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Microwave-assisted Synthesis of Perylene-3,4-dicarboximides: Highly Photostable Fluorescent Dyes

Published online by Cambridge University Press:  01 February 2011

Brian Guthrie ,
Zixing Wang  and
Jian Li
Brian Guthrie
Affiliation:
brian.guthrie@asu.edu, Arizona State University, School of Materials and Advanced Photovoltaics Center, 7700 S River Parkway, Tempe, AZ, 85284, United States
Zixing Wang
Affiliation:
zixing.wang@asu.edu, Arizona State University, School of Materials, 7700 S River Parkway, Tempe, AZ, 85284, United States, 480-965-2612, 480-727-8965
Jian Li
Affiliation:
jian.li.1@asu.edu, Arizona State University, School of Materials and Advanced Photovoltaics Center, 7700 S River Parkway, Tempe, AZ, 85284, United States
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Abstract

A new method for synthesis of perylene-3,4-dicarboximides (PDCIs) is reported. Modified from a literature reported synthetic method, microwave assisted heating was used to perform the reaction, which not only shortened the original reaction time, from 18 hours to 30 min, but also increased the corresponding reaction yield. A variety of PDCI derivatives were synthesized in order to correlate the influence of substituents on the reaction outcome. Moreover, the photophysical and electrochemical properties of PDCIs are characterized and reported.

Keywords

microwave heatingluminescenceoptical properties
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1091: Symposium AA – Conjugated Organic Materials–Synthesis, Structure, Device and Applications , 2008 , 1091-AA07-08
Copyright
Copyright © Materials Research Society 2008

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