Hostname: page-component-848d4c4894-ndmmz Total loading time: 0 Render date: 2024-05-15T04:11:10.291Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of New Iron and Zinc Phosphate Materials with Open Framework

Published online by Cambridge University Press:  11 February 2011

Yanning Song ,
Natasha A. Chernova ,
Peter Y. Zavalij  and
M. Stanley Whittingham
Yanning Song
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902–6016
Natasha A. Chernova
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902–6016
Peter Y. Zavalij
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902–6016
M. Stanley Whittingham
Affiliation:
Department of Chemistry and Institute for Materials Research, State University of New York at Binghamton, Binghamton, NY 13902–6016
Get access

Abstract

Open framework materials are of great interest due to the applications in the fields of adsorption, ion exchange, molecular sieving and catalysis. Metal phosphates are very important open framework materials due to the rich crystallography. Several new iron phosphate materials have been synthesized and characterized in our lab. Two new iron (III) phosphates, FePO4, have been synthesized from careful dehydration of hydrothermally prepared monoclinic and orthorhombic hydrated phosphates FePO4·2H2O. Reversible insertion and extraction of lithium into new iron phosphate hydroxide materials with 3-d rod-packing framework shows it to be an excellent intercalation material. Several other transition metals are also incorporated successfully into these compounds without changing the structure. With ethylenediamine as template, 1-D chain, 2-D layered and 3-D network iron phosphate materials were synthesized. The structure, electrochemical and magnetic properties of these compounds were studied. Meanwhile, two new zinc phosphates with methylammonium templates were also synthesized. There are infinite Zn-O-Zn chains in one of the compounds, while closed 4-member circuits made up from Zn-O-Zn linkage present in the other.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 755: Symposium DD – Solid-State Chemistry of Inorganic Materials IV , 2002 , DD3.9
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Ferey, G., Cheetham, A. K., Science 283, 125 (1999).Google Scholar
2. Cheetham, A. K., Ferey, G., Loiseau, T. and Loiseau, T., Angew. Chem., Int. Ed. Engl. 38, 3268 (1999).Google Scholar
3. Moore, P. B., Am. Mineral. 55, 135 (1970).Google Scholar
4. Ng, H. N. and Calvo, C., Can. J. Chem. 53, 2064 (1975).Google Scholar
5. Kinomura, N., Shimada, M., and Koizumi, M., Mater. Res. Bull. 11, 457 (1976).Google Scholar
6. Andersson, A. S., Kalska, B., Haggstrom, L., Thomas, J. O., Solid State Ionics 130, 41 (2000).Google Scholar
7. Moore, P. B., Am. Mineral. 51, 168 (1966).Google Scholar
8. Gay, H. D., Rev. Asoc. Geol. Argent. 23, 279 (1968).Google Scholar
9. Song, Y., Zavalij, P. Y., Suzuki, M. and Whittingham, M. S., Inorg. Chem. 41, 5778 (2002).Google Scholar
10. Lii, K-W., Huang, Y-F., Zima, V., Huang, C-Y., Lin, H-M., Jiang, Y-C., Liao, F-L. and Wang, S-L., Chem. Mater. 10, 2599 (1998) and references herein.Google Scholar
11. Song, Y., Zavalij, P. Y., and Whittingham, M. S., J. Mater. Chem. (submitted) and references herein.Google Scholar
12. Song, Y., Chernova, N. A., Zavalij, P. Y., and Whittingham, M. S., J. Solid State Chem., in press.Google Scholar
13. Song, Y., Yang, S., Zavalij, P. Y. and Whittingham, M. S., Mater. Res. Bull. 37, 1249 (2002).Google Scholar
14. Song, Y., Zavalij, P. Y., and Whittingham, M. S., Electrochem. Comm. (submitted).Google Scholar