Hostname: page-component-8448b6f56d-xtgtn Total loading time: 0 Render date: 2024-04-20T01:30:21.777Z Has data issue: false hasContentIssue false
  • English
  • Français

The Structure and Properties of Vicinal Water

Published online by Cambridge University Press:  16 February 2011

Frank M. Etzler ,
James J. Conners  and
Russell F. Ross
Frank M. Etzler
Affiliation:
Surface and Colloid Science Section, Institute of Paper Science and Technology, Atlanta, GA 30318.
James J. Conners
Affiliation:
Surface and Colloid Science Section, Institute of Paper Science and Technology, Atlanta, GA 30318.
Russell F. Ross
Affiliation:
Surface and Colloid Science Section, Institute of Paper Science and Technology, Atlanta, GA 30318.
Get access

Abstract

The properties of water near surfaces are known to differ from those of the bulk. For instance, in 140 A diameter silica pores the density has been found to be 3% lower than that of the bulk while the heat capacity is 25% greater than that the bulk. Etzler [15] has proposed a statistical thermodynamic model for vicinal water. This model has been able to correlate a number of thermodynamic properties of water in silica pores. Furthermore, some of the microscopic implications of the model have been found to be consistent with molecular dynamics simulations. Here we discuss the results of a statistical geometric analysis of a molecular dynamics simulation which, as first suggested by Roentgen (1892), indicates that water indeed exists in “bulky” and “dense” states. Furthermore, recent results concerning the temperature dependence of the heat capacity of water in silica pores is discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 197: Symposium U – Materials Interactions Relevant to the Pulp, Paper and Wood Industries , 1990 , 185
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Hardy, W.B., Proc. Roy. Soc. London Ser. A., 86, 610 (1912).Google Scholar
2. Henniker, J.C., Rev. Mod. Phys. 21, 322 (1949).Google Scholar
3. Drost-Hansen, W., Ind. Eng. Chem., 61, 10 (1969).Google Scholar
4. Drost-Hansen, W., in Chemistry of the Cell Interface, Part B, edited by Brown, H.D. (Academic Press, New York, 1971).Google Scholar
5. Etzler, F.M. and Drost-Hansen, W., in Cell Associated Water edited by Drost-Hansen, W. and Clegg, J.S. (Academic Press, New York, 1979)Google Scholar
6. Etzler, F.M. and Drost-Hansen, W., Croat. Chem. Acta, 56, 563 (1983).Google Scholar
7. Etzler, F. M. in Water Relations in Foods, edited by Levine, H. and Slade, L. (Plenum Press, New York, 1991).Google Scholar
8. Low, P.F., Soil Sci. Soc. Amer. J. 43, 651 (1979).Google Scholar
9. Peschel, G. and AdIfinger, K.H., Naturweissenschaften 56, 558 (1969); Z. Naturforsch. A, 26, 707 (1971); J. Colloid and Interface Sci., 34, 505 (1972)Google Scholar
10. Etzler, F.M. and Fagundus, D.M., J. Colloid and Interface Sci. 93, 585 (1983); 115. 513 (1987).Google Scholar
11. Peschel, G., Beloucheck, P., Muller, M.M., Muller, M.R. and Koine, R.. Colloid & Polymer Sci. 260. 444 (1982).Google Scholar
12. Braun, C.V. and Drost-Hansen, W. in Colloid & Interface Sci., Vol. II edited by Kerker, M. (Academic Press, New York, 1976).Google Scholar
13. Cianci, J.J., M.S. Thesis, University of Miami, 1981.Google Scholar
14. Etzler, F.M., Langmuir 4, 878 (1988).Google Scholar
15. Etzler, F.M., J. Colloid & Interface Sci., 92, 43 (1983).Google Scholar
16. Stey, G.C., Ph.D. Dissertation, University of Pittsburgh, 1967.Google Scholar
17. Wiggins, P.M., Biophys. J., 13, 385 (1973); Clin. Exp. Pharmacol. Physiol. 2, 121 (1975).Google Scholar
18. Hurtado, R.M. and Drost-Hansen, W. in Cell Assosciated Water, edited by Drost-Hanscn, W. and Clegg, J.S. (Academic Press, New York 1979).Google Scholar
19. Etzler, F.M. and Liles, T.L., Langmuir 2, 797 (1986).Google Scholar
20. Stanley, H.E. and Teixeira, J., J. Chem. Phys. 73, 404 (1980).Google Scholar
21. Etzler, F.M., Halcomb, R.A., Ross, R.F., to be published 1991.Google Scholar
22. Roentegen, W.K., Ann. Phys. (Wein) 45, 91 (1892).Google Scholar
23. Lumry, R. and Rajender, S., Biopolymers 9, 1125 (1970).Google Scholar
24. Etzler, F.M. and Conners, J.J., Langmuir, in press 1990.Google Scholar
25. Goring, D.A.I., Pulp and Paper Mag. 62, T519 (1966).Google Scholar
26. Weatherwax, R.C. and Tarkow, H., Forest Prod. J. 18, 44 (1968).Google Scholar