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Structural Requirements for Surface-Induced Aromatic Stabilization

Published online by Cambridge University Press:  28 March 2014

Takuya Hosokai ,
Keiichirou Yonezawa ,
Kengo Kato ,
Rintaro Makino ,
Jinpeng Yang ,
Kaveenga Rasika Koswattage ,
Alexander Gerlach ,
Frank Schreiber ,
Nobuo Ueno  and
Satoshi Kera
Takuya Hosokai
Affiliation:
Department of Materials Science and Technology, Iwate University, 4-3-5 Ueda, Morioka, 0208551 Iwate, JAPAN
Keiichirou Yonezawa
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Kengo Kato
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Rintaro Makino
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Jinpeng Yang
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Kaveenga Rasika Koswattage
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Alexander Gerlach
Affiliation:
Institut für Angewandte Physik, Universität Tübingen, Auf der Morgenstelle 10, Tübingen 72076, GERMANY
Frank Schreiber
Affiliation:
Institut für Angewandte Physik, Universität Tübingen, Auf der Morgenstelle 10, Tübingen 72076, GERMANY
Nobuo Ueno
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
Satoshi Kera
Affiliation:
Department of Nanomaterial Science, Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, 2638522 Chiba, JAPAN
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Abstract

Surface-induced aromatic stabilization (SIAS), a recently proposed mechanism leading to a formation of charge-transfer (CT) states at organic/metal (O/M) interfaces [G. Heimel, et al., Nat. Chem.5, 187 (2013)], was investigated for an aromatic hydrocarbon, diindenoperylene (DIP), by means of synchrotron radiation-based ultraviolet photoelectron spectroscopy (UPS). By employing DIP and noble metal substrates (Ag and Cu), we confirmed the formation of CT states, indicating that an inclusion of a specific functional group with a hetero-atom within adsorbate molecules as suggested before is not necessarily required for the formation of CT states mediated by the SIAS. With a comparison of the mother and analogue molecules, perylene and PTCDA, we discuss the structural requirement for the realization of the SIAS.

Keywords

adsorptionphotoemissionsurface chemistry

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Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1647: Symposium GG – Surface/Interface Characterization and Renewable Energy , 2014 , mrsf13-1647-gg01-03
Copyright
Copyright © Materials Research Society 2014 

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