit, S., Courtial, A., Juraszek, J., Bellaiche, L., Barthélémy, A., Dkhil, B., Phys. Rev. Lett. 105, 057601 (2010).
20.Chen, Z., Luo, Z., Huang, C., Qi, Y., Yang, P., You, L., Hu, C., Wu, T., Wang, J., Gao, C., Sritharan, T., Chen, L., Adv. Funct. Mater. 21, 133 (2011).
21.Zeches, R.J., Rossell, M.D., Zhang, J.X., Hatt, A.J., He, Q., Yang, C.-H., Kumar, A., Wang, C.H., Melville, A., Adamo, C., Sheng, G., Chu, Y.-H., Ihlefeld, J.F., Erni, R., Ederer, C., Gopalan, V., Chen, L.Q., Schlom, D.G., Spaldin, N.A., Martin, L.W., Ramesh, R., Science 326, 977 (2009).
22.Chen, P., Podraza, N.J., Xu, X.S., Melville, A., Vlahos, E., Gopalan, V., Ramesh, R., Schlom, D.G., Musfeldt, J.L., Appl. Phys. Lett. 96, 131907 (2010).
23.Christen, H.M., Nam, J.H., Kim, H.S., Hatt, A.J., Spaldin, N.A., Phys. Rev. B 83, 144107 (2011).
24.Martin, L.W., Schlom, D.G., Curr. Opin. Solid State Mater. Sci. 16, 199 (2012).
25.Griffith, A.A., Philos. Trans. R. Soc. London, Ser. A 221, 163 (1920).
26.Klokholm, E., Matthews, J.W., Mayadas, A.F., Angilello, J., in Magnetism and Magnetic Materials, Graham, C.D. Jr., Rhyne, J.J., Eds. (American Institute of Physics, New York, 1972), pp. 105109.
27.Freund, L.B., Suresh, S., Thin Film Materials: Stress, Defect Formation and Surface Evolution (Cambridge University Press, Cambridge, 2003), pp. 6083, 283–290, 396–416.
28.Pertsev, N.A., Tagantsev, A.K., Setter, N., Phys. Rev. B 61, R825 (2000).
29.Pertsev, N.A., Tagantsev, A.K., Setter, N., Phys. Rev. B 65, 219901 (2002).
30.Devonshire, A.F., Philos. Mag. 3 (Suppl.), 85 (1954).
31.Antons, A., Neaton, J.B., Rabe, K.M., Vanderbilt, D., Phys. Rev. B 71, 024102 (2005).
32.Li, Y.L., Choudhury, S., Haeni, J.H., Biegalski, M.D., Vasudevarao, A., Sharan, A., Ma, H.Z., Levy, J., Gopalan, V., Trolier-McKinstry, S., Schlom, D.G., Jia, Q.X., Chen, L.Q., Phys. Rev. B 73, 184112 (2006).
33.Canedy, C.L., Li, H., Alpay, S.P., Salamanca-Riba, L., Roytburd, A.L., Ramesh, R., Appl. Phys. Lett. 77, 1695 (2000).
34.Misirlioglu, I.B., Vasiliev, A.L., Aindow, M., Alpay, S.P., Ramesh, R., Appl. Phys. Lett. 84, 1742 (2004).
35.Chu, M.-W., Szafraniak, I., Scholz, R., Harnagea, C., Hesse, D., Alexe, M., Gösele, U., Nature Mater. 3, 87 (2004).
36.Alpay, S.P., Misirlioglu, I.B., Nagarajan, V., Ramesh, R., Appl. Phys. Lett. 85, 2044 (2004).
37.Nagarajan, V., Jia, C.L., Kohlstedt, H., Waser, R., Misirlioglu, I.B., Alpay, S.P., Ramesh, R., Appl. Phys. Lett. 86, 192910 (2005).
38.Biegalski, M.D., Fong, D.D., Eastman, J.A., Fuoss, P.H., Streiffer, S.K., Heeg, T., Schubert, J., Tian, W., Nelson, C.T., Pan, X.Q., Hawley, M.E., Bernhagen, M., Reiche, P., Uecker, R., Trolier-McKinstry, S., Schlom, D.G., J. Appl. Phys. 104, 114109 (2008).
39.Uecker, R., Wilke, H., Schlom, D.G., Velickov, B., Reiche, P., Polity, A., Bernhagen, M., Rossberg, M., J. Cryst. Growth 295, 84 (2006).
40.Uecker, R., Velickov, B., Klimm, D., Bertram, R., Bernhagen, M., Rabe, M., Albrecht, M., Fornari, R., Schlom, D.G., J. Cryst. Growth 310, 2649 (2008).
41.Uecker, R., Klimm, D., Bertram, R., Bernhagen, M., Schulze-Jonack, I., Brützam, M., Kwasniewski, A., Gesing, T.M., Schlom, D.G., Acta Phys. Pol. A 124, 295 (2013).
