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Solid State Reactions in Mechanically Deformed Composites in the Ni-Zr and the Ni-Ti Systems

Published online by Cambridge University Press:  21 February 2011

B. E. White ,
M. E. Patt  and
E. J. Cotts
B. E. White
Affiliation:
Department of Physics, Applied Physics and Astronomy State University of New York at Binghamton, Binghamton, NY 13901
M. E. Patt
Affiliation:
Department of Physics, Applied Physics and Astronomy State University of New York at Binghamton, Binghamton, NY 13901
E. J. Cotts
Affiliation:
Department of Physics, Applied Physics and Astronomy State University of New York at Binghamton, Binghamton, NY 13901
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Abstract

Differential scanning calorimetry and x-ray diffraction analysis were utilized to monitor solid state reactions in mechanically deformed Ni/Ti multilayered composites. Solid state reactions at temperatures less than = 650 K result in the formation of a highly disordered phase which is apparently amorphous.The subsequent nucleation and growth at higher temperatures of intermetallic compounds from the amorphous phase is examined. The relatively small thickness of amorphous material (less than 100 Å) which can be grown by solid state reaction in our Ni/Ti samples, combined with the indication that a disordered interface such as that produced by mechanical deformation facilitates these reactions in the Ni-Ti system, may provide some explanation for the relatively high degree of success experienced in the production of amorphous Ni- Ti by means of ball milling. Comparisons are made to results obtained in the Ni-Zr system.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 170: Symposium N – Interfaces in Composites , 1989 , 185
Copyright
Copyright © Materials Research Society 1990

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