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Incorporation of Siloxane And Cyclophosphazene Units Into Metal Oxides by a Nonhydrolytic Sol-Gel Route

Published online by Cambridge University Press:  10 February 2011

L. Crouzet ,
D. Leclercq ,
P. H. Mutin ,
R. J. P. Corriu  and
A. Vioux
L. Crouzet
Affiliation:
UMR CNRS 5637, cc 007, Université Montpellier 2, Montpellier, F34095 Cedex 05
D. Leclercq
Affiliation:
UMR CNRS 5637, cc 007, Université Montpellier 2, Montpellier, F34095 Cedex 05
P. H. Mutin
Affiliation:
UMR CNRS 5637, cc 007, Université Montpellier 2, Montpellier, F34095 Cedex 05
R. J. P. Corriu
Affiliation:
UMR CNRS 5637, cc 007, Université Montpellier 2, Montpellier, F34095 Cedex 05
A. Vioux
Affiliation:
UMR CNRS 5637, cc 007, Université Montpellier 2, Montpellier, F34095 Cedex 05
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Abstract

A nonhydrolytic sol-gel method was used to incorporate siloxane and cyclotriphosphazene units within metal oxides. The degree of mixing of the components was investigated by EDX, XPS, and 29Si and 31P solid-state NMR. The NMR data confirmed the presence of Si-O-M and PO- M bonds.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 51
Copyright
Copyright © Materials Research Society 1998

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