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Patterning PETN and HMX using Dip Pen Nanolithography

  • Omkar Nafday (a1), Brandon Weeks (a2), Jason Haaheim (a3) and Ray Eby (a4)
Abstract

Recently there has been a focused effort to develop reliable nanoscopic writing and reading capabilities. Dip-pen nanolithography (DPN) has emerged as a convenient method to deliver nanoscale materials onto a substrate by leveraging scanning probe microscopy capability. A new application for the DPN method is the field of microdetonics which is the microscale decomposition and study of reactions of explosives. Results are presented for patterning pentaerythritol tetranitrate (PETN) and cyclotetramethylene tetranitramine (HMX) on silicon and mica substrates. The ultimate goal is to pattern both energetic materials in nanoscale registry and investigate their reaction and decomposition at the nanoscale due to heating or shock initiation. In addition to patterning of high explosives, a discussion on the effect of surface energy on patterning rates is investigated. This knowledge will be applicable to inks beyond high explosives.

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1. Piner, R. D., Zhu, J., Xu, F., Hong, S. and Mirkin, C. A., Science, 283, 5402, 661 (1999).
2. Xia, Y. N., Rogers, J. A., Paul, K. E., Whitesides, G. M., Chem. Rev., 99, 7, 1823 (1999).
3. Vieu, C., Carcenac, F., Pepin, A., Chen, Y., Mejias, M., Lebib, A., Manin-Ferlazzo, L., Couraud, L., Launois, H., Appl. Surf. Sci., 164, 1, 111(2000).
4. Zankovych, S., Hoffmann, T., Seekamp, J., Bruch, J. U., Torres, C. M. S., Nanotechnology, 12, 91 (2001).
5. Melngailis, J., J. Vac. Sci. Tech. B: Microelectronics and Nanometer Structures, 5, 2, 469 (1987).
6. Sheehan, P. E. and Whitman, L. J., Phys. Rev. Lett., 88 (15), 6104 (2002).
7. Schwartz, P.V., Langmuir, 18, 4041 (2002).
8. Weeks, B. L., Noy, A., Miller, A. E., De Yoreo, J. J., Phys. Rev. Lett., 88 (25), 5505 (2002).
9. Manandhar, P., Jang, J., Schatz, G. C., Ratner, M. A., Hong, S., Phys. Rev. Lett., 90 (11), 5505 (2003).
10. McKendry, R., Huck, W. T. S., Weeks, B. L., Fiorini, M., Abell, C., Rayment, T., Nano Lett., 2, 713 (2002).
11. Zhang, H., Li, Z., Mirkin, C. A., Adv. Mater., 14, 1472 (2002).
12. Demers, L. M., Ginger, D. S., Park, S. J., Li, Z., Chung, S. W., Mirkin, C. A., Science, 296, 1836 (2002).
13. Lee, K. B., Lim, J. H., Mirkin, C. A., J. Am. Chem. Soc., 125, 5588 (2003).
14. Noy, A., Miller, A. E., Klare, J. E., Weeks, B. L., Woods, B. W., De Yoreo, J. J., Nano Lett., 2 (2), 109 (2002).
15. Su, M., Liu, X. G., Li, S. Y., Dravid, V. P., Mirkin, C. A., J. Am. Chem. Soc., 124, 1560 (2002).
16. Sheehan, P. E., Whitman, L. J., King, W. P., Nelson, B. A., Appl. Phys. Lett., 85 (9), 1589 (2004).
17. Binnig, G., Quate, C. F., Gerber, G. H., Phys. Rev. Lett., 56, 930 (1986).
18. Gruzdkov, Y. A. and Gupta, Y. M., J. Phys. Chem. A, 105, 6197 (2001).
19. Worley, C. M., Vannet, M. D., Ball, G. L., Moddeman, W. E., Surface and Interface Analysis, 10, 273 (1987).
20. Lee, J. S., Hsu, C. K., Chang, C. L., Thermochemica Acta, 392–393, 173 (2002).
21. Zaoui, A. and Sekkal, W., Solid State Communications, 118, 345350 (2001).
22. Gibbs, T.R. and Popolato, A., LASL Explosive Property Data (University of California Press, Berkeley, CA, 1981).
23. George, R. S., Cady, H. C., Rogers, R. N., Rohwer, R. K., Ind. Eng. Chem., Prod. Res. and Dev., 4, 209 (1965).
24. Hoffman, D. M. and Swansiger, R. W., Propellants, Explosives and Pyrotechnics, 24, 301 (1999).
25. Lynch, J. C., Myers, K. F., Brannon, J. M., Delfino, J. J., J. Chem. Eng. Data, 46, 1549 (2001).
26. Ericson, K. L., Skocypec, R. D., Trott, W. M. and Renlund, A. M., Proceedings of the 15th International Pyrotechnics Seminar, Boulder, CO, 239 (1990).
27. Tappan, A. S., Renlund, A. M., Long, G. T., Kravitz, S. H., Ericson, K. L., Trott, W. M. and Baer, Melvin R., Proceedings of the 12th International Detonation Symposium, San Diego, CA, 0810 (1992).
28. Siele, V. I., Warman, M., Leccacorci, J., Hutchinson, R. W., Motto, R., Gilbert, E. E., Benzinger, T. M., Coburn, M. D., Rohwer, R. K. and Davey, R. K., Propellants, Explosives and Pyrotechnics, 6, 67 (1981).
30. Sitzmann, M. E. and Foti, S. C., Journal of Chemical and Engineering Data, 20 (1), 53 (1975).
31. Leggett, D. C., Jenkins, T.F. and Miyares, P.H., Analytical Chemistry, 62, 1335 (1990).
33. Rozhok, S., Piner, R., Mirkin, C. A., J. Phys. Chem. B, 107, 751 (2003).
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