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Published online by Cambridge University Press: 21 February 2011
Tyrosine-derived polycarbonates are currently in preclinical evaluations for biomedical applications. Although physical aging can significantly alter a wide range of polymer properties, physical aging is has rarely been investigated for biomedical polymers. A series of four tyrosinederived polycarbonates was used as a model system to study the effect of polymer structure on the enthalpy relaxation kinetics.