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Macroscopic and Microscopic Aspects of Electron Hopping in Mixed Conductor Membranes using the Quasi-Fermi level

Published online by Cambridge University Press:  21 February 2011

Richard P. Buck
Richard P. Buck*
Affiliation:
Dept. of Chemistry, University of North Carolina, Chapel Hill, NC 27599-3290
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Abstract

Electron transport in mixed conductor redox electrolyte membranes: anion/electron charge carriers, and cation/electron charge carriers are analyzed by irreversible thermodynamic methods appropriate to electrolyte transport. The generalized force for electron transport is the gradient of the Fermi level of electrons in electrolyte phases. The generalized force for ion transport is the gradient of the ionic electrochemical potential. New results include current-time, current-voltage, small amplitude and DC bias impedance functions.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 83
Copyright
Copyright © Materials Research Society 1989

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References

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