Skip to main content

Mesoporous Hybrid Thin Films: Building Blocks for Complex Materials with Spatial Organization

  • Galo J. Soler-Illia (a1), Paula C. Angelomé (a1), M. Cecilia Fuertes (a1), Alejandro Wolosiuk (a1), Sara A. Bilmes (a2), Francisco Javier López-Alcaraz (a3) and Hernán Míguez (a3)...

Mesoporous Hybrid Thin Films (MHTF) of a variety of compositions and embedded organic functions are produced by combining sol-gel synthesis, template self-assembly and surface modification. One-pot or post-grafting strategies permit to modify the pore surface behavior. Highly controlled MHTF issued from a reproducible and modular synthesis can be used as building blocks for more complex structures, presenting order at larger scales, and novel properties derived from this multiscale order. Multilayer stacks of MHTF presenting specific and different functions and frameworks located in a well-defined position have been produced by combining sequential film deposition, selective functionalization and dissolution. These systems present new properties such as localized chemistry or modulable photonic crystal behavior.

Hide All
1.a) See the Special Issue fiFunctional Hybrid Materialsfl, J. Mater. Chem. 2005, 15, 3557ss.
b) Soler-Illia, G. J. A. A., Innocenzi, P., Chem. Euro. J., 2006, 12, 4478.
2.a) Liu, N., Assink, R. A., Smarsly, B., Brinker, C.J., Chem. Commun. 2003, 1146;
b) Liu, N., Dunphy, D.R., Atanassov, P., Bunge, S.D., Chen, Z., López, G. P., Boyle, T.J., Brinker, C.J., Nano. Lett. 2004, 4, 551;
b) Petkov, N., Mintova, S., Jean, B., Metzger, T., Bein, T., Mat. Sci. Eng. C 2003, 23, 827.
3.Gibaud, A., Bardeau, J.-F., Dutreilh-Colas, M., Bellour, M., Balasubramanian, V. V., Robert, A., Mehdi, A., Reyé, C. and Corriu, R. J., J. Mater. Chem., 2004, 14, 1854.
4.Cagnol, F., Grosso, D., Sanchez, C., Chem. Commun. 2004, 1742.
5.Soler-Illia, G.J.A.A., Angelomé, P. C., Bozzano, P., Chem. Commun., 2004, 2854.
6.a) Crepaldi, E. L., Soler-Illia, G.J.A.A., Grosso, D., Albouy, P.-A., Sanchez, C.., Chem. Commun., 2001, 1582.
b) Angelomé, P. C., Aldabe-Bilmes, S., Calvo, M. E., Crepaldi, E. L., Grosso, D., Sanchez, C., Soler-Illia, G.J.A.A., New J. Chem., 2005, 29, 59.
7.Lee, A. Van der, Solid State Sci. 2000, 2, 157.
8.a) Grosso, D., Cagnol, F., Soler-Illia, G. J. A. A., Crepaldi, E. L., Amenitsch, H., BrunetBruneau, A., Bourgeois, A., Sanchez, C., Adv. Funct. Mater., 2004, 14, 309.
b) Angelomé, P. C., Andrini, L., Calvo, M. E., Requejo, F. G., Bilmes, S. A., Soler-Illia, G. J. A. A. J. Phys. Chem. C, 2007, 111, 10886.
9.Kim, T.-W., Ryoo, R., Kruk, M., Gierszal, K. P., Jaroniec, M., Kamiya, S., Terasaki, O., J. Phys. Chem. B 2004, 108, 11480.
10.Angelomé, P. C., Soler-Illia, G. J. A. A., Chem. Mater., 2005, 17, 322331.
11.a) Song, C., Villemure, G., Microporous Mesoporous Mater., 2001, 44–45, 679.
b) Etienne, M., Quach, A., Grosso, D., Nicole, L., Sanchez, C., Walcarius, A., Chem. Mater. 2007, 19, 844.
12.Otal, E. H., Angelomé, P. C., Aldabe-Bilmes, S., Soler-Illia, G.J.A.A., Adv. Mater., 2006, 18, 934.
13.Grosso, D., Soler-Illia, G.J.A.A., Crepaldi, E., Cagnol, F., Sinturel, C., Bourgeois, A., Brunet-Bruneau, A., Amenitsch, H., Albouy, P.-A., Sanchez, C., Chem. Mater. 2003, 15, 4562.
14.Sakatani, Y., Grosso, D., Nicole, L., Boissière, C., Soler-Illia, G. J. A. A., Sanchez, C.. J. Mater. Chem., 2006, 16, 77.
15.Crepaldi, E. L., Soler-Illia, G.J.A.A., Grosso, D., Sanchez, C., New J. Chem., 2003, 27, 9.
16.a) Liu, J., Shin, Y., Nie, Z., Chang, J. H., Wang, L.-Q., Fryxell, G. E., Samuels, W. D., Exarhos, G. J., J. Phys. Chem. A 2000, 104, 8328.
b) Notestein, J.M., Katz, A., Chem. Euro. J. 2006, 12, 3854.
17.Calvo, A., Angelomé, P.C., Williams, F. J., Soler-Illia, G.J.A.A., to be published.
18.a) Bronstein, L., Top. Curr. Chem., 2003, 226, 55.
b) Shi, J.L., Hua, Z. L., Zhang, L.X., J. Mater. Chem. 2004, 14, 795.
19.Perez, M. D., Otal, E., Bilmes, S. A., Soler-Illia, G., Crepaldi, E. L., Grosso, D. and Sanchez, C., Langmuir, 2004, 20, 6879.
20.Wang, D., Luo, H., Kou, R., Gil, M. P., Xiao, S., Golub, V. O., Yang, Z., Brinker, C. J. and Lu, Y., Angew. Chem. - Int. Ed., 2004, 43, 6169.
21.Mallory, G. O. and Hajdu, J. B., Electroless Plating: Fundamentals and Applications, American Electroplaters and Surface Finishers Society, Florida, 1990.
22.Kumai, Y., Tsukada, H., Akimoto, Y., Sugimoto, N., Seno, Y., Fukuoka, A. T., Ichikawa, M. and Inagaki, S., Adv. Mater., 2006, 18, 760.
23.Huang, M. H., Choudrey, A. and Yang, P., Chem. Commun., 2000, 1063.
24.Besson, S., Gacoin, T., Ricolleau, C. and Boilot, J. P., Chem. Commun., 2003, 360.
25.Fuertes, M. C., Wolosiuk, A. and Soler-Illia, G. J. A. A., to be published.
26.Mulvaney, P., MRS Bull 2001, 1009.
27.Tognalli, N., Fainstein, A., Wolosiuk, A., Bilmes, S.A., Soler-Illia, G.J.A.A., to be published.
28.Angelomé, P. C., Fuertes, M. C., Soler-Illia, G. J. A. A., Adv. Mater., 2006, 18, 2397.
29.Choi, S.Y., Mamak, M., Freymann, G. von, Chopra, N., Ozin, G.A., Nano Lett. 2006, 6, 2456.
30.Fuertes, M. C., López-Alcaraz, F. J., Marchi, M.C., Troiani, H., Luca, V., Míguez, H., Soler-Illia, G. J. A. A., Adv. Funct. Mater., 2007, 17, 1247.
Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

MRS Online Proceedings Library (OPL)
  • ISSN: -
  • EISSN: 1946-4274
  • URL: /core/journals/mrs-online-proceedings-library-archive
Please enter your name
Please enter a valid email address
Who would you like to send this to? *


Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed