Hostname: page-component-848d4c4894-hfldf Total loading time: 0 Render date: 2024-06-06T18:33:17.063Z Has data issue: false hasContentIssue false

Monitoring of Heteropolysiloxane Thin film Properties Using Rheological and Acoustic Characterization Methods

Published online by Cambridge University Press:  25 February 2011

C. Guizard
Affiliation:
Laboratoire de Physicochimie des Matériaux CNRS-URA 1312 ENSC - 8, rue de l'Ecole Normale. 34053 Monpellier Cedex 1 (France).
P. Lacan
Affiliation:
Kodak-Pathe, Centre de Recherches et de Technologie, Zone Industrielle, 71102 Chalón sur Saône Cedex (France).
J. M. Saurel
Affiliation:
Laboratoire de Microacoustique, Université de Montpellier II, Place Eugène Bataillon, 34060 Montpellier Cedex (France).
F. Hajoub
Affiliation:
Laboratoire de Microacoustique, Université de Montpellier II, Place Eugène Bataillon, 34060 Montpellier Cedex (France).
L. Cot
Affiliation:
Laboratoire de Physicochimie des Matériaux CNRS-URA 1312 ENSC - 8, rue de l'Ecole Normale. 34053 Monpellier Cedex 1 (France).
Get access

Abstract

This paper emphasizes on the mechanical characterization of heteropolysiloxane (HPS) derived materials using rheology and acoustic microscopy methods. Dynamic rheological measurements have been performed at the sol and the gel stages with two different precursors. An organic gel-like behaviour has been brought into evidence related to the fact that several microns thick coated layers can be obtained with these materials. On the contrary acoustic analysis revealed a glass-like behaviour for the cured layers. These results confirm the interest of organic/inorganic polymers to design new materials with tailored properties.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Sholze, H., J. Non-cryst. Solids, 73, 669 (1985).CrossRefGoogle Scholar
2. Schmidt, H. K., ACS Symp. Ser. 360 (27), 333 (1988).CrossRefGoogle Scholar
3. Henning Winter, H., MRS Bulletin, XVI (8), 44 (1991).CrossRefGoogle Scholar
4. Guizard, C., Ajaka, N., Besland, M. P., Larbot, A. and Cot, L., in Polyimides and other High-Temperature Polymers, edited by Abadie, M. J. M. and Sillion, B., (Elsevier Science Pub. B. V., Amsterdam, 1991), p. 537.Google Scholar
5. Gauthier-Manuel, B., Guyon, E., Roux, S., Gits, S. and Le Faucheux, F., Journal de Physique, 48 (5), 869 (1987).CrossRefGoogle Scholar
6. Sacks, M. D. and Sheu, R. S. in Science of Ceramic Chemical Processing, edited by Hench, L. L., Ulrich, D. R. (Wiley, New York, 1986), p. 100.Google Scholar
7. Sacks, M. D. and Scheu, R. S., Non, J. Cryst. Solids, 92, 383 (1987).CrossRefGoogle Scholar
8. Guizard, C., Achddou, J. C., Larbot, A. and Cot, L., to be published in J. Non-cryst. Solids, Special issue on the Six International Workshop on Glasses and Ceramics from Gels. Seville 1991.Google Scholar
9. Chambon, F. and Henning Winter, H., Polymer Bull. 13, 499 (1985).CrossRefGoogle Scholar
10. Atalar, A., J. Appl. Phys., 50, 8237 (1979).CrossRefGoogle Scholar
11. Attal, J., Robert, L., Despaux, G., Caplain, R. and Saurel, J. M., to be published in “19th Int. Symp. Proceed, on Acoustical ImagingBochum (Germany), April 35, 1991.Google Scholar