Skip to main content
×
Home
    • Aa
    • Aa

Mesoporous Hybrid Thin Films: Building Blocks for Complex Materials with Spatial Organization

  • Galo J. Soler-Illia (a1), Paula C. Angelomé (a1), M. Cecilia Fuertes (a1), Alejandro Wolosiuk (a1), Sara A. Bilmes (a2), Francisco Javier López-Alcaraz (a3) and Hernán Míguez (a3)...
Abstract
ABSTRACT

Mesoporous Hybrid Thin Films (MHTF) of a variety of compositions and embedded organic functions are produced by combining sol-gel synthesis, template self-assembly and surface modification. One-pot or post-grafting strategies permit to modify the pore surface behavior. Highly controlled MHTF issued from a reproducible and modular synthesis can be used as building blocks for more complex structures, presenting order at larger scales, and novel properties derived from this multiscale order. Multilayer stacks of MHTF presenting specific and different functions and frameworks located in a well-defined position have been produced by combining sequential film deposition, selective functionalization and dissolution. These systems present new properties such as localized chemistry or modulable photonic crystal behavior.

Copyright
Linked references
Hide All

This list contains references from the content that can be linked to their source. For a full set of references and notes please see the PDF or HTML where available.

1.a) See the Special Issue fiFunctional Hybrid Materialsfl, J. Mater. Chem. 2005, 15, 3557ss.

b) G. J. A. A. Soler-Illia , P. Innocenzi , Chem. Euro. J., 2006, 12, 4478.

b) N. Liu , D.R. Dunphy , P. Atanassov , S.D. Bunge , Z. Chen , G. P. López , T.J. Boyle , C.J. Brinker , Nano. Lett. 2004, 4, 551;

b) N. Petkov , S. Mintova , B. Jean , T. Metzger , T. Bein , Mat. Sci. Eng. C 2003, 23, 827.

3. A. Gibaud , J.-F. Bardeau , M. Dutreilh-Colas , M. Bellour , V. V. Balasubramanian , A. Robert , A. Mehdi , C. Reyé and R. J. Corriu , J. Mater. Chem., 2004, 14, 1854.

b) P. C. Angelomé , S. Aldabe-Bilmes , M. E. Calvo , E. L. Crepaldi , D. Grosso , C. Sanchez , G.J.A.A. Soler-Illia , New J. Chem., 2005, 29, 59.

8.a) D. Grosso , F. Cagnol , G. J. A. A. Soler-Illia , E. L. Crepaldi , H. Amenitsch , A. BrunetBruneau , A. Bourgeois , C. Sanchez , Adv. Funct. Mater., 2004, 14, 309.

b) P. C. Angelomé , L. Andrini , M. E. Calvo , F. G. Requejo , S. A. Bilmes , G. J. A. A. Soler-Illia J. Phys. Chem. C, 2007, 111, 10886.

9. T.-W. Kim , R. Ryoo , M. Kruk , K. P. Gierszal , M. Jaroniec , S. Kamiya , O. Terasaki , J. Phys. Chem. B 2004, 108, 11480.

10. P. C. Angelomé , G. J. A. A. Soler-Illia , Chem. Mater., 2005, 17, 322331.

b) M. Etienne , A. Quach , D. Grosso , L. Nicole , C. Sanchez , A. Walcarius , Chem. Mater. 2007, 19, 844.

12. E. H. Otal , P. C. Angelomé , S. Aldabe-Bilmes , G.J.A.A. Soler-Illia , Adv. Mater., 2006, 18, 934.

13. D. Grosso , G.J.A.A. Soler-Illia , E. Crepaldi , F. Cagnol , C. Sinturel , A. Bourgeois , A. Brunet-Bruneau , H. Amenitsch , P.-A. Albouy , C. Sanchez , Chem. Mater. 2003, 15, 4562.

14. Y. Sakatani , D. Grosso , L. Nicole , C. Boissière , G. J. A. A. Soler-Illia , C. Sanchez . J. Mater. Chem., 2006, 16, 77.

15. E. L. Crepaldi , G.J.A.A. Soler-Illia , D. Grosso , C. Sanchez , New J. Chem., 2003, 27, 9.

16.a) J. Liu , Y. Shin , Z. Nie , J. H. Chang , L.-Q. Wang , G. E. Fryxell , W. D. Samuels , G. J. Exarhos , J. Phys. Chem. A 2000, 104, 8328.

b) J.M. Notestein , A. Katz , Chem. Euro. J. 2006, 12, 3854.

18.a) L. Bronstein , Top. Curr. Chem., 2003, 226, 55.

b) J.L. Shi , Z. L. Hua , L.X. Zhang , J. Mater. Chem. 2004, 14, 795.

19. M. D. Perez , E. Otal , S. A. Bilmes , G. Soler-Illia , E. L. Crepaldi , D. Grosso and C. Sanchez , Langmuir, 2004, 20, 6879.

20. D. Wang , H. Luo , R. Kou , M. P. Gil , S. Xiao , V. O. Golub , Z. Yang , C. J. Brinker and Y. Lu , Angew. Chem. - Int. Ed., 2004, 43, 6169.

22. Y. Kumai , H. Tsukada , Y. Akimoto , N. Sugimoto , Y. Seno , A. T. Fukuoka , M. Ichikawa and S. Inagaki , Adv. Mater., 2006, 18, 760.

28. P. C. Angelomé , M. C. Fuertes , G. J. A. A. Soler-Illia , Adv. Mater., 2006, 18, 2397.

29. S.Y. Choi , M. Mamak , G. von Freymann , N. Chopra , G.A. Ozin , Nano Lett. 2006, 6, 2456.

30. M. C. Fuertes , F. J. López-Alcaraz , M.C. Marchi , H. Troiani , V. Luca , H. Míguez , G. J. A. A. Soler-Illia , Adv. Funct. Mater., 2007, 17, 1247.

Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

MRS Online Proceedings Library (OPL)
  • ISSN: -
  • EISSN: 1946-4274
  • URL: /core/journals/mrs-online-proceedings-library-archive
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 1 *
Loading metrics...

Abstract views

Total abstract views: 61 *
Loading metrics...

* Views captured on Cambridge Core between September 2016 - 22nd September 2017. This data will be updated every 24 hours.