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Charge Carrier Transport in the Bulk and at the Surface of Nanoparticles: A Quasi-Solid-State Dye-Sensitized Solar Cell

Published online by Cambridge University Press:  01 February 2011

Dennis Friedrich
Affiliation:
friedrich@helmholtz-berlin.de, Helmholtz-Zentrum Berlin für Materialien und Energie, Institute Solar Fuels, Berlin, Germany
Marinus Kunst
Affiliation:
kunst@helmholtz-berlin.de, Helmholtz-Zentrum Berlin für Materialien und Energie, Institute Solar Fuels, Berlin, Germany
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Abstract

A quasi-solid-state dye-sensitized solar cell is presented, where the conventional liquid electrolyte is replaced by an electrolyte film, reaching a solar light-to-current conversion efficiency of 3%. Contactless transient photoconductance measurements were performed, revealing decay behavior of photoinduced charge carriers, dependent on external applied potential conditions. The measurements show that the decay is controlled by the injection of electrons into the front contact, hindered or enhanced by the field in the space charge region.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1 O'Regan, B. and Grätzel, M. Gr, Nature, 353 737740 (1991).Google Scholar
2 Sommeling, P.M., O'Regan, B.C., Haswell, R.R., Smit, H.J.P., Bakker, N.J., Smits, J.J.T., Kroon, J.M., and Roosmalen, J.A.M. van, J. Phys.Chem. B 110 1919119197 (2006).Google Scholar
3 Kunst, M. and Beck, G., J. Appl. Phys. 60, 35583566 (1986).Google Scholar
4 Swiatkowski, C., Sanders, A., Buhre, K., and Kunst, M. Ku, J. Appl. Phys. 78, 17631775 (1995).Google Scholar
5 Kunst, M., Goubard, F., Colbeau-Justin, C. Colbeau, and Wünsch, F., Mater. Sci. Eng., C 27, 10611064 (2007).Google Scholar