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Moisture Effects in the Conducting Polymer, Polyaniline

Published online by Cambridge University Press:  25 February 2011

J. P. Travers ,
C. Menardo ,
M. Nechtschein ,
S. K. Manohar  and
A. G. MacDiarmid
J. P. Travers
Affiliation:
DRF/SPh/DSPE (UPR CNRS 216), Centre d’Etudes Nucléaires de Grenoble, 85 X, 38041 Grenoble-Cédex, (FRANCE)
C. Menardo
Affiliation:
DRF/SPh/DSPE (UPR CNRS 216), Centre d’Etudes Nucléaires de Grenoble, 85 X, 38041 Grenoble-Cédex, (FRANCE)
M. Nechtschein
Affiliation:
DRF/SPh/DSPE (UPR CNRS 216), Centre d’Etudes Nucléaires de Grenoble, 85 X, 38041 Grenoble-Cédex, (FRANCE)
S. K. Manohar
Affiliation:
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, (USA)
A. G. MacDiarmid
Affiliation:
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, (USA)
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Abstract

Water content as well as conductivity have been measured as a function of water vapour pressure on polyaniline and poly-N-methylaniline samples. It is shown that i) absorption is governed by the acid protons of the polymers and ii) enhancement of conductivity needs the existence of protonated imines. It is concluded that moisture favours conductivity through an increase of the interchain transfers.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 173: Symposium Q – Advanced Organic Solid State Materials , 1989 , 335
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. de Surville, R., Josefowicz, M., Yu, L.T., Perichon, J. and Buvet, R. Electrochim. Acta 13, 1451 (1968)Google Scholar
2. Travers, J.P., Chroboczek, J., Devreux, F., Genoud, F., Nechtschein, M., Syed, A., Genies, E.M. and Tsintavis, C., Mol. Cryst. Liq. Cryst. 121, 195 (1985)CrossRefGoogle Scholar
3. Chiang, J.C. and MacDiarmid, A.G., Synth. Met. 13, 193 (1986)Google Scholar
4. Epstein, A.J., Ginder, J.M., Zuo, F., Bigelow, R.W., Woo, H.S., Tanner, D.B., Richter, A.F., Huang, W.S. and MacDiarmid, A.G., Synth. Met. 18, 303 (1987) ;Google Scholar
Ginder, J.M., Richter, A.F., MacDiarmid, A.G. and Epstein, A.J., Sol. St. Comm. 63, 97 (1987)Google Scholar
5. Hemle, M., Mayer, C., Mehring, M., Nechtschein, M. and Pron, A. in Electronic Properties of Conjugated Polymers, ed. by Kuzmany, H., Roth, S., Mehring, M. (Springer Verlag, 1989)Google Scholar
6. Nechtschein, M., Genoud, F., Menardo, C., Mizoguchi, K., Travers, J.P. and Villeret, B., Synth. Met 29, E 211 (1989)CrossRefGoogle Scholar
7. Mizoguchi, K., Nechtschein, M., Travers, J.P. and Menardo, C. Phys. Rev. Lett. 63, 66 (1989)CrossRefGoogle Scholar
8. Nechtschein, M., Santier, C., Travers, J.P., Chroboczek, J., Alix, A. and Ripert, M., Synth. Met 18, 311 (1987)Google Scholar
9. Javadi, H.H.S., Angelopoulos, M., MacDiarmid, A.G. and Epstein, A.J. Synth. Met 26, 1 (1988)Google Scholar
10. Travers, J.P. and Nechtschein, M., Synth. Met 21, 135 (1987)Google Scholar
11. Focke, W.W., Wnek, G.E. and Wei, Y., J. Phys. Chem. 91, 5813 (1987)Google Scholar
12. MacDiarmid, A.G., Chiang, J.C., Richter, A.F., Somanisi, N.L.D., Epstein, A.J. in Conducting Polymers, ed. by Alcacer, L. (Reidel Pub, Dordrecht, Holland, 1987) p 107 Google Scholar
13. Manohar, S.K., MacDiarmid, A.G., Cromack, K.R., Ginder, J.M. and Epstein, A.J., Synth. Met. 29, E 349 (1989)Google Scholar
14. Alix, A., Lemoine, V., Nechtschein, M., Travers, J.P. and Menardo, C. Synth. Met 29, E 457 (1989)Google Scholar
15. Alix, A., Thesis, Grenoble (1989)Google Scholar
16. Menardo, C., Nechtschein, M., Rousseau, A. and Travers, J.P. Synth. Met 25, 311 (1988)Google Scholar