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Na+/H+ Topotactic Exchange on NaNbWO6 with TTB-like Structure: The series HxNa1-xNbWO6

Published online by Cambridge University Press:  11 February 2011

A. Kuhn ,
F. García-Alvarado ,
H. Bashir ,
A. L. Dos Santos  and
J. L. Acosta
A. Kuhn
Affiliation:
Department of Chemistry. Universidad San Pablo-CEU. E-28668 Boadilla del Monte, Madrid (SPAIN); e-mail: flgaal@ceu.es
F. García-Alvarado
Affiliation:
Department of Chemistry. Universidad San Pablo-CEU. E-28668 Boadilla del Monte, Madrid (SPAIN); e-mail: flgaal@ceu.es
H. Bashir
Affiliation:
Instituto de Ciencia y Tecnología de Polímeros, CSIC, 28006 Madrid (SPAIN).
A. L. Dos Santos
Affiliation:
Instituto de Ciencia y Tecnología de Polímeros, CSIC, 28006 Madrid (SPAIN).
J. L. Acosta
Affiliation:
Instituto de Ciencia y Tecnología de Polímeros, CSIC, 28006 Madrid (SPAIN).
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Abstract

TTB-type NaNbWO6 has been used to perform sodium-proton exchange reactions by using nitric acid as an exchanging agent. The characterisation of the exchange reaction products, performed by means of chemical analysis, X-ray diffraction and thermogravimetric analysis, indicate that the exchange reaction takes place topotactically. The following formula is proposed for the obtained phase of variable composition: Na1-xHxNbWO6 (0<x<0.46).

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 755: Symposium DD – Solid-State Chemistry of Inorganic Materials IV , 2002 , DD6.26
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

Wöhler, F., Ann. Chim. Phys. 43, 29 (1823).Google Scholar
Magnéli, A., Arkiv för Kemi 1, 24, 213–221(1949).Google Scholar
3. Magnéli, A., Arkiv för Kemi 1, 32, 269–276 (1949).Google Scholar
4. Takusagawa, F. and Jacobson, R.A., J. Solid State Chem. 18, 163–174 (1976).Google Scholar
5. Marinder, B.-O., Chem. Script. 26, 547–560 (1986).Google Scholar
6. Raub, Ch., Sweedler, A.R., Jensen, M.A., Broadston, S. and Matthias, B.T., Phys. Rev. Letters 13, 746 (1964).Google Scholar
7. Figlarz, M., Prog. Solid State Chem. 19, 1 (1989).Google Scholar
8. Gèrand, B., Nowogrocky, G., Guenot, J., Figlarz, M., J. Solid State Chem. 29, 429 (1979).Google Scholar
9. Dickens, P.G., Murphy, D.J. and Halstead, T.K., J. Solid State Chem. 6(3), 370–373 (1973).Google Scholar
10. Kihlborg, L. and Sharma, R., J. Microsc. Spectrosc. Electron 7, 387 (1982).Google Scholar
11. Horlin, T., Marinder, B.-O. and Nygren, M., Rev. Chim. Minér., 19, 231–238 (1982).Google Scholar
12. García-Alvarado, F., Kuhn, A., Acosta, J.L., Bashir, H. and Dos Santos, A.L., Spanish Patent. Appl. N° 200102544 (16 November 2001).Google Scholar
13. Rietveld, H.M., Cryst. 22, 151 (1967); J. Appl. Cryst. 65, 2 (1969).Google Scholar
14. Rodríguez-Carvajal, J.., presented at the Satellite Meeting of the XVth Congress of the International Union of Crystrallography, Toulouse, France, 1992 (unpublished).Google Scholar