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Preparation and Characterization of Epitaxial KNBO3 Thin Films by a Sol-Gel Method

Published online by Cambridge University Press:  21 February 2011

Hidehiro Endo
Affiliation:
Advanced Materials & Technology Research Laboratories, Nippon Steel Corp., 1618 Ida, Nakahara-ku, Kawasaki 211, JAPAN
M. J. Cima
Affiliation:
Department of Materials Science & Engineering, Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, MA 02139
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Abstract

Epitaxial formation of KNbO3 films on several substrates was examined. The films were prepared by a sol-gel process using potassium ethoxide and niobium pentaethoxide. Hetero-epitaxial KNbO3 films with (100) orientation were successfully obtained both on MgO (100) and SrTiO3 (100) substrates by heat treatments above 700°C, while polycrystalline KNbO3 were formed on Si (111) substrates. Higher temperatures and extended soaking time promoted the grain growth of KNbO3 and KNbO3 films with improved surface morphologies (smoother surfaces) could be obtained by controlling heat treatment parameters.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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References

[1] Sheppard, L.M., Am. Ceram. Soc. Bull., 71, 8595 (1992)Google Scholar
[2] Fukushima, J., Kodaira, K. and Matsushita, T., ibid., 55, 1064–65 (1976)Google Scholar
[3] Tsuchiya, T., Kawano, T., Sei, T. and Hatano, J., J. Jap. Ceram. Soc., 98 743–48 (1990)Google Scholar
[4] Budd, K.D., Dey, S.K. and Payne, D.A., Brit. Ceram. Soc. Proc., 36, 107–21 (1985)Google Scholar
[5] Idem; Better Ceramics Through Chemistry II, Mater. Res. Soc., Pittsburgh, PA (1986) pp. 711–16Google Scholar
[6] Chen, C., Ryder, D.F. Jr., and Spurgeon, W.A., J. Am. Ceram. Soc., 72, 1495–98 (1989)Google Scholar
[7] Suzuki, T., Matsuki, M., Matsuda, Y., Kobayashi, K. and Takahashi, Y., J. Jap. Ceram. Soc., 98, 754–58 (1990)Google Scholar
[8] Dey, S.K., Budd, K.D. and Payne, D.A., IEEE Trans. Ultrason. Ferroelect. Freq. Contr., 35, 8081 (1988)Google Scholar
[9] Yamashita, H., Yoko, T. and Sakka, S., J. Am. Ceram. Soc., 74, 1668–74 (1991)CrossRefGoogle Scholar
[10] Eichorst, D.J. and Payne, D.A., Better Ceramics Through Chemistry III, Mater. Res. Soc., Pittsburgh, PA (1988) pp. 773-78Google Scholar
[11] Yanovskaya, M.I., Turevskaya, E.P., Leonov, A.P., Ivanov, S.A., Kolganova, N.V., Stefanovich, S.Y., Turova, N.Y. and Venevtsev, Y.N., J. Mater. Sci., 23, 395–99 (1988)Google Scholar
[12] Partlow, D.P. and Greggi, J., J. Mater. Res., 2, 595605 (1987)Google Scholar
[13] Hirano, S. and Kato, K., Adv. Ceram. Mater., 3, 503506 (1988)Google Scholar
[14] Idem, Processing Science of Advanced Ceramics, Mater. Res. Soc., Pittsburgh, PA (1989) pp. 181–90Google Scholar
[15] Wu, E.T., Kuang, A.X. and MacKenzie, J.D., Proc. of the Sixth IEEE International Sympo sium on Applications of Ferroelectrics, 388–90 (1986)Google Scholar
[16] Swartz, S.L., Melling, P.J. and Grant, C.S., Optical Materials: Processing and Science, Mater. Res. Soc. Proc., 152, Pittsburgh, PA (1989) pp. 227–32Google Scholar
[17] Amini, M.M. and Sachs, M.D., Mater. Res. Soc. Symp. Proc. 180, 675–83 (1990)CrossRefGoogle Scholar
[18] Cheng, C.H., Xu, Y. and Mackenzie, J.D., Mater. Res. Soc. Symp. Proc. 271, 383–88 (1992)Google Scholar