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Nucleation and Growth of Silicon Microstructures by Direct-Laser Writing

Published online by Cambridge University Press:  28 February 2011

David E. Kotecki
Affiliation:
Physics Department, Lawrence Livermore National Laboratory, Livermore CA. 94550 and Department of Applied Science, University of California, Davis/Livermore, Livermore, CA. 94550
Irving P. Herman
Affiliation:
Department of Applied Physics, Columbia University, New York, N.Y. 10027
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Abstract

This paper reports on a study of the nucleation phase of thin film growth during pyrolytic deposition by direct-laser writing. A Monte Carlo computer simulation is used to model the initial surface dynamics occurring during the deposition of silicon from silane (SiH4) on strongly binding substrates such as silicon, and on weakly binding substrates such as silicon dioxide (SiO2) and silicon nitride (Si3N4). Results show that for high peak temperatures (≥ 1200 K) and weakly binding substrates, the most probable location for the initiation of thin film growth is radialy displaced from the center of the locally laser-heated region of the surface. At low peak temperatures, thin film nucleation is found to begin at the center of the locally laser-heated surface for all substrates.

Type
Articles
Copyright
Copyright © Materials Research Society 1987

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References

[1] Herman, I.P., in Photochemical Materials Processing, edited by Ibbs, K.G. and Osgood, R.M. (Cambridge University Press, 1987).Google Scholar
[2] Rytz-Froidevaux, Y., Salathé, R.P., and Gilgen, H.H., Appl. Phys. A. 37, 121 (1985).Google Scholar
[3] Osgood, R.M. and Deutsch, T.F., Science 227 709 (1985).Google Scholar
[4] Ehrlich, D.J. and Tsao, J.Y., in VLSI Electronics: Microstructure Science, edited by Einspruch, N. (Academic Press, New York, 1983) p.129.Google Scholar
[5] McWilliams, B.M., Chin, H.W., Herman, I.P., Hyde, R.A., Mitlitsky, F., Whitehead, J.C., and Wood, L.L., in Proceedings of the SPIE, edited by Allen, S. (SPIE, Bellingham, Washington, 1984) 459, p. 49.Google Scholar
[6] Maissel, L.I. and Glang, R., Handbook of Thin Film Technology, (McGraw-Hill, New York, 1970).Google Scholar
[7] Müller-Krumbhaar, H. in Monte Carlo Methods, edited by Binder, K. (Springer-Verlag, New York, 1979).Google Scholar
[8] Claassen, W. A. P. and Bloem, J., J. Electrochem. Soc. 127, 194 (1980).Google Scholar
[9] Bloem, J. and Claassen, W.A.P., Phillips Tech. Rev. 41 60 (1983/1984).Google Scholar
[10] Farnaam, M.K., PhD thesis, University of California, Berkeley, 1983.Google Scholar
[11] Farrow, R.R.C., J. Electrochem. Soc. 121 899 (1974).CrossRefGoogle Scholar
[12] Kotecki, D.E. and Herman, I.P., (to be published).Google Scholar
[13] Lewis, B. and Anderson, J.C., Nucleation and Growth of Thin Films, (Academic Press, New York, 1978).Google Scholar
[14] Herman, I.P., Magnotta, F., and Kotecki, D.E., J. Vac. Sci. Technol. B. 4 659 (1986).Google Scholar