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Solvent–Controlled Helicity in Self-Assembling Rosette Nanotubes

  • Ross S Johnson (a1), Takeshi Yamazaki (a2), Andriy Kovalenko (a3) and Hicham Fenniri (a4)
Abstract

A newly designed module was synthesized and found to self-assemble into rosette nanotubes (RN) in both water and methanol. Characterization using transmission electron microscopy (TEM) and scanning electron microscopy (SEM) established the formation of analogous RNs in both solvents. However, the chiroptical outcome of the assemblies, observed by circular dichrosim (CD) spectroscopy, was found to be mirror image based solely on the solvent used. Preliminary molecular modeling studies indicated the formation of M and P helical rosette nanotubes, in agreement with the experimental observations. This work represents the first example of solvent-controlled helicity in a self-assembling supramolecular system.

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1.Lorenzo, M. O., Baddeley, C. J., Muryn, C., and Raval, R., Nature 404, 376379 (2000).
2.(a) Kauranen, M., Veerbiest, T., Bouttoon, C., Teerenstra, M. N., Clays, K., Schouten, A. J., Nolte, R. J. M., and Persoons, A., Science 270, 966969 (1995). (b) T. Verbiest, S. V. Elshocht, M. Kauranen, L. Hellemans, J. Snauwaert, C. Nuckolls, T. J. Katz, and A. Persoons, Science 282, 913-915 (1998).
3.(a) Tanatani, A., Mio, M. J., and Moore, J. S., J. Am. Chem. Soc. 123, 17921793 (2001). (b) V. V. Borovkov, G. A. Hembury, and Y. Inoue, Acc. Chem. Res. 37, 449–459 (2004). (c) J. M. Rivera, S. L. Craig, T. Martin, and J. Jr. Rebek, Angew. Chem. Int. Ed. 39, 2130– 2132 (2000). (d) Y. Kikuchi, K. Kobayashi, and Y. Aoyama, J. Am. Chem. Soc. 114, 1351–1358 (1992).
4.(a) Iftime, G., Labarthet, F. L., Natanshon, A., and Rochon, P., J. Am. Chem. Soc. 122, 1264612650 (2000). (b) A. E. Holmes, H. Barcena, and J. W. Canary, Adv. Supramol. Chem. 8, 43–78 (2002). (c) J. W. Canary, and S. Zahn, TRENDS Biotech. 19, 251–255 (2001). (d) J. Tabei, R. Nomura, F. Sanda, and T. Masuda, Macromolecules 37, 1175– 1179 (2004).
5.Mateos-Timoneda, M. A., Crego-Calama, M., Reinhoudt, D. R., Chem. Soc. Rev. 33, 363372 (2004).
6.(a) Fenniri, H., Deng, B. L., Ribbe, A. E., Hallenga, K., Jacob, J., and Thiyagarajan, P., Proc. Natl. Acad. Sci. USA. 99, 64876492 (2002). (b) J. G. Moralez, J. Raez, T. Yamazaki, R. K. Motkuri, A. Kovalenko, and H. Fenniri, J. Am. Chem. Soc. 127, 83078309 (2005). (c) H. Fenniri, B. L. Deng, and A. E. Ribbe, J. Am. Chem. Soc. 124, 11064-11072 (2002).
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  • EISSN: 1946-4274
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