42.Lempicki, A., Randles, M.H., Wisniewski, D., Balcerzyk, M., Brecher, C., Wojtowicz, A.J., IEEE Trans. Nucl. Sci. 42, 280 (1995).
43.Petrosyan, A.G., Shirinyan, G.O., Pedrini, C., Durjardin, C., Ovanesyan, K.L., Manucharyan, R.G., Butaeva, T.I., Derzyan, M.V., Cryst. Res. Technol. 33, 241 (1998).
44.Asano, H., Kubo, S., Michikami, O., Satoh, M., Konaka, T., Jpn. J. Appl. Phys., Part 2 29, L1452 (1990).
45.Brown, R., Pendrick, V., Kalokitis, D., Chai, B.H.T., Appl. Phys. Lett. 57, 1351 (1990).
46.Miyazawa, Y., Toshima, H., Morita, S., J. Cryst. Growth 128, 668 (1993).
47.Berkstresser, G.W., Valentino, A.J., Brandle, C.D., J. Cryst. Growth 109, 467 (1991).
48.Berkstresser, G.W., Valentino, A.J., Brandle, C.D., J. Cryst. Growth 128, 684 (1993).
49.Hontsu, S., Ishii, J., Kawai, T., Kawai, S., Appl. Phys. Lett. 59, 2886 (1991).
50.Mateika, D., Kohler, H., Laudan, H., Volkel, E., J. Cryst. Growth 109, 447 (1991).
51.Simon, R.W., Platt, C.E., Lee, A.E., Lee, G.S., Daly, K.P., Wire, M.S., Luine, J.A., Urbanik, M., Appl. Phys. Lett. 53, 2677 (1988).
52.Berkstresser, G.W., Valentino, A.J., Brandle, C.D., J. Cryst. Growth 109, 457 (1991).
53.Chakoumakos, B.C., Schlom, D.G., Urbanik, M., Luine, J., J. Appl. Phys. 83, 1979 (1998).
54.Sandstrom, R.L., Giess, E.A., Gallagher, W.J., Segmüller, A., Cooper, E.I., Chisholm, M.F., Gupta, A., Shinde, S., Laibowitz, R.B., Appl. Phys. Lett. 53, 1874 (1988).
55.Merker, L., US Patent No. 2,684,910 (27 July 1954).
56.Bednorz, J.G., Scheel, H.J., J. Cryst. Growth 41, 5 (1977).
57.Nabokin, P.I., Souptel, D., Balbashov, A.M., J. Cryst. Growth 250, 397 (2003).
58.Scheel, H.J., Bednorz, J.G., Dill, P., Ferroelectrics 13, 507 (1976).
59.Lim, S.-G., Kriventsov, S., Jackson, T.N., Haeni, J.H., Schlom, D.G., Balbashov, A.M., Uecker, R., Reiche, P., Freeouf, J.L., Lucovsky, G., J. Appl. Phys. 91, 4500 (2002).
60.Soukiassian, A., Tian, W., Vaithyanathan, V., Haeni, J.H., Chen, L.Q., Xi, X.X., Schlom, D.G., Tenne, D.A., Sun, H.P., Pan, X.Q., Choi, K.J., Eom, C.B., Li, Y.L., Jia, Q.X., Constantin, C., Feenstra, R.M., Bernhagen, M., Reiche, P., Uecker, R., J. Mater. Res. 23, 1417 (2008).
61.Feenstra, R., Boatner, L.A., Budai, J.D., Christen, D.K., Galloway, M.D., Poker, D.B., Appl. Phys. Lett. 54, 1063 (1989).
62.Yang, J.C., He, Q., Suresha, S.J., Kuo, C.Y., Peng, C.Y., Haislmaier, R.C., Motyka, M.A., Sheng, G., Adamo, C., Lin, H.J., Hu, Z., Chang, L., Tjeng, L.H., Arenholz, E., Podraza, N.J., Bernhagen, M., Uecker, R., Schlom, D.G., Gopalan, V., Chen, L.Q., Chen, C.T., Ramesh, R., Chu, Y.H., Phys. Rev. Lett. 109, 247606 (2012).
63.Coh, S., Heeg, T., Haeni, J.H., Biegalski, M.D., Lettieri, J., Edge, L.F., O’Brien, K.E., Bernhagen, M., Reiche, P., Uecker, R., Trolier-McKinstry, S., Schlom, D.G., Vanderbilt, D., Phys. Rev. B 82, 064101 (2010).
64.Ovanesyan, K.L., Petrosyan, A.G., Shirinyan, G.O., Pedrini, C., Zhang, L., J. Cryst. Growth 198, 497 (1999).
65.Biegalski, M.D., Jia, Y., Schlom, D.G., Trolier-McKinstry, S., Streiffer, S.K., Sherman, V., Uecker, R., Reiche, P., Appl. Phys. Lett. 88, 192907 (2006).
