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Nanocomposites From Polymers and Layered Minerals

Published online by Cambridge University Press:  10 February 2011

H. R. Fischer ,
L. H. Gielgens  and
T. P. M. Koster
H. R. Fischer
Affiliation:
TNO-TPD Institute of Applied Physics, Materials Division, P. 0. Box 595, 5600 AN Eindhoven, The Netherlands
L. H. Gielgens
Affiliation:
TNO-TPD Institute of Applied Physics, Materials Division, P. 0. Box 595, 5600 AN Eindhoven, The Netherlands
T. P. M. Koster
Affiliation:
TNO-TPD Institute of Applied Physics, Materials Division, P. 0. Box 595, 5600 AN Eindhoven, The Netherlands
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Abstract

Composite materials consisting of polymeric matrix materials and natural or synthetic layered minerals like clays were prepared by using special compatibilizing agents between the two intrinsically non-miscible materials. These compatibiliseres are block- or graft copolymers combining one part of the polymer identically and/or completely miscible with the organic polymer (matrix compound) an another part compatible/miscible with the natural mineral. The interaction between the first part of the compatibiliser is preferentially an ionic interaction or an interaction via H-bonds. This interaction leads to a separation of the mineral into single sheets and a subsequent homogeneous incorporation of these sheets into the polymer matrix material.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 117
Copyright
Copyright © Materials Research Society 1998

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References

1 Kawasumi, M., Kohzaki, M., Kojima, Y., Okada, A., Kamigaito, O., U.S. Patent 4,810734 (1989)Google Scholar
2 Usuki, A., Kojima, Y., Kawasumi, M., Okada, A., Fukushima, Y., Kurauchi, T., Kamigato, O., J. Mater.Res., 8, 1179 (1993)10.1557/JMR.1993.1179Google Scholar
3 Arranda, P., Ruiz-Hitzky, E., Chem. Mater., 4, 1395 (1992)10.1021/cm00024a048Google Scholar
4 Wu, J., Lerner, M. M., Chem. Mater., 5, 835 (1993)10.1021/cm00030a019Google Scholar
5 Vaia, R. A., Vasudevan, S., Krawiec, W., Scalon, L. G., Giannelis, E. P., Adv. Mater., 7, 154 (1995)10.1002/adma.19950070210Google Scholar
6 Oriakhi, C. O., Nafshun, R. L., Lerner, M. W., MRS Bulletin, 31, 1513 (1996)10.1016/S0025-5408(96)00142-0Google Scholar
7 Kleinfeld, E. R., Ferguson, G. S., Science, 265, 370 (1994)10.1126/science.265.5170.370Google Scholar
8 Friedlander, H. Z., Frink, C. R., Polym. Lett., 2, 475 (1964)10.1002/pol.1964.110020435Google Scholar
9 Beall, G. W., Tsipurski, S., Sorokin, A., Goldman, A., U. S. Patent 5,578,672, (1996)Google Scholar
10 Kawasumi, M., Hasegawa, N., Kato, M., Ususki, A., Okada, A., Macromolecules, 30, 6333 (1997)10.1021/ma961786hGoogle Scholar
11 Miyata, S., Kumara, M.T., Chem. Lett., 1973, 842 Google Scholar
12 Lee, D. C., Jang, L. W., J. Appl. Polym. Sci., 61, 1117 (1996)10.1002/(SICI)1097-4628(19960815)61:7<1117::AID-APP7>3.0.CO;2-P3.0.CO;2-P>Google Scholar