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Occupied and Unoccupied Orbitals of C60 and C70 Probed with C 1s Emission and Absorption

Published online by Cambridge University Press:  22 February 2011

J. A. Carlisle ,
L. J. Terminello ,
E. A. Hudson ,
E.L. Shirley ,
F. J. Himpsel ,
J. J. Jia ,
T. A. Callcott ,
R. C. C. Perera ,
S. G. Louie  and
J. StÖhr
...Show all authors
J. A. Carlisle
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94550
L. J. Terminello
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94550
E. A. Hudson
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94550
E.L. Shirley
Affiliation:
Lawrence Livermore National Laboratory, Livermore, CA 94550
F. J. Himpsel
Affiliation:
IBM Research Division, Thomas J. Watson Research Center, Yorktown Heights, NY 10598
J. J. Jia
Affiliation:
University of Tennessee, Knoxville, TN 37996
T. A. Callcott
Affiliation:
University of Tennessee, Knoxville, TN 37996
R. C. C. Perera
Affiliation:
Lawrence Berkeley Laboratory, Berkeley, CA 94720
S. G. Louie
Affiliation:
Lawrence Berkeley Laboratory, Berkeley, CA 94720
J. StÖhr
Affiliation:
Department of Physics, U.C. Berkeley, CA 94720
M. G. Samant
Affiliation:
IBM Research Division, Almaden Research Center, 650 Harry Road, San Jose, CA 95120-6099
D. L. Ederer
Affiliation:
Tulane University, New Orleans, LA, 70118
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Abstract

The full spectrum of occupied and unoccupied σ and Π orbitals is presented for solid C60, C70, and graphite, using C1s emission and absorption spectroscopy. There are significant differences between C60 and C70, and even larger changes relative to their infinite analog graphite C∞. A comparison is made with photoemission and inverse photoemission results, along with first principles quasiparticle calculations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 349: Symposium T – Novel Forms of Carbon II , 1994 , 245
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

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