Hostname: page-component-76fb5796d-2lccl Total loading time: 0 Render date: 2024-04-30T03:09:27.543Z Has data issue: false hasContentIssue false

Phase Equilibria among γ-Fe, γ-Fe and Fe2Mo Phases and Stability of the Laves Phase in Fe-Mo-Ni Ternary System at Elevated Temperatures

Published online by Cambridge University Press:  26 February 2011

Shigehiro Ishikawa
Affiliation:
ishikawa_shigehiro@mtl.titech.ac.jp, Tokyo Institute of Technology, Metallurgy and Ceramics Science, 2-12-1 Ookayama, Meguro-ku, Tokyo, 152-8552, Japan, 81-3-5734-3133, 81-3-5734-2801
Takashi Matsuo
Affiliation:
tmatsuo@mtl.titech.ac.jp, Tokyo Institute of Technology, Metallurgy and Ceramics Science, S8-8, 2-12-1 Ookayama, Meguro-ku, Tokyo, 152-8552, Japan
Masao Takeyama
Affiliation:
takeyama@mtl.titech.ac.jp, Tokyo Institute of Technology, Metallurgy and Ceramics Science, S8-8, 2-12-1 Ookayama, Meguro-ku, Tokyo, 152-8552, Japan
Get access

Abstract

Phase equilibria among the bcc Fe(α), fcc Fe(γ) and Fe2Mo(λ)_phases in Fe-Mo-Ni ternary system, particularly paying attention to the existence of the γ+λ two-phase region, have been examined at elevated temperatures below Tc (1200 K), the peritectoid reaction temperature in Fe-Mo binary system: λ?α+Fe7Mo6 (μ). At 1173 K the α+γ+μ three-phase coexisting region exists near the Fe-Mo binary edge and no λ phase region was identified. At 1073 K the λ phase in equilibrium with α and γ phases exists, although the composition homogeneity region of the ternary λ phase was limited to its binary edge toward the equi-nickel concentration direction up to about 3at % Ni. Instead, large two-phase region of γ+μ was extended along the same direction up to 20 at% Ni. The γ+λ two-phase region appears below Tc through a transition peritectoid reaction: α+μ¨γ+λ. The γ phase in equilibrium with λ phase is stable only at elevated temperatures, and it transforms martensitically to α phase during cooling. The addition of Ni stabilizes γ and μ phases against α and λ phases, thereby decreasing the relative stability of the λ phase.

Type
Research Article
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Takeyama, M., Kinzoku, 76, 743 (2006).Google Scholar
2. Takeyama, M., Gomi, N., Morita, S., and Matsuo, T., Mater. Res. Soc. Symp., 842, 461 (2006).Google Scholar
3. Gomi, N., Morita, S., Matsuo, T., Takeyama, M., Report of JSPS 123rd Committee on Heat-Resisting Materials and Alloys, 45, 157 (2004).Google Scholar
4. Oikawa, H., Technology Reports, Tohoku University, 47, 215 (1982).Google Scholar
5. Fernandez, A., Bulletin of Alloy Phase Diagram, 3, 359 (1982).Google Scholar
6. Okamoto, H., Desk Handbook: Phase Diagrams for Binary Alloys, 367 (2000).Google Scholar
7. Raynor, G. V., Rivlin, V. G., Phase Equilibria in Iron Ternary Alloys, 4, 392 (1988).Google Scholar
8. Van Loo, F. J. J., Bastin, G. F., Vrolijk, J. W. G. A., Hendriks, J. J. M., Journal of Less-Common Metals, 72, 225 (1980).Google Scholar
9. Takeyama, M., Yokota, H., Ghanem, M. M. and Matsuo, T., Journal of Materials Processing Technology, 117, 3 (2001).Google Scholar