Hostname: page-component-54dcc4c588-64p75 Total loading time: 0 Render date: 2025-10-03T14:48:26.050Z Has data issue: false hasContentIssue false
  • English
  • Français

Optical Properties of Distyrylbenzene Chromophores and their Segmented Copolymers

Published online by Cambridge University Press:  10 February 2011

Nicholas Benfaremo ,
Daniel J. Sandman ,
Sukant Tripathy ,
Jayant Kumar ,
Ke Yang ,
Michael F. Rubner  and
Cormac Lyons
Nicholas Benfaremo
Affiliation:
Center for Advanced Materials, Department of Chemistry, University of Massachusetts Lowell, Lowell, MA 01854
Daniel J. Sandman
Affiliation:
Center for Advanced Materials, Department of Chemistry, University of Massachusetts Lowell, Lowell, MA 01854
Sukant Tripathy
Affiliation:
Center for Advanced Materials, Department of Chemistry, University of Massachusetts Lowell, Lowell, MA 01854
Jayant Kumar
Affiliation:
Center for Advanced Materials, Department of Physics, University of Massachusetts Lowell, Lowell, MA 01854
Ke Yang
Affiliation:
Center for Advanced Materials, Department of Physics, University of Massachusetts Lowell, Lowell, MA 01854
Michael F. Rubner
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139.
Cormac Lyons
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139.
Get access

Abstract

A new segmented polymer (3) consisting of a distyrylbenzene chromophore separated by polyethylene glycol segments has been prepared by two independent methods: a novel, polymer analogous Mitsunobu reaction and conventional double displacement reaction. The polymer is soluble in a variety of organic solvents, forms excellent, optically clear films and exhibits strong fluorescence. The properties of the chromophore and the polymer, as well as the scope and limitations of the novel Mitsonobu polymerization are presented. Attempts to use polymer (3) in electroluminescent devices are also discussed.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 533
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

1 Travis, J., Science, 263, 1700 (1994) and references therein.Google Scholar
2 Stalmach, U., Kolshorn, H., Brehm, I., Meier, H., Liebigs Ann. 1996, 1449.Google Scholar
3 Cumming, R., Gaudiana, R.A., Hutchinson, K., Kolbe, E., Ingwall, R.. Mehta, P., Minns, R.A., Petersen, C.P., Waldman, D., J. Mater. Sci.-Pure Appl. Chem. A33(9), 1301 (1996).Google Scholar
4 Hay, M., Klavetter, F.L., J. Am. Chem. Soc. 117, 7112 (1995).Google Scholar
5 Yang, Z., Sokolik, I., Karasz, F.E., Macromolecules 26, 1188 (1993).Google Scholar
6 Greiner, A., Bolle, B., Hesemann, P., Oberski, J.M., Sander, R., Macromol. Phy. and Chem. 197, 113 (1996).Google Scholar
7 Gill, R.E., van Hutten, P.F., Meetsama, A., Hadziioannou, G., Chem. Mater. 8, 1341 (1996).Google Scholar
8 Stalmach, V., Kolshorn, H., Brehn, I., Meier, H., Liebigs, Ann. 1996, 1449.Google Scholar
9 Hide, F., Díaz-García, M.A., Schwartz, B.J., Heeger, A.J., Acc. Chem. Res. 30, 430 (1997).Google Scholar
10 Pei, Q., Yang, Y., Yu, G., Zhang, C., Heeger, A.J., J. Am. Chem. Soc. 118, 3922 (1996).Google Scholar
11 Rubner, M.F., Lyons, C., Manuscript in preparation.Google Scholar
12 Pei, Q., Yang, Y., J. Am. Chem. Soc. 118, 7416 (1996).Google Scholar
13 Tewari, R.S., Kumari, N., Kendurkar, P.S., Ind. J. Chem. 15B, 753 (1977).Google Scholar
14 Yang, Z., Geise, H.J., Mehbod, M., Debrue, G., Visser, J.W., Sonneveld, E.J., dack, L. Van't, Gijbels, R., Syn. Metals 39, 137 (1990).Google Scholar
15 Mitsunobu, O., Synthesis 1981, 1.Google Scholar
16 Hughes, D.L., Organic Reactions. edited by Paquett, Leo A (John Wiley and Sons, New York, 1992), vol.42, p. 335–656.Google Scholar
17 Harris, J.M., Struck, E.C., Case, M.G., Paley, M.S., Yalpani, M., Van Alstine, J.M., Brooks, D.E., J. Poly. Sci.: Poly. Ed. 22, 341 (1984).Google Scholar
18 Dust, J.M., Fang, Z-h., Harris, J.M., Macromolecules 23(16), 3742 (1990).Google Scholar
19 Mates, T.E. and Ober, C.K., J. Poly. Sci.: Part C: Poly. Lett. 28, 331 (1990).Google Scholar
20 Lee, J-K., Yoo, D.S., Handy, E.S., Rubner, M.F., Appl. Phys. Lett. 69, 1686 (1996).Google Scholar