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In-situ X-ray Studies of Clean Catalytic Technologies

Published online by Cambridge University Press:  25 July 2011

Adam F. Lee ,
Christine V. Ellis ,
Mark A. Newton ,
Christopher M. Parlett  and
Karen Wilson
Adam F. Lee
Affiliation:
Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff, United Kingdom;
Christine V. Ellis
Affiliation:
Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff, United Kingdom;
Mark A. Newton
Affiliation:
Electronic Structure and Magnetism, European Synchrotron Radiation Facility, Grenoble, France
Christopher M. Parlett
Affiliation:
Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff, United Kingdom;
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Abstract

The rational design of new heterogeneous catalysts for clean chemical technologies can be accelerated by molecular level insight into surface chemical processes. In-situ methodologies, able to provide time-resolved and/or pressure dependent information on the evolution of reacting adsorbed layers over catalytically relevant surfaces, are therefore of especial interest. Here we discuss the application of in-situ XPS and in-situ, synchronous DRIFTS/MS/XAS methodologies to elucidate the active site in Pd-catalyzed, selective aerobic oxidation of allylic alcohols.

Keywords

Pdoxidationextended x-ray absorption fine structure(EXAFS)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1351: Symposium FF – Surfaces and Nanomaterials for Catalysis through In-Situ or Ex-Situ Studies , 2011 , mrss11-1351-ff16-05
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1 Vinod, C.P., Wilson, K., and Lee, A.F., J. Chem. Tech. Biotech. 86, 161 (2011).Google Scholar
2 Sheldon, R.A., Arends, I. and Hanefeld, U., Green Chemistry and Catalysis, (Wiley-VCH, 2007).Google Scholar
3 Della Pina, C., Falletta, E., Prati, L. and Rossi, M., Chem. Soc. Rev. 37, 2077 (2008).Google Scholar
4 Hackett, S.F.J, Brydson, R.M., Gass, M.H., Harvey, I., Newman, A.D., Wilson, K. and Lee, A.F., Angew. Chem.- Int. Ed 46, 8593 (2007).Google Scholar
5 Lee, A.F., Hackett, S.F.J., Hargreaves, J.S.J., and Wilson, K., Green Chem. 8, 549 (2006).Google Scholar
6 Grunwaldt, J.D., Caravati, M., and Baiker, A., J. Phys. Chem. B 110, 25586 (2006).Google Scholar
7 Zhao, D.Y., Feng, J.L., Huo, Q.S., Melosh, N., Fredrickson, G.H., Chmelka, B.F. and Stucky, G.D., Science 279, 548 (1998).Google Scholar
8 Xiong, Y. J., McLellan, J. M., Yin, Y. D. and Xia, Y. N., Angew. Chem. Int. Ed. 46, 790 (2007).Google Scholar
9 Newton, M.A., Top. Catal. 52, 1410 (2009).Google Scholar
10 Lee, A.F., Chang, Z., Ellis, P., Hackett, S.F.J., and Wilson, K., J. Phys. Chem. C 111, 18844 (2007).Google Scholar
11 Naughton, J., Lee, A.F., Thompson, S., Vinod, C.P., and Wilson, K., PCCP 12, 2670 (2010).Google Scholar