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Dielectric Friction in Restricted Geometries

Published online by Cambridge University Press:  25 February 2011

M. Urbakh
Affiliation:
School of Chemistry, Tel-Aviv University, 69978, Ramat-Aviv, Tel-Aviv, Israel
J. Klafter
Affiliation:
School of Chemistry, Tel-Aviv University, 69978, Ramat-Aviv, Tel-Aviv, Israel
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Abstract

The influence of a solid-liquid interface on the relaxation of a point dipole embedded in the liquid side is discussed. The dielectric friction of a dipole as a function of its distance from a boundary is calculated. The calculations are carried out assuming a nonlocal dielectric function of the liquid, characterized by a typical correlation length which may depend on temperature. The corrections to the relaxation of a dipole due to the presence of a boundary are shown to be small. Larger corrections can be introduced by postulating structural changes in the nature of the liquid near the boundary.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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