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Different Solvent Free Synthetic Routes to Organic/Inorganic Hybrid Materials

Published online by Cambridge University Press:  10 February 2011

H. Kaddami ,
J. F. Gerard  and
J. P. Pascault
H. Kaddami
Affiliation:
Laboratoire des Matériaux Macromoléculaires, Bâtiment 403, UMR 5627, 20 avenue Albert Einstein, 69621 Villeurbanne Cedex, France, pascault@insa-Iyon.fr Université Cadi Ayyad, FSTG, BP 618, Gueliz, Marrakech, Marocco
J. F. Gerard
Affiliation:
Laboratoire des Matériaux Macromoléculaires, Bâtiment 403, UMR 5627, 20 avenue Albert Einstein, 69621 Villeurbanne Cedex, France, pascault@insa-Iyon.fr
J. P. Pascault
Affiliation:
Laboratoire des Matériaux Macromoléculaires, Bâtiment 403, UMR 5627, 20 avenue Albert Einstein, 69621 Villeurbanne Cedex, France, pascault@insa-Iyon.fr
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Abstract

The sol-gel chemistry in low-temperature conditions can be used to produce organicinorganic materials nanocomposite from the in-situ formation of silica-rich phase in a polymer matrix. Different synthetic routes have been proposed: i) hydrolysis and condensation reactions of silane end capped oligomers, ii) polymerization of hydroxyethyl methacrylate, HEMA in presence of preformed functionalized silica nanoparticles, and iii) simultaneous hydrolysis and condensation of tetraethoxysilane and polymerization of hydroxyethymeth-acrylate.

Rheological investigations made during the polymerization of these three systems display many differences. Time for gelation was chosen as the time at which the loss factor, tanδ is independent on the testing frequency, or the time at which the system displays an elastic response. Vitrification phenomenon is associated with a tanδ peak. In some cases vitrification of the inorganic-rich phase interfered with the observation of gelation and the appearance of a non soluble fraction in a good solvent like tetrahydrofurane can help for attribution.

During radical chain-polymerization of HEMA a classical Trommsdorff-effect was observed. It can be at the same time than the macrogelation in the case of neat HEMA or delayed by the presence of grafted SiO2 nanoparticles. During simultaneous synthesis of inorganic and organic phases, vitrification of the inorganic-rich phase occured just after macrogelation of the system.

Final morphologies are strongly dependent on the occurrence of these different structural transformations.

Keywords

Hybrid chemistryphase separationgelationvitrificationTrommsdorff-effect
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 51
Copyright
Copyright © Materials Research Society 1999

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References

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