Skip to main content
×
×
Home

New Structure Model for Lithium Nickel Batteries

  • M.A. Monge (a1), E. Gutiérrez-Puebla (a1), I. Rasines (a2) and J.A. Campa (a3)
Abstract

After growing black colored single crystals of LixNi1−xO (x = 0.27) and solving its crystal structure, a model is proposed as an alternative to the structural type admitted for LixNi1−xO. The new rhombohedral cell consists of a cubic close packing of oxygens in which the alternation of two kind of mixed layers containing Li and Ni in different ratios can be detected along the c direction. This model implies a Li order incompatible with the alternation of Ni layers, one of them pure and the other containing some Li. The results of magnetization measurements look consistent with the new structural type, and reveal that LixNi1−xO behaves as mictomagnetic.

Copyright
References
Hide All
1 Lee, Y.S., Sun, Y.K., and Nahm, K.S., , K.S., Solid State Ionics 118, p.15 9(1999).
2 Tao, S., Wu, Q., ZZhan, h., and Meng, G., Solid State Ionics 124, 53 (1999).
3 Dyer, L.D., Borie, B.S., and Smith, G.P., J. Am. Chem. Soc. 76, p. 1, 499 (1954).
4 Goodenough, J.B., Wickham, D.G., and Croft, W.J., J. Phys. Chem. Solids 5, p. 107 (1958).
5 Bajpai, A., and Banerjee, A., Phys. Rev. B 55, p. 12, 439 (1997).
6 Hirano, A., Kanno, R., Kawamoto, Y., Takeda, Y., Yamaura, K., Takano, M., Ohyama, K., Ohashi, M., and Yamaguchi, Y., Solid State Ionics 78, p. 12 (1995).
7 Massarotti, V., Capsoni, D., Bini, M., Mustarelli, P., and Marini, S.. Ionics 1, p. 421 (1995).
8 Shirakami, T., Takematsu, M., Hirano, A., Kanno, R., Yamaura, K., Takano, M., and Atake, T., Mater. Sc. Engineer. B 4 p. 70 (1998).
9 Yamaura, K., Takano, M., Hirano, A., and Kanno, R.J., Solid State Chem. 127, p. 109 (1996).
10 Takematsu, M., Shirakami, T., Atake, T., Hirano, A., and Kanno, R. in Solid State Ionics: New Developments, edited by Chowdari, B.V.R., World Scientific, Singapore, 1996, p. 330.
11 SMART and SHELXTL, Siemens Energy and Automation Inc. Analytical Instrumentation, 1996.
12 Boudreaux, E.A., and Mulay, L.N., Theory and Applications of Molecular Paramag-netism, Wiley, New York, 1976, p. 494495.
13 International Tables for Crystallography, edited by Wilson, A.J.C., Kluwer, Dordrecht, 1995, Vol. C, p. 219, 484-485.
14 International Centre for Diffraction Data. Powder Diffraction File. Card Nos. 47–1049, 41-890, and 4163.
15 Peres, J.P., Weill, F., and Delmas, C., Solid State Ionics 116, p. 19 (1999).
16 Evain, M., Boucher, F., and Gourdon, O., Chem. Mat. 10, p. 3068, 1998.
17 Merzt, D., Ksari, Y., Celestini, F., Debierre, J.M.,Stepanov, A., and Delmas, C., Phys. Rev. B 61, p. 1240 (2000).
Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

MRS Online Proceedings Library (OPL)
  • ISSN: -
  • EISSN: 1946-4274
  • URL: /core/journals/mrs-online-proceedings-library-archive
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 2 *
Loading metrics...

Abstract views

Total abstract views: 38 *
Loading metrics...

* Views captured on Cambridge Core between September 2016 - 20th August 2018. This data will be updated every 24 hours.