66.Ihlefeld, J.F., Tian, W., Liu, Z.-K., Doolittle, W.A., Bernhagen, M., Reiche, P., Uecker, R., Ramesh, R., Schlom, D.G., IEEE Trans. Ultrason. Ferroelectr. Freq. Control 56, 1528 (2009).
67.Lee, J.H., Ke, X., Misra, R., Ihlefeld, J.F., Xu, X.S., Mei, Z.G., Heeg, T., Roeckerath, M., Schubert, J., Liu, Z.K., Musfeldt, J.L., Schiffer, P., Schlom, D.G., Appl. Phys. Lett. 96, 262905 (2010).
68.Irvin, P., Levy, J., Haeni, J.H., Schlom, D.G., Appl. Phys. Lett. 88, 042902 (2006).
69.Ma, H.Z., Levy, J., Biegalski, M.D., Trolier-McKinstry, S., Schlom, D.G., J. Appl. Phys. 105, 014102 (2009).
70.Vasudevarao, A., Kumar, A., Tian, L., Haeni, J.H., Li, Y.L., Eklund, C.-J., Jia, Q.X., Uecker, R., Reiche, P., Rabe, K.M., Chen, L.Q., Schlom, D.G., Gopalan, V., Phys. Rev. Lett. 97, 257602 (2006).
71.Vasudevarao, A., Denev, S., Biegalski, M.D., Li, Y.L., Chen, L.Q., Trolier-McKinstry, S., Schlom, D.G., Gopalan, V., Appl. Phys. Lett. 92, 192902 (2008).
72.Denev, S., Kumar, A., Biegalski, M.D., Jang, H.W., Folkman, C.M., Vasudevarao, A., Han, Y., Reaney, I.M., Trolier-McKinstry, S., Eom, C.B., Schlom, D.G., Gopalan, V., Phys. Rev. Lett. 100, 257601 (2008).
73.Biegalski, M.D., Vlahos, E., Sheng, G., Li, Y.L., Bernhagen, M., Reiche, P., Uecker, R., Streiffer, S.K., Chen, L.Q., Gopalan, V., Schlom, D.G., Trolier-McKinstry, S., Phys. Rev. B 79, 224117 (2009).
74.Nuzhnyy, D., Petzelt, J., Kamba, S., Kužel, P., Kadlec, C., Bovtun, V., Kempa, M., Schubert, J., Brooks, C.M., Schlom, D.G., Appl. Phys. Lett. 95, 232902 (2009).
75.Lee, C.H., Skoromets, V., Biegalski, M.D., Lei, S., Haislmaier, R., Bernhagen, M., Uecker, R., Xi, X.X., Gopalan, V., Martí, X., Kamba, S., Kužel, P., Schlom, D.G., Appl. Phys. Lett. 102, 082905 (2013).
76.Hubbard, K.J., Schlom, D.G., J. Mater. Res. 11, 2757 (1996).
77.Schlom, D.G., Guha, S., Datta, S., MRS Bull. 33, 1017 (2008).
78.Kourkoutis, L.F., Hellberg, C.S., Vaithyanathan, V., Li, H., Parker, M.K., Andersen, K.E., Schlom, D.G., Muller, D.A., Phys. Rev. Lett. 100, 036101 (2008).
79.Li, H., Hu, X., Wei, Y., Yu, Z., Zhang, X., Droopad, R., Demkov, A.A., Edwards, J., Moore, K., Ooms, W., Kulik, J., Fejes, P., J. Appl. Phys. 93, 4521 (2003).
80.Kawasaki, M., Takahashi, K., Maeda, T., Tsuchiya, R., Shinohara, M., Ishiyama, O., Yonezawa, T., Yoshimoto, M., Koinuma, H., Science 266, 1540 (1994).
81.Koster, G., Kropman, B.L., Rijnders, G.J.H.M., Blank, D.H.A., Rogalla, H., Appl. Phys. Lett. 73, 2920 (1998).
82.Schrott, A.G., Misewich, J.A., Copel, M., Abraham, D.W., Zhang, Y., Appl. Phys. Lett. 79, 1786 (2001).
83.Biswas, A., Rossen, P.B., Yang, C.H., Siemons, W., Jung, M.H., Yang, I.K., Ramesh, R., Jeong, Y.H., Appl. Phys. Lett. 98, 051904 (2011).
84.Chang, J., Park, Y.-S., Kim, S.-K., Appl. Phys. Lett. 92, 152910 (2008).
85.Blok, J.L., Wan, X., Koster, G., Blank, D.H.A., Rijnders, G., Appl. Phys. Lett. 99, 151917 (2011).
86.Ohnishi, T., Takahashi, K., Nakamura, M., Kawasaki, M., Yoshimoto, M., Koinuma, H., Appl. Phys. Lett. 74, 2531 (1999).
