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Conversion of an Aurivillius Phase Bi2SrNaNb3O12 into Its Protonated Form via Treatment with Various Mineral Acids

  • Masashi Shirata (a1), Yu Tsunoda (a1), Wataru Sugimoto (a2) and Yoshiyuki Sugahara (a1)
Abstract

A protonated form of a layered perovskite was prepared from an Aurivillius phase Bi2SrNaNb3O12 via acid treatments, and the effect of the type of mineral acids was investigated. The treatment with HX (X = Cl, Br, I) resulted in the formation of a protonated form H1.8[Sr0.8Bi0.2NaNb3O10], while no reactions were observed for HNO3 and H2SO4 under the present experimental conditions. All the products obtained by HX-treatments exhibited layered structures and the structures of the perovskite-like slabs were preserved.

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1.Gopalakrishnan, J., Rev. Solid State Sci. 1, 515 (1988).
2.Dion, M., Ganne, M. and Tournoux, M., Mater. Res. Bull. 16, 1429 (1981).
3.Jacobson, A. J., Johnson, J. W. and Lewandowski, J. T., Inorg. Chem. 24, 3727 (1985).
4.Ruddlesden, S. N. and Popper, P., Acta Crystllogr. 10, 538 (1957).
5.Ruddlesden, S. N. and Popper, P., Acta Crystllogr. 11, 54 (1958).
6.Gopalakrishnan, J., Bhat, V. and Raveau, B., Mater. Res. Bull. 22, 413 (1987).
7.Dion, M., Ganne, M. and Tournoux, M., Rev. Chim. Miner. 23, 61 (1986).
8.Jacobson, A. J., Lewandowski, J. T. and Johnson, J. W., J. Less-Common Met. 116, 137 (1986).
9.Ebina, Y., Tanaka, A., Kondo, J. N. and Domen, K., Chem. Mater. 8, 2534 (1996).
10.Subramanian, M. A., Gopalakrishnan, J. and Sleight, A. W., Mater. Res. Bull. 23, 837 (1988).
11.Jacobson, A. J., Johnson, J. W. and Lewandowski, J. T., Mater. Res. Bull. 22, 45 (1987).
12.Olivier, P. J. and Mallouk, T. E., Chem. Mater. 10, 2585 (1998).
13.Rao, C. N. R. and Raveau, B., Transition Metal Oxide, 2nd edition, (Wiley-VCH, 1998) pp.74-75.
14.Suzuki, M., Nagasawa, N., Machida, A. and Ami, T., Jpn. J. Appl. Phys. 35, L564 (1996).
15.Sugimoto, W., Shirata, M., Sugahara, Y. and Kuroda, K., J. Am. Chem. Soc. 121, 11601 (1999).
16.Gopalakrishnan, J., Sivakumar, T., Ramesha, K., Thangadurai, V. and Subbanna, G. N., J. Am. Chem. Soc. 122, 6237 (2000).
17., Ismunandar and Kennedy, B. J., J. Solid State Chem. 126, 135 (1996).
18.Izumi, F., Rietveld Analysis Programs RIETAN and PREMOS and Special Applications, Rietveld Analysis, ed. Young, R. A., (Oxford University Press, 1993) pp.236253.
19.Kim, Y. I. and Izumi, F., J. Ceram. Soc. Jpn. 102, 401 (1994).
20.Blake, S. M., Falconer, M. J., McCreedy, M. and Lightfoot, P., J. Mater. Chem. 7, 1609 (1997).
21.Bleza, M. A., Morando, P. J. and Regazzoni, A. E., Chemical Dissolution of Metal Oxides, (CRC Press, 1994) pp.172177.
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