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Electrochemical Synthesis and Characterization of NaCuO2

Published online by Cambridge University Press:  21 February 2011

Gerald L. Roberts  and
Susan M. Kauzlarich
Gerald L. Roberts
Affiliation:
Department of Chemistry, University of California, Davis, CA 95616 Chemistry and Materials Science Department, University of California, Lawrence Livermore National Laboratory Livermore, CA 94550
Susan M. Kauzlarich
Affiliation:
Department of Chemistry, University of California, Davis, CA 95616
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Abstract

NaCuO2 has been prepared via electrodeposition from a sodiumhydroxide/potassium hydroxide melt and characterized by single crystal andpowder X-ray diffraction, magnetic susceptibility, and resistivity. Clustersof blue-black plate-like and needle crystals are grown at positivepotentials on a platinum anode with a platinum or a zirconium crucibleserving as the cathode and a platinum reference electrode. Details of theelectrochemical procedure are described, along with a cyclic voltammogram. NaCuO2 exhibits temperature independent paramagnetism over thetemperature range 30 – 300 K. Its room temperature resistivity is greaterthan 106 Ω-cm.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 346: Symposium N – Better Ceramics Through Chemistry VI , 1994 , 457
Copyright
Copyright © Materials Research Society 1998

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References

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