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The Initial Stages of Metal Deposition on Metal and Semiconductor Electrodes Studied by In Situ Stm

Published online by Cambridge University Press:  10 February 2011

D. M. Kolb ,
R. J. Randler ,
R. I. Wielgosz  and
J. C. Ziegler
D. M. Kolb
Affiliation:
Dept. of Electrochemistry, University of Ulm, 89069 Ulm, Germany
R. J. Randler
Affiliation:
Dept. of Electrochemistry, University of Ulm, 89069 Ulm, Germany
R. I. Wielgosz
Affiliation:
Dept. of Electrochemistry, University of Ulm, 89069 Ulm, Germany
J. C. Ziegler
Affiliation:
Dept. of Electrochemistry, University of Ulm, 89069 Ulm, Germany
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Abstract

The deposition of Cu onto Au(100) and of Pb onto n- Si(111) electrodes from aqueous solutions has been monitored in situ by scanning tunneling microscopy. In the first case, a bcc structure of the Cu overlayer is observed, which allows pseudomorphic growth on Au(100) up to the 10th layer. Then a slow structural transition to fee begins. In contrast, Pb on Si(111) is shown to deposit as 3D crystallites with flat (111) terminated surfaces.

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Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 451: Symposium P – Electrochemical Synthesis and Modification , 1996 , 19
Copyright
Copyright © Materials Research Society 1997

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References

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