87.Ngai, J.H., Schwendemann, T.C., Walker, A.E., Segal, Y., Walker, F.J., Altman, E.I., Ahn, C.H., Adv. Mater. 22, 2945 (2010).
88.Kleibeuker, J.E., Koster, G., Siemons, W., Dubbink, D., Kuiper, B., Blok, J.L., Yang, C.-H., Ravichandran, J., Ramesh, R., ten Elshof, J.E., Blank, D.H.A., Rijnders, G., Adv. Funct. Mater. 20, 3490 (2010).
89.Kleibeuker, J.E., Kuiper, B., Harkema, S., Blank, D.H.A., Koster, G., Rijnders, G., Tinnemans, P., Vlieg, E., Rossen, P.B., Siemons, W., Portale, G., Ravichandran, J., Szepieniec, J.M., Ramesh, R., Phys. Rev. B 85, 165413 (2012).
90.Bae, H.-J., Sigman, J., Norton, D.P., Boatner, L.A., Appl. Surf. Sci. 241, 271 (2005).
91.Pertsev, N.A., Zembilgotov, A.G., Tagantsev, A.K., Phys. Rev. Lett. 80, 1988 (1998).
92.Diéguez, O., Tinte, S., Antons, A., Bungaro, C., Neaton, J.B., Rabe, K.M., Vanderbilt, D., Phys. Rev B 69, 212101 (2004).
93.Li, Y.L., Chen, L.Q., Appl. Phys. Lett. 88, 072905 (2006).
94.Tenne, D.A., Turner, P., Schmidt, J.D., Biegalski, M., Li, Y.L., Chen, L.Q., Soukiassian, A., Trolier-McKinstry, S., Schlom, D.G., Xi, X.X., Fong, D.D., Fuoss, P.H., Eastman, J.A., Stephenson, G.B., Thompson, C., Streiffer, S.K., Phys. Rev. Lett. 103, 177601 (2009).
95.Pertsev, A., Koukhar, V.G., Phys. Rev. Lett. 84, 3722 (2000).
96.Koukhar, V.G., Pertsev, N.A., Waser, R., Phys. Rev. B 64, 214103 (2001).
97.Li, Y.L., Hu, S.Y., Liu, Z.K., Chen, L.Q., Appl. Phys. Lett. 78, 3878 (2001).
98.Li, Y.L., Hu, S.Y., Liu, Z.K., Chen, L.Q., Acta Mater. 50, 395 (2002).
99.Streiffer, S.K., Eastman, J.A., Fong, D.D., Thompson, C., Munkholm, A., Murty, M.V.R., Auciello, O., Bai, G.R., Stephenson, G.B., Phys. Rev. Lett. 89, 067601 (2002).
100.Fong, D.D., Stephenson, G.B., Streiffer, S.K., Eastman, J.A., Auciello, O., Fuoss, P.H., Thompson, C., Science 304, 1650 (2004).
101.Abe, K., Yanase, N., Sano, K., Izuha, M., Fukushima, N., Kawakubo, T., Integr. Ferroelectr. 21, 197 (1998).
102.Yanase, N., Abe, K., Fukushima, N., Kawakubo, T., Jpn. J. Appl. Phys., Part 1 38, 5305 (1999).
103.Specht, E.D., Christen, H.-M., Norton, D.P., Boatner, L.A., Phys. Rev. Lett. 80, 4317 (1998).
104.Christen, H.-M., Knauss, L.A., Harshavardhan, K.S., Mater. Sci. Eng., B 56, 200 (1998).
105.Christen, H.M., Specht, E.D., Silliman, S.S., Harshavardhan, K.S., Phys. Rev. B 68, 20101 (2003).
106.Dawber, M., Lichtensteiger, C., Cantoni, M., Veithen, M., Ghosez, P., Johnston, K., Rabe, K.M., Triscone, J.-M., Phys. Rev. Lett. 95, 177601 (2005).
107.Bousquet, E., Dawber, M., Stucki, N., Lichtensteiger, C., Hermet, P., Gariglio, S., Triscone, J.M., Ghosez, P., Nature 452, 732 (2008).
108.Neaton, J.B., Rabe, K.M., Appl. Phys. Lett. 82, 1586 (2003).
109.Tenne, D.A., Bruchhausen, A., Lanzillotti-Kimura, N.D., Fainstein, A., Katiyar, R.S., Cantarero, A., Soukiassian, A., Vaithyanathan, V., Haeni, J.H., Tian, W., Schlom, D.G., Choi, K.J., Kim, D.M., Eom, C.B., Sun, H.P., Pan, X.Q., Li, Y.L., Chen, L.Q., Jia, Q.X., Nakhmanson, S.M., Rabe, K.M., Xi, X.X., Science 313, 1614 (2006).
110.Li, Y.L., Hu, S.Y., Tenne, D., Soukiassian, A., Schlom, D.G., Xi, X.X., Choi, K.J., Eom, C.B., Saxena, A., Lookman, T., Jia, Q.X., Chen, L.Q., Appl. Phys. Lett. 91, 112914 (2007).
