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Photocross-Linked Second Order Nonlinear Optical Polymers

  • Y. M. Chen (a1), B. K. Mandal (a2), J. Y. Lee (a2), P. Miller (a1), J. Kumar (a1) and S. Tripathy (a2)...
Abstract

We report a novel method to obtain stable second order nonlinear optical (NLO) properties in polymeric thin films. Photocross-linking between the NLO active molecules and a photoreactive polymer is achieved by UV irradiation subsequent to poling. The thin film exhibits a nonlinear coefficient d33of 16.5 pm/V at a doping level of 20% by weight of NLO active molecules and possesses quite stable second order nonlinear optical properties

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1. Mandal, B. K., Chen, Y. M., Jeng, R. J., Takahashi, T., Huang, J. C., Kumar, J., and Tripathy, S., Eur. Polym. J. (in press).
2. Chen, Y. M., Rahaman, A. K. M., Takahashi, T., Mandal, B. K., Lee, J. Y., Kumar, J., and Tripathy, S. K., J. Polym. Sci., Polym. Phys. Edn. to be sumitted.
3. Singer, K. D., Sohn, J. E., and Lalama, S. J., Appl. Phys. Lett. 49, 248 (1986).
4. Mortazavi, M. A., Knoessen, A., Kowel, S. T., Higgins, B. G., and Dienes, A., J. Opt. Soc. Am. B 6, 733 (1989).
5. Mandal, B. K., Chen, Y. M., Lee, J. Y., Kumar, J., and Tripathy, S., Appl. Phys. Lett. (submitted)
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MRS Online Proceedings Library (OPL)
  • ISSN: -
  • EISSN: 1946-4274
  • URL: /core/journals/mrs-online-proceedings-library-archive
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