Hostname: page-component-76fb5796d-vfjqv Total loading time: 0 Render date: 2024-04-30T02:02:34.948Z Has data issue: false hasContentIssue false

Sol-Gel Synthesis of Ceramic-Organic Nano Composites

Published online by Cambridge University Press:  15 February 2011

Helmut K. Schmidt*
Affiliation:
Institut für Neue Materialien, Im Stadtwald, Bldg. 43, D-6600 Saarbrücken 11, Federal Republic of Germany
Get access

Abstract

Sol-gel synthesis can be used for generating nano particles from a variety of compositions. In order to avoid aggregation and undesired gelation, it is necessary to react the particle surfaces with ligands reducing their interaction but allowing the incorporation into desired matrices. Three examples (semiconducting and metal quantum dots, ZrO2 and Al2O3 containing composites) are described, their properties and some applications for optics and protective coatings are discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Wilkes, G. L., Orler, B. and Huang, H. H., Polym. Prepr 26, 300 (1985).Google Scholar
[2] Garrido, L., Ackermann, J. L., Mark, J. E., Mat. Res. Soc. Symp. Proc. 171, 65 (1990).CrossRefGoogle Scholar
[3] Schmidt, H., in Chemical Processing of Advanced Materials; edited by Hench, L. L. and West, J. K. (J. Wiley & Sons, New York, 1992).Google Scholar
[4] Novak, B. M. and Davies, C., Polym. Prepr. 32, 512 (1991).Google Scholar
[5] Landry, C. J. T. and Coltrain, B. K., Polym. Prepr. 32, 514 (1991).Google Scholar
[6] Huang, H. H., Orler, B. and Wilkes, G. L., Polym. Bull. 14, 557 (1985).CrossRefGoogle Scholar
[7] Huang, H. H., Orler, B. and Wilkes, G. L., Macromolecules 20, 1322 (1987).CrossRefGoogle Scholar
[8] Brennan, A. B. and Wilkes, G. L., Polymer 32, 733 (1991).CrossRefGoogle Scholar
[9] Sanchez, C., in Proc. 6th International Workshop on Glasses and Ceramics from Gels, October 1991, Sevilla/Spain, edited by Esquivias, L. (J. Non-Cryst. Solids), in print.Google Scholar
[10] Mackenzie, J. D., in: Proc. 6th International Workshop on Glasses and Ceramics from Gels, October 1991, Sevilla/Spain edited by Esquivias, L. (J. Non-Cryst. Solids), in print.Google Scholar
[11] Prasad, P. N., in: SPIE Vol. 1328 Sol-Gel Optics, edited by Mackenzie, J. D. and Ulrich, D. R. (SPIE, Bellingham/Washington, 1990), p. 168.Google Scholar
[12] Schmidt, H., Seiferling, B., Philipp, G. and Deichmann, K., in: Ultrastruacture of Processing of Advanced Ceramics, edited by Mackenzie, J. D. and Ulrich, D. R. (John Wiley & Sons, New York, 1988), p. 651.Google Scholar
[13] Teowee, G., Boulton, J. M., Fox, H. H., Koussa, A., Gudgel, T. and Uhlmann, D. R., Mat. Res. Soc. Symp. Proc. 180 (1980).Google Scholar
[14] Schmidt, H., Mat. Res. Soc. Symp. Proc. 171, 3 (1990).CrossRefGoogle Scholar
[15] Schmidt, H., Scholze, H. and Tinker, G., J. Non-Cryst. Solids 80, 557 (1986).CrossRefGoogle Scholar
[16] Naß, R. and Schmidt, H., in: Ceramic Powder Processing Science, edited by Hausner, H., Messing, G. L. and Hirano, S. (Deutsche Keramische Gesellschaft, Köln), p. 69.Google Scholar
