Hostname: page-component-cb9f654ff-kl2l2 Total loading time: 0 Render date: 2025-08-20T05:31:12.406Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of Some New Metal-Containing Polymers for Third Order Nonlinear Optical Applications

Published online by Cambridge University Press:  10 February 2011

Mamoun M. Bader ,
Phuong-Truc T. Pham ,
Angela Molli ,
Justin Moser ,
Kevin Meyres  and
Leslie Albright
Mamoun M. Bader
Affiliation:
Department of Chemistry, The Pennsylvania State University, Hazleton, PA 18201