111.Li, Y.L., Hu, S.Y., Tenne, D., Soukiassian, A., Schlom, D.G., Chen, L.Q., Xi, X.X., Choi, K.J., Eom, C.B., Saxena, A., Lookman, T., Jia, Q.X., Appl. Phys. Lett. 91, 252904 (2007).
112.Sai, N., Meyer, B., Vanderbilt, D., Phys. Rev. Lett. 84, 5636 (2000).
113.Warusawithana, M.R., Colla, E.V., Eckstein, J.N., Weissman, M.B., Phys. Rev. Lett. 90, 036802 (2003).
114.Lee, H.N., Christen, H.M., Chisholm, M.F., Rouleau, C.M., Lowndes, D.H., Nature 433, 395 (2005).
115.Zembilgotov, A.G., Pertsev, N.A., Böttger, U., Waser, R., Appl. Phys. Lett. 86, 052903 (2005).
116.Sheng, G., Li, Y.L., Zhang, J.X., Choudhury, S., Jia, Q.X., Gopalan, V., Schlom, D.G., Liu, Z.K., Chen, L.Q., J. Appl. Phys. 108, 084113 (2010).
117.Kathan-Galipeau, K., Wu, P.P., Li, Y.L., Chen, L.Q., Soukiassian, A., Xi, X.X., Schlom, D.G., Bonnell, D.A., ACS Nano 5, 640 (2011).
118.Kathan-Galipeau, K., Wu, P.P., Li, Y.L., Chen, L.Q., Soukiassian, A., Zhu, Y., Muller, D.A., Xi, X.X., Schlom, D.G., Bonnell, D.A., J. Appl. Phys. 112, 052011 (2012).
119.Ravichandran, J., Yadav, A.K., Cheaito, R., Rossen, P.B., Soukiassian, A., Suresha, S.J., Duda, J.C., Foley, B.M., Lee, C.H., Zhu, Y., Lichtenberger, A.W., Moore, J.E., Muller, D.A., Schlom, D.G., Hopkins, P.E., Majumdar, A., Ramesh, R., Zurbuchen, M.A., Nat. Mater. (2013), in press, doi: 10.1038/nmat3826.
120.Wang, J., Neaton, J.B., Zheng, H., Nagarajan, V., Ogale, S.B., Liu, B., Viehland, D., Vaithyanathan, V., Schlom, D.G., Waghmare, U.V., Spaldin, N.A., Rabe, K.M., Wuttig, M., Ramesh, R., Science 299, 1719 (2003).
121.Ramesh, R., Spaldin, N.A., Nat. Mater. 6, 21 (2007).
122.Belik, A.A., Iikubo, S., Kodama, K., Igawa, N., Shamoto, S.-I., Niitaka, S., Azuma, M., Shimakawa, Y., Takano, M., Izumi, F., Takayama-Muromachi, E., Chem. Mater. 18, 798 (2006).
123.Li, M.-R., Adem, U., McMitchell, S.R.C., Xu, Z., Thomas, C.I., Warren, J.E., Giap, D.V., Niu, H., Wan, X., Palgrave, R.G., Schiffmann, F., Cora, F., Slater, B., Burnett, T.L., Cain, M.G., Abakumov, A.M., van Tendeloo, G., Thomas, M.F., Rosseinsky, M.J., Claridge, J.B., J. Am. Chem. Soc. 134, 3737 (2012).
124.Wang, W., Zhao, J., Wang, W., Gai, Z., Balke, N., Chi, M., Lee, H.N., Tian, W., Zhu, L., Cheng, X., Keavney, D.J., Yi, J., Ward, T.Z., Snijders, P.C., Christen, H.M., Wu, W., Shen, J., Xu, X., Phys. Rev. Lett. 110, 237601 (2013).
125.Li, J.F., Wang, J., Wuttig, M., Ramesh, R., Wang, N., Ruette, B., Pyatakov, A.P., Zvezdin, A.K., Viehland, D., Appl. Phys. Lett. 84, 5261 (2004).
126.Das, R.R., Kim, D.M., Baek, S.H., Eom, C.B., Zavaliche, F., Yang, S.Y., Ramesh, R., Chen, Y.B., Pan, X.Q., Ke, X., Rzchowski, M.S., Streiffer, S.K., Appl. Phys. Lett. 88, 242904 (2006).
127.Dho, J., Qi, X., Kim, H., MacManus-Driscoll, J.L., Blamire, M.G., Adv. Mater. 18, 1445 (2006).
128.Kubel, F., Schmid, H., Acta Crystallogr., Sect. B: Struct. Sci. 46, 698 (1990).
129.Hatt, A.J., Spaldin, N.A., Ederer, C., Phys. Rev. B 81, 054109 (2010).
130.Christy, A.G., Acta Crystallogr. Sect. B: Struct. Sci. 51, 753 (1995).
