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Small Angle Neutron Scattering Study of Micellization of a Charged Copolymer in Aqueous Solutions

Published online by Cambridge University Press:  26 February 2011

L. B. Shih ,
M. H. Luccas ,
S. H. Chen  and
T. L. Lin
L. B. Shih
Affiliation:
Polymer Research Department, S. C. Johnson & Son, Inc., Racine, WI 53403
M. H. Luccas
Affiliation:
Polymer Research Department, S. C. Johnson & Son, Inc., Racine, WI 53403
S. H. Chen
Affiliation:
Nuclear Engineering Department, MIT, Cambridge, MA 02139
T. L. Lin
Affiliation:
Nuclear Engineering Department, MIT, Cambridge, MA 02139
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Abstract

We present an asymototic analysis of small angle neutron scattering data of a comb-shaped charged copolymer, poly (1-octadecene-co-maleic anhydride), in D20. It is shown that at full ionization, the coRolymer self-asso iate to form cylindrical shape micelles with a radius 26Å and length 101 Å. The number of repeating units per micelle is calculated to be 200 and the hydration number 15 per repeating unit. The dimension of the cylinder remains approximately constant over the concentration range studied.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 79: Symposium F – Scattering, Deformation and Fracture in Polymers , 1986 , 429
Copyright
Copyright © Materials Research Society 1987

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References

1. Robb, I. D., in Surfactant Science Series, vol. II, edited by Lucassen-Reynders, E. H. (Marcel Dekker, New York 1981), p. 109.Google Scholar
2. Strauss, U. P., in Micellization, Solubilization and Microemulsions, Vol. II, edited by Mittal, K. L. (Plenum Press, New York 1977), p. 895.Google Scholar
3. Dubin, P. L. and Strauss, U. P., in Polyelectrolytes and Their Applications, edited by Rembaum, A. and Selegny, E., (D. Reidel Pubisher, Dordrecht-Holland, 1975), pp. 3–13.Google Scholar
4. Strauss, U. P., in Microdomains in Polymer Solutions, edited by Dubin, P. L., (Plenum Press, New York, 1985), pp. 1–12.Google Scholar
5. Martic, P. A., Harman, S. E. and Williams, J. L. R., in Solution Behavior of Surfactants - Theoretical and Applied Aspects, edited by Mittal, K. L. and Fendler, E. J., (Plenum Press, New York, 1980).Google Scholar
6. Shih, L. B., Luccas, M. H. and Warner, R. J., Polymer Preprints, 27, No. 2, 288 (1986).Google Scholar
7. Lin, T. L., Chen, S. H., Gabriel, N. E. and Roberts, M. F., J. Phys. Chem., January (1987).Google Scholar
8. Chen, S. H., Ann. Rev. Phys. Chem. 37, 351–99 (1986).Google Scholar
9. Glatter, O., in Small Angle X-Ray Scattering, edited by Glatter, O. and Kratky, O. (Academic Press, New York, 1982), p. 156.Google Scholar