Hostname: page-component-848d4c4894-75dct Total loading time: 0 Render date: 2024-05-09T01:20:55.523Z Has data issue: false hasContentIssue false
  • English
  • Français

High-Pressure, High-Temperature Synthesis of Superhard Boron Suboxide

Published online by Cambridge University Press:  10 February 2011

H. Hubert ,
L. A. J. Garvie ,
K. Leinenweber ,
P. R. Buseck ,
W. T. Petuskeyt  and
P. F. McMillan
H. Hubert
Affiliation:
Materials Research Group in High Pressure Synthesis, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604.
L. A. J. Garvie
Affiliation:
Department of Geology, Arizona State University, Tempe, AZ 85287-1404.
K. Leinenweber
Affiliation:
Materials Research Group in High Pressure Synthesis, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604.
P. R. Buseck
Affiliation:
Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604.
W. T. Petuskeyt
Affiliation:
Materials Research Group in High Pressure Synthesis, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604.
P. F. McMillan
Affiliation:
Materials Research Group in High Pressure Synthesis, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287-1604.
Get access

Abstract

A multianvil device was used to investigate the formation of BxO phases produced in the 2 to 10 GPa pressure range with temperatures between 1000 and 1800 °C.Amorphous and crystalline B and BP were oxidized using B2O3 and CrO3. Using powder X-ray diffraction and parallel electron energy-loss spectroscopy (PEELS), we were unable to detect graphitic or diamondstructured B2O, reported in previous studies. The refractory boride B6O, which has the α-rhombohedral boron structure, is the dominant suboxide in the P and T range of our investigation. PEELS with a transmission electron microscope was used to characterize the boron oxides.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 410: Symposium S – Covalent Ceramics III-Science and Technology of Non-Oxides , 1995 , 191
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Bundy, F.P., Hall, H. Tracy, Strong, H.M., and Wentorf, R.H., Nature 176, 51 (1955).Google Scholar
2. Hall, H. Tracy and Compton, L.A., Inorg. Chem. 4, 1213 (1965).Google Scholar
3. Boron Oxide Having a Structure Similar to the Diamond Structure and Method, Patent, Japan Kokai Tokyo Koho, No 60-21812 (1985).Google Scholar
4. Endo, T., Sato, T., and Shimada, M., J. Mater. Sci. Lett. 6, 683 (1987)Google Scholar
5. Grumbach, M.P., Sankey, O.F., and McMillan, P.F., Phys. Rev. B, (in press).Google Scholar
6. Higashi, I., in Boron-Rich Solids, vol.140, A.I.P Conference and Proceedings (1986), pp. 1–10.Google Scholar
7. Srikanth, V., Roy, R., Graham, E.K., and Voigt, D.E., J. Am. Ceram. Soc. 74 (12), 3145–47 (1991).Google Scholar
8. Leinenweber, K. and Parise, J., J. Solid State Chem. 114, 277–281 (1985).Google Scholar
9. Garvie, L.A.J., Rev. Mineral. 33 (in press).Google Scholar
10. Garvie, L.A.J., Buseck, P.R. and Craven, A.J., Can. Mineral., 33 (in press).Google Scholar
11. Garvie, L.A.J., Brydson, R. and Craven, A.J., Am. Mineral, 80 (in press).Google Scholar
12. Pasternak, R.A., Acta Crystallogr., 12, 612–13 (1959).Google Scholar
13. Badzian, A.R., Appl. Phys. Lett., 53 (25), 2495–97 (1988).Google Scholar
14. LaPlaca, S. and Post, B., Planseeber. Pulvermet. 9, 109–112 (1961).Google Scholar
15. Rizzo, H.F., Simmons, W.C., and Bielstein, H.O., J. Electrochem. Soc. 109, 1079–82 (1962).Google Scholar
16. Petrak, D.R., Rub, R., and Goosey, B.F., in Proceedings of the 5th Materials Research Symposium, NBS Spec. Pub. 364, July 1972, pp. 605–611.Google Scholar
17. Kobayashi, M., Higashi, I., Brodhag, C., Thévenot, F., J. Mat. Sci. 28 (8), 2129–34 (1993).Google Scholar
18. Gurr, G.E., Montgomery, P.W., Knutson, C.D. and Gorres, B.T., Acta Cryst. B, 26, 906–915 (1970).Google Scholar
19. Prewitt, C.T. and Shannon, R.D., Acta Cryst. B, 24, 868–874 (1968).Google Scholar
20. Senkovits, Hawley (private communication).Google Scholar