131.Ehm, L., Knorr, K., Peters, L., Rath, S., Depmeier, W., J. Alloys Compd. 429, 82 (2007).
132.Haines, J., Léger, J.M., Schulte, O., Phys. Rev. B 57, 7551 (1998).
133.Zhang, J.X., Xiang, B., He, Q., Seidel, J., Zeches, R.J., Yu, P., Yang, S.Y., Wang, C.H., Chu, Y.H., Martin, L.W., Minor, A.M., Ramesh, R., Nat. Nanotechnol. 6, 98 (2011).
134.He, Q., Chu, Y.H., Heron, J.T., Yang, S.Y., Liang, W.I., Kuo, C.Y., Lin, H.J., Yu, P., Liang, C.W., Zeches, R.J., Kuo, W.C., Juang, J.Y., Chen, C.T., Arenholz, E., Scholl, A., Ramesh, R., Nat. Commun. 2, 225 (2011).
135.Yang, J.C., He, Q., Suresha, S.J., Kuo, C.Y., Peng, C.Y., Haislmaier, R.C., Motyka, M.A., Sheng, G., Adamo, C., Lin, H.J., Hu, Z., Chang, L., Tjeng, L.H., Arenholz, E., Podraza, N.J., Bernhagen, M., Uecker, R., Schlom, D.G., Gopalan, V., Chen, L.Q., Chen, C.T., Ramesh, R., Chu, Y.H., Phys. Rev. Lett. 109, 247606 (2012).
136.Fennie, C.J., Rabe, K.M., Phys. Rev. Lett. 97, 267602 (2006).
137.Rivera, J.P., Schmid, H., Ferroelectrics 36, 447 (1981).
138.von Wartburg, W., Phys. Status Solidi A 21, 557 (1974).
139.Birol, T., Fennie, C.J., Phys. Rev. B 88, 094103 (2013).
140.McGuire, T.R., Shafer, M.W., Joenk, R.J., Alperin, H.A., Pickart, S.J., J. Appl. Phys. 37, 981 (1966).
141.Chien, C.-L., DeBenedetti, S., De, F.Barros, S., Phys. Rev. B 10 3913 (1974).
142.Katsufuji, T., Takagi, H., Phys. Rev. B 64, 054415 (2001).
143.Wang, H.-H., Fleet, A., Brock, J.D., Dale, D., Suzuki, Y., J. Appl. Phys. 96, 5324 (2004).
144.Kugimiya, K., Fujita, K., Tanaka, K., Hirao, K., J. Magn. Magn. Mater. 310, 2268 (2007).
145.Chae, S.C., Chang, Y.J., Kim, D.-W., Lee, B.W., Choi, I., Jung, C.U., J. Electroceram. 22, 216 (2009).
146.Fujita, K., Wakasugi, N., Murai, S., Zong, Y., Tanaka, K., Appl. Phys. Lett. 94, 062512 (2009).
147.Schafer, M.W., J. Appl. Phys. 36, 1145 (1965).
148.McCarthy, G.J., White, W.B., Roy, R., J. Inorg. Nucl. Chem. 31, 329 (1969).
149.Kim, Y.S., Kim, D.J., Kim, T.H., Noh, T.W., Choi, J.S., Park, B.H., Yoon, J.-G., Appl. Phys. Lett. 91, 042908 (2007).
150.Müller, K.A., Burkard, H., Phys. Rev. B 19, 3593 (1979).
151.Tarsa, E.J., Hachfeld, E.A., Quinlan, F.T., Speck, J.S., Eddy, M., Appl. Phys. Lett. 68, 490 (1996).
152.Ohnishi, T., Lippmaa, M., Yamamoto, T., Meguro, S., Koinuma, H., Appl. Phys. Lett. 87, 2419191 (2005).
153.Ohnishi, T., Shibuya, K., Yamamoto, T., Lippmaa, M., J. Appl. Phys. 103, 103703 (2008).
154.Kestigian, M., Dickinson, J.G., Ward, R., J. Am. Chem. Soc. 79, 5598 (1957).
155.Tenne, D.A., Gonenli, I.E., Soukiassian, A., Schlom, D.G., Nakhmanson, S.M., Rabe, K.M., Xi, X.X., Phys. Rev. B 76, 024303 (2007).
156.Brooks, C.M., Fitting Kourkoutis, L., Heeg, T., Schubert, J., Muller, D.A., Schlom, D.G., Appl. Phys. Lett. 94, 162905 (2009).
157.Lee, J.H., Ke, X., Podraza, N.J., Fitting Kourkoutis, L., Heeg, T., Roeckerath, M., Freeland, J.W., Fennie, C.J., Schubert, J., Muller, D.A., Schiffer, P., Schlom, D.G., Appl. Phys. Lett. 94, 212509 (2009).
158.Lee, J.H., Rabe, K.M., Phys. Rev. Lett. 104, 207204 (2010).
