Skip to main content
×
×
Home

Photocatalytic reforming of formic acid with simultaneous hydrogen production under visible light over CdS sensitized Na2Ti2O4(OH)2

  • Wendong Tang (a1), Dengwei Jing (a1) and Liejin Guo (a1)
Abstract

The present work reports the renewable hydrogen production by an anaerobic photocatalytic reforming of formic acid over CdS sensitized Na2Ti2O4(OH)2 nanotubes. the Na2Ti2O4(OH)2 nanotube was prepared and charactered by X-ray diffraction, UV-visible absorption, transmission electron microscopy, etc. The activity of the catalyst in formic acid was investigated. The greatest photocatalytic reforming activity of formic acid occurs as the formic acid initial concentration is 20 v.%. A probable mechanism for the photocatalytic reforming process was proposed and discussed.

Copyright
References
Hide All
1.Kudo, A., Miseki, Y., Chem. Soc. Rev. 38, 253278 (2002).
2.Maeda, K., Teramura, K., Lu, D., Takata, T., Saito, N., Inoue, Y. and Domen, K., Nature 295, 440 (2006).
3.Khan, S. U. M., Al-Shahry, M., Ingler, W. B. Jr., Science 297, 2242 (2002).
4.Kapoor, M. P., Inagaki, S., and Yoshida, H., J. Phys. Chem. B 109, 92319238 (2005).
5.Konta, R., Ishii, T., Kato, H. and Kudo, A., J. Phys. Chem. B 108, 8992 (2004).
6.Tawkaew, S., Fujishiro, Y., Yin, S. and Sato, T., Colloids Surf. A 139, 179 (2001).
7.Reber, J. F. and Rusek, M., J. Phys. Chem. 90, 824(1986).
8.Tsuji, I., Kato, H., Kobayashi, H. and Kudo, A., J. Am. Chem. Soc. 41, 13406 (2004).
9.Tsuji, I., Kato, H. and Kudo, A., Angew. Chem. Int. Ed. 44, 3565 (2005).
10.Fujishima, A., Honda, K., Nature 238, 37 (1972).
11.Ni, M., Leung, M. K.H., Leung, D. Y.C. and Sumathy, K., Renewable and Sustainable Energy Reviews 126(2005).
12.Galińska, A. and Walendziewski, J., Energy Fuels 19(3), 11431147(2005)
13., H. Werner, A. F. and Bauer, R., International Journal of Hydrogen Energy 21(8), 643650(1996).
14.Bamwenda, G.R., Tsubota, S., Nakamura, T. and Harura, M., J. Photochem. Photobiol. A 89, 177 (1995).
15.Sakata, T., Kawai, T., Chem. Phys. Lett. 80, 341(1981).
16.Zalas, M., Laniecki, M., Sol. Energy Mater. Sol. Cells 89, 287(2005).
17.Bamwenda, G.R., Tsubota, S., Kobayashi, T., Haruta, M., J. Photochem. Photobiol. A 59, 77 (1994).
18.Enea, O., Electrochim. Acta 31, 405(1986).
19.St. John, M.R., Furgala, A.J., Sammells, A.F., J. Phys. Chem. 87, 801(1983).
20.Li, Y., Lu, G., Li, S., Appl. Catal. A 179, 214 (2001).
21.Hashimoto, K., Kawai, T., Sakata, T., J. Phys. Chem. 88 (1984) 4083.
22.Comini, E., Faglia, G., Sberveglieri, G., Li, Y., Wlodarski, W., Ghantasala, M.K.. Sensors and Actuators B 64, 169174(2000).
23.Li, Y., Xie, Y., Peng, S., Lu, G., Li, S.. Chemosphere 63, 13121318(2006).
24.Fu, X., Long, J., Wang, X., Leungb, Dennis Y.C., Ding, Z., Wu, L., Zhang, Z., Li, Z., Fu, X., International Journal of Hydrogen Energy 33, 64846491(2008).
25.Patsoura, A., Kondarides, D. I., Verykios, X. E., Catalysis Today 124, 94102, (2007)
26.Du, G.H., Chen, Q., Che, R.C., Yuan, Z.Y., Peng, L.M., Appl. Phys. Lett. 79, 3702 (2001).
27.Xing, C., Jing, D., Liu, M., Guo, L., Materials Research Bulletin 44, 442445(2009).
28.Yang, J., Jin, Z., Wang, X., Li, W., Zhang, J., Zhang, S., Guo, X., Zhang, Z., J. Chem. Soc., Dalton Trans. 14, 3898(2003).
29.Chatterjee, D., Dasgupta, S., J. Photochem. Photobiol. C 6, 186(2005).
30.Linsebigler, A.L., Lu, G., Yates, J. T. Jr., Chem. Rev. 95, 735(1995).
31.Dey, G. R., Nair, K. N. R., Pushpa, K. K., Journal of Natural Gas Chemistry 18, 5054(2009).
Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

MRS Online Proceedings Library (OPL)
  • ISSN: -
  • EISSN: 1946-4274
  • URL: /core/journals/mrs-online-proceedings-library-archive
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×

Keywords

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed