Hostname: page-component-54dcc4c588-gwv8j Total loading time: 0 Render date: 2025-09-16T08:18:13.075Z Has data issue: false hasContentIssue false
  • English
  • Français

The Preparation of III-V Semiconductors in Aqueous Solution

Published online by Cambridge University Press:  21 February 2011

Toby J. Cumberbatch  and
Andrew Putnis
Toby J. Cumberbatch
Affiliation:
Department of Engineering, University of Cambridge, Trumpington Street, Cambridge CB2 1PZ, England
Andrew Putnis
Affiliation:
Department of Earth Sciences, University of Cambridge, Cambridge CB2 3EQ, England
Get access

Abstract

Indium arsenide colloids have been prepared by passing arsine through an aqueous solution of the metal nitrate. Similar experiments with gallium solutions produced an extremely fine precipitate which has been tentatively identified as amorphous gallium arsenide. Attempts to precipitate aluminium arsenide from aqueous solutions or mixed organic solvent systems were unsuccessful. The materials were characterised by transmission electron microscopy, X-ray powder diffraction and and optical absorption spectroscopy.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 164: Symposium H – Materials Issues in Microcrystalline Semiconductors , 1989 , 129
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

1. Cotton, F.A. and Wilkinson, G., Advanced Inorganic Chemistry, 5th ed. (Wiley Interscience, New York, 1988) p. 391.Google Scholar
2. Brukl, A. Z. Anorg. Chem. 131, 236 (1923)Google Scholar
3. Naud, J. and Priest, P. Mat. Res. Bull. 2, 337 (1974)Google Scholar
4. Kulifay, S.M. J. Am. Chem. Soc. 83, 4916 (1961)Google Scholar
5. Stahl, H.A. U.S. Patent No. 3 925 698 (1975)Google Scholar
6. Weast, R.C., CRC Handbook of Chemistry and Physics, 68th ed. (CRC Press Inc., Boca Raton, 1987) p. D-163.Google Scholar
7. Burgess, J., Metal Ions in Solution, (Ellis Horwood, Chichester, 1978) p. 317.Google Scholar
8. Moser, L. and Brukl, A. Monatsh. 45, 25 (1924)Google Scholar
9. Mahavadi, K.K., Ph.D. Thesis, University of Cambridge, 1985.Google Scholar
10. Paul, W., Moustakas, T.D., Anderson, D.A. and Freeman, E., in 7th Int. Conf. on Liguid and Amorphous Semiconductors, ed. by Spicer, W.E. (CICL Univ., Edinburgh, 1977) p. 467 Google Scholar
11. Rosetti, R. and Brus, L. J. Phys. Chem. 86, 4470 (1982)Google Scholar