159.Bousquet, E., Spaldin, N.A., Ghosez, P., Phys. Rev. Lett. 104, 037601 (2010).
160.Ryan, P.J., Kim, J.-W., Birol, T., Thompson, P., Lee, J.-H., Ke, X., Normile, P.S., Karapetrova, E., Schiffer, P., Brown, S.D., Fennie, C.J., Schlom, D.G., Nat. Commun. 4, 1334 (2013).
161.Lee, C.H., Orloff, N.D., Birol, T., Zhu, Y., Goian, V., Rocas, E., Haislmaier, R., Vlahos, E., Mundy, J.A., Kourkoutis, L.F., Nie, Y., Biegalski, M.D., Zhang, J., Bernhagen, M., Benedek, N.A., Kim, Y., Brock, J.D., Uecker, R., Xi, X.X., Gopalan, V., Nuzhnyy, D., Kamba, S., Muller, D.A., Takeuchi, I., Booth, J.C., Fennie, C.J., Schlom, D.G., Nature 502, 532 (2013).
162.Vendik, O.G., Ferroelectrics 12, 85 (1976).
163.Kirchoefer, S.W., Pond, J.M., Carter, A.C., Chang, W., Agarwal, K.K., Horwitz, J.S., Chrisey, D.B., Microwave Opt. Technol. Lett. 18, 168 (1998).
164.Gevorgian, S.S., Kollberg, E.L., IEEE Trans. Microwave Theory Tech. 49, 2117 (2001).
165.Tagantsev, A.K., Sherman, V.O., Astafiev, K.F., Venkatesh, J., Setter, N., J. Electroceram. 11, 5 (2003).
166.Andersson, S., Wadsley, A.D., Nature 211, 581 (1966).
167.Anderson, J.S, Browne, J.M., Cheetham, A.K., Vondreel, R., Hutchison, J.L., Lincoln, F.J., Bevan, D.J.M., Straehle, J., Nature 243, 81 (1973).
168.Tilley, R.J.D., Nature 269, 229 (1977).
169.Tilley, R.J.D., J. Solid State Chem. 21, 293 (1977).
170.Nakamura, T., Sun, P.H., Shan, Y.J., Inaguma, Y., Itoh, M., Kim, I.S., Sohn, J.H., Ikeda, M., Kitamura, T., Konagaya, H., Ferroelectrics 196, 205 (1997).
171.Wise, P.L., Reaney, I.M., Lee, W.E., Price, T.J., Iddles, D.M., Cannell, D.S., J. Eur. Ceram. Soc. 21, 1723 (2001).
172.Orloff, N.D., Tian, W., Fennie, C.J., Lee, C.H., Gu, D., Mateu, J., Xi, X.X., Rabe, K.M., Schlom, D.G., Takeuchi, I., Booth, J.C., Appl. Phys. Lett. 94, 042908 (2009).
173.Birol, T., Benedek, N.A., Fennie, C.J., Phys. Rev. Lett. 107, 257602 (2011).
174.Klenov, D.O., Donner, W., Foran, B., Stemmer, S., Appl. Phys. Lett. 82, 3427 (2003).
175.Donner, W., Chen, C., Liu, M., Jacobson, A.J., Lee, Y.-L., Gadre, M., Morgan, D., Chem. Mater. 23, 984 (2011).
176.Rondinelli, J.M., Spaldin, N.A., Adv. Mater. 23, 3363 (2011).
177.Rondinelli, J.M., May, S.J., Freeland, J.W., MRS Bull. 37, 261 (2012).
178.Choi, W.S., Kwon, J.-H., Jeen, H., Hamann-Borrero, J.E., Radi, A., Macke, S., Sutarto, R., He, F., Sawatzky, G.A., Hinkov, V., Kim, M., Lee, H.N., Nano Lett. 12, 4966 (2012).
179.Yang, Y., Schlepütz, C.M., Adamo, C., Schlom, D.G., Clarke, R., APL Mater. 1, 052102 (2013).
180.Jia, C.-L., Nagarajan, V., He, J.-Q., Houben, L., Zhao, T., Ramesh, R., Urban, K., Waser, R., Nat. Mater. 6, 64 (2006).
181.Jia, C.-L., Mi, S.-B., Urban, K., Vrejoiu, I., Alexe, M., Hesse, D., Nat. Mater. 7, 57 (2008).
182.Nelson, C.T., Winchester, B., Zhang, Y., Kim, S.-J., Melville, A., Adamo, C., Folkman, C.M., Baek, S.-H., Eom, C.-B., Schlom, D.G., Chen, L.-Q., Pan, X., Nano Lett. 11, 828 (2011).
183.Jia, C.L., Urban, K.W., Alexe, M., Hesse, D., Vrejoiu, I., Science 331, 1420 (2011).
