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Conversion of an Aurivillius Phase Bi2SrNaNb3O12 into Its Protonated Form via Treatment with Various Mineral Acids

  • Masashi Shirata (a1), Yu Tsunoda (a1), Wataru Sugimoto (a2) and Yoshiyuki Sugahara (a1)

A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi2SrNaNb3O12 via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H1.8[Sr0.8Bi0.2NaNb3O10], while no reactions were observed for HNO3 and H2SO4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

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