Hostname: page-component-76fb5796d-22dnz Total loading time: 0 Render date: 2024-04-26T19:48:30.639Z Has data issue: false hasContentIssue false
  • English
  • Français

Atomic Scale Structure and Chemistry of Interfaces by Z-Contrast Imaging and Electron Energy Loss Spectroscopy in the Stem

Published online by Cambridge University Press:  15 February 2011

M. M. McGibbon ,
N. D. Browning ,
M. F. Chisholm ,
A. J. McGibbon ,
S. J. Pennycook ,
V. Ravikumar  and
V. P. Dravid
M. M. McGibbon
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831–6031, USA
N. D. Browning
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831–6031, USA
M. F. Chisholm
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831–6031, USA
A. J. McGibbon
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831–6031, USA
S. J. Pennycook
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831–6031, USA
V. Ravikumar
Affiliation:
Northwestern University, Department of Materials Science and Engineering, Evanston, IL 60208, USA
V. P. Dravid
Affiliation:
Northwestern University, Department of Materials Science and Engineering, Evanston, IL 60208, USA
Get access

Abstract

The macroscopic properties of many materials are controlled by the structure and chemistry at grain boundaries. A basic understanding of the structure-property relationship requires a technique which probes both composition and chemical bonding on an atomic scale. High-resolution Z-contrast imaging in the scanning transmission electron microscope (STEM) forms an incoherent image in which changes in atomic structure and composition across an interface can be interpreted directly without the need for preconceived atomic structure models (1). Since the Z-contrast image is formed by electrons scattered through high angles, parallel detection electron energy loss spectroscopy (PEELS) can be used simultaneously to provide complementary chemical information on an atomic scale (2). The fine structure in the PEEL spectra can be used to investigate the local electronic structure and the nature of the bonding across the interface (3). In this paper we use the complimentary techniques of high resolution Zcontrast imaging and PEELS to investigate the atomic structure and chemistry of a 25° symmetric tilt boundary in a bicrystal of the electroceramic SrTiO3.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 341: Symposium F – Epitaxial Oxide Thin Films and Heterostructures , 1994 , 139
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

(1) Pennycook, S.J. and Jesson, D.E., Phys.Rev.Lett, 64, 938, (1990)CrossRefGoogle Scholar
(2) Browning, N.D., et al Nature, 366, 143 (1993)Google Scholar
(3) Batson, P.E., Nature, 366,727 (1993)CrossRefGoogle Scholar
(4) Pennycook, S.J. and Jesson, D.E., Ultramicroscopy, 37, 14, (1991)Google Scholar
(5) Pennycook, S.J., Annu. Rev. Mater. Sci., 22, 171, (1992)Google Scholar
(6) Pennycook, S.J., Contemp.Phys, 23, 371 (1982)CrossRefGoogle Scholar
(7) Browning, N.D. and Pennycook, S.J., Microbeam Analysis, 2, 81, (1993)Google Scholar
(8) Batson, P.E., Ultramicroscopy, 47, 133 (1992)Google Scholar
(9) Gull, S.F. and Skilling, J., IEE Proc, 13IF, 646 (1984)Google Scholar
(10) Grunes, L.A. et al, Phys.Rev.B, 25, 7157 (1982)Google Scholar
(11) Brydson, R., Sauer, H. and Engel, W., Transmission Electron Energy Loss Spectrometry in Materials Science (The Minerals, Metals and Materials Society) 1992 Google Scholar
(12) Paterson, J.H. and Krivanek, O.L., Ultramicroscopy, 32, 319 (1990)Google Scholar
(13) Otten, M.T. et al, Ultramicroscopy, 18, 285, (1985)Google Scholar
(14) Brydson, R. et al, J.Phys:Condens.Matter, 4, 3429 (1992)Google Scholar
(15) Altermatt, D. and Brown, I.D., Acta Cryst, B41, 240 (1985)Google Scholar
(16) Brown, I.D. and Altermatt, D., Acta Cryst, B41, 244 (1985)Google Scholar