184.Borisevich, A.Y., Chang, H.J., Huijben, M., Oxley, M.P., Okamoto, S., Niranjan, M.K., Burton, J.D., Tsymbal, E.Y., Chu, Y.H., Yu, P., Ramesh, R., Kalinin, S.V., Pennycook, S.J., Phys. Rev. Lett. 105, 087204 (2010).
185.Muller, D.A., Kourkoutis, L.F., Murfitt, M., Song, J.H., Hwang, H.Y., Silcox, J., Dellby, N., Krivanek, O.L., Science 319, 1073 (2008).
186.Lee, D., Behera, R., Wu, P., Xu, H., Li, Y.L., Sinnott, S.B., Phillpot, S., Chen, L., Gopalan, V., Phys. Rev. B 80, 060102 (2009).
187.Kneller, E.F., Hawig, R., Magnetics, IEEE Trans. Magn. 27, 3588 (1991).
188.Fullerton, E.E., Jiang, J.S., Bader, S.D., J. Magn. Magn. Mater. 200, 392 (1999).
189.Wu, P., Ma, X., Li, Y., Gopalan, V., Chen, L.Q., Appl. Phys. Lett. 100, 092905 (2012).
190.Lee, J.H., Rabe, K.M., Phys. Rev. Lett. 107, 067601 (2011).
191.Newns, D.M., Elmegreen, B.G., Liu, X.-H., Martyna, G.J., Adv. Mater. 24, 3672 (2012).
192.Newns, D., Elmegreen, B., Hu Liu, X., Martyna, G., J. Appl. Phys. 111, 084509 (2012).
193.Newnham, R.E., Kramer, J.J., Schulze, W.A., Cross, L.E., J. Appl. Phys. 49, 6088 (1978).
194.Harris, M.J., Bramwell, S.T., McMorrow, D.F., Zeiske, T., Godfrey, K.W., Phys. Rev. Lett. 79, 2554 (1997).
195.Fennie, C., Rabe, K., Phys. Rev. B 72, 100103 (2005).
196.Choi, T., Horibe, Y., Yi, H.T., Choi, Y.J., Wu, W., Cheong, S.W., Nat. Mater. 9, 253 (2010).
197.Arkenbout, A., Palstra, T., Siegrist, T., Kimura, T., Phys. Rev. B 74, 184431 (2006).
198.Ye, F., Ren, Y., Huang, Q., Fernandez-Baca, J., Dai, P., Lynn, J., Kimura, T., Phys. Rev. B 73, 220404 (2006).
199.Kimura, T., Sekio, Y., Nakamura, H., Siegrist, T., Ramirez, A.P., Nat. Mater. 7, 291 (2008).
200.Kitagawa, Y., Hiraoka, Y., Honda, T., Ishikura, T., Nakamura, H., Kimura, T., Nat. Mater. 9, 797 (2010).
201.Bossak, A.A., Graboy, I.E., Gorbenko, O.Y., Kaul, A.R., Kartavtseva, M.S., Svetchnikov, V.L., Zandbergen, H.W., Chem. Mater. 16, 1751 (2004).
202.Wang, W., Zhao, J., Wang, W., Gai, Z., Balke, N., Chi, M., Lee, H.N., Tian, W., Zhu, L., Cheng, X., Keavney, D.J., Yi, J., Ward, T.Z., Snijders, P.C., Christen, H.M., Wu, W., Shen, J., Xu, X., Phys. Rev. Lett. 110, 237601 (2013).
203.Machlin, E.S., Chaudhari, P., in Synthesis and Properties of Metastable Phases, Machlin, E.S., Rowland, T.J., Eds. (The Metallurgical Society of AIME, Warrendale, 1980), pp. 1129.
204.Flynn, C.P., Phys. Rev. Lett. 57, 599 (1986).
205.Bruinsma, R., Zangwill, A., J. Phys. (Paris) 47, 2055 (1986).
206.Gorbenko, O.Y., Samoilenkov, S.V., Graboy, I.E., Kaul, A.R., Chem. Mater. 14, 4026 (2002).
207.Rondinelli, J.M., Fennie, C.J., Adv. Mater. 24, 1961 (2012).
208.Mulder, A.T., Benedek, N.A., Rondinelli, J.M., Fennie, C.J., Adv. Funct. Mater. 23, 4810 (2013).
209.Fennie, C.J., Phys. Rev. Lett. 100, 167203 (2008).
210.Varga, T., Kumar, A., Vlahos, E., Denev, S., Park, M., Hong, S., Sanehira, T., Wang, Y., Fennie, C., Streiffer, S., Ke, X., Schiffer, P., Gopalan, V., Mitchell, J., Phys. Rev. Lett. 103, 047601 (2009).
211.Singh-Bhalla, G., Bell, C., Ravichandran, J., Siemons, W., Hikita, Y., Salahuddin, S., Hebard, A.F., Hwang, H.Y., Ramesh, R., Nat. Phys. 7, 80 (2010).
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