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Fabrication and Characterization of Size- and Shape-Controlled C60 Nano/microcrystals by Solvent-Induced Reprecipitation Process (SIRP)

Published online by Cambridge University Press:  01 February 2011

Akito Masuhara ,
Zhenquan Tan ,
Hitoshi Kasai ,
Hachiro Nakanishi  and
Hidetoshi Oikawa
Akito Masuhara
Affiliation:
masuhara@tagen.tohoku.ac.jp, Tohoku university, IMRAM, Katahira, 2-1-1, Aobaku, Sendai, 980-8577, Japan, +81-22-217-5645, +81-22-217-5645
Zhenquan Tan
Affiliation:
tanzq@mail.tagen.tohoku.ac.jp, IMRAM, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577, Japan
Hitoshi Kasai
Affiliation:
hkasai@tagen.tohoku.ac.jp, IMRAM, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577, Japan
Hachiro Nakanishi
Affiliation:
hnakanis@tagen.tohoku.ac.jp, IMRAM, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577, Japan
Hidetoshi Oikawa
Affiliation:
oikawah@tagen.tohoku.ac.jp, IMRAM, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577, Japan
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Abstract

We have first developed useful Solvent-Induced Reprecipitation Process, and have first succeeded in fabricating C60 nano/microcrystals with various shape and size, using m-xylene and 2-propanol as good and poor solvents, respectively.

It was found that the resulting C60 nano/microcrystals had a hexagonal crystal structure, and that were a kind of crystal solvates in which the molar ratio of C60 to m-xylene was 3:2. C60 nano/microcrystals could be said to be important nano components of integrated devices in electronics.

Keywords

colloidmicrostructureorganic

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References

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