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Investigation on Additional Hardening Mechanisms in Off-Stoichiometric Al-Rich Ni3Al Alloys in Terms of Anti-Site Defect Configuration

Published online by Cambridge University Press:  11 February 2011

Seiji Miura ,
Satoshi Takizawa ,
Yoshinao Mishima  and
Tetsuo Mohri
Seiji Miura
Affiliation:
Division of Materials Science and Engineering, Graduate School of Engineering, Hokkaido University, Kita-13, Nishi-8, Kita-ku, Sapporo 060–8628, Japan.
Satoshi Takizawa
Affiliation:
Division of Materials Science and Engineering, Graduate School of Engineering, Hokkaido University, Kita-13, Nishi-8, Kita-ku, Sapporo 060–8628, Japan.
Yoshinao Mishima
Affiliation:
Division of Materials Science and Engineering, Graduate School of Engineering, Hokkaido University, Kita-13, Nishi-8, Kita-ku, Sapporo 060–8628, Japan.
Tetsuo Mohri
Affiliation:
Division of Materials Science and Engineering, Graduate School of Engineering, Hokkaido University, Kita-13, Nishi-8, Kita-ku, Sapporo 060–8628, Japan.
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Abstract

One of the unsettled issues of the mechanical properties of L12-Ni3Al compound is the effect of off-stoichiometry on the 0.2% flow stress at low temperature region. 0.2% flow stress at 77 K increases as deviating from the stoichiometric composition to both Ni-rich and Al-rich sides, but in Al-rich side the increasing rate is higher. According to the XRD results for the binary Ni3Al alloys, however, the composition dependence of the lattice constant is the same in both sides of the stoichiometric composition, which implies that the magnitude of lattice strain induced at off-stoichiometric composition is symmetrical. And it is not rational to associate the strengthening mechanism to a sole effect of isotropic strain due to an atomic size difference. In this study, attempts are made to explain the additional strengthening in Al-rich alloys in terms of the tetragonal distortion hardening mechanism, which arises from anisotropic atomic configuration around an anti-site Al atom.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 753: Symposium BB – Defect Properties and Related Phenomena in Intermetallic Alloys , 2002 , BB1.5
Copyright
Copyright © Materials Research Society 2003

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References

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