[17] Schmidt, H., Mater. Res. Soc. Symp. Proc. 32, 327 (1984).CrossRefGoogle Scholar
[18] Krug, H. and Schmidt, H., in: Proc. Workshop “Integrated Optics and Microoptics with polymers”, Mainz/FRG, March 1992 (in print).Google Scholar
[19] Klein, L. C. and Abramoff, B., Polym. Prepr. 32, 519 (1991).Google Scholar
[20] Dunn, B. S., Mackenzie, J. D., Zink, J. I., Stafsudd, O. M., in: SPIE Vol. 1328 Sol-Gel optics, edited by Mackenzie, J. D. and Ulrich, D. R., 1990, p. 174.Google Scholar
[21] Okada, A., Fukumori, K., Usuki, A., Kojima, Y., Sato, N., Kurauchi, T. and Kamigaito, O., Polym. Prepr. 32, 540 (1991).Google Scholar
[22] Schmidt, H., in: Proceedings of the International Symposium on Molecular Level Designing of Ceramics; edited by the Team of the NEDO International Joint Research Program, Nagoya, 1991, p. 59.Google Scholar
[23] Schmidt, H., Krug, H. and Merl, N., Rivista della Staz. Sper. Vetro 23, 11 (1992).Google Scholar
[24] Henglein, A., Topics in Current Chemistry: Mechanism of reactions on colloidal microelectrodes and size quantization effects 143, 115 (1988).Google Scholar
[25] Li, C., Chung, Y. J., Mackenzie, J. D. and Knobbe, E. T., presented at Amer. Cer. Soc. Optical Materials Symposium, October 1991, Washington/USA.Google Scholar
[26] Fukomi, K., Chayahara, A., Kadono, K., Sakaguchi, T., Horino, Y., Hayakawa, J. and Satou, M., Jpn. J. Appl. Phys. 30, L 742 (1991).CrossRefGoogle Scholar
[27] Spanhel, L., Arpaq, E. and Schmidt, H., in: Proc. 6th International Workshop on Glasses and Ceramics from Gels, edited by L. Esquivias (J. Non-Cryst. Solids) in print.Google Scholar
[28] Spanhel, L., Schmidt, H., Uhrig, A. and Klingshirn, C., in: Proc. MRS Spring Meeting 1992, San Francisco (Mat. Res. Soc. Symp. Proc.) in print.Google Scholar
[29] Spanhel, L., Mennig, M. and Schmidt, H., in: Proc. ICG Congress on Glass, Madrid, Oktober 1992, accepted for publication.Google Scholar
[30] Lintner, B., Arfsten, N. and Dislich, H., J. Non-Cryst. Solids 100, 378 (1988).Google Scholar
[31] Sanchez, C., in: Proc. 2nd Eurogel Conf., June 1991, Saarbracken, North Holland Publishers (in print).Google Scholar
[32] Rinn, G. und Schmidt, H., in: Ceramic Powder Processing Science, edited by Hausner, H., Messing, G. L. and Hirano, S. (Deutsche Keramische Gesellschaft, Köln), p. 221Google Scholar
[33] Schmidt, H., Krug, H. and Kasemann, R., in: Homage to Galileo, edited by Mazzoldi, P. (Università di Padova, 1992) p. 303.Google Scholar
[34] Wilhelm, R. and coworkers, , private communication.Google Scholar
[35] Schmidt, H., Krug, H., Kasemann, R., Tiefensee, F., in: SPIE Vol. 1590 Submolecular Glass Chemistry and Physics, edited by Kreidl, N. (SPIE Bellingham/Washington, 1991) p. 36.Google Scholar
[36] Oliveira, P. and Krug, H., private communication.Google Scholar
[37] Annual report of Fraunhofer-Institut für Silicatforschung, 1990, p. 55.Google Scholar
[38] Wagner, G., Master's Thesis, Saarbrücken 1992.Google Scholar
[39] Fedtke, M., Makromol. Chem., Macromol Symp. 2 153 (1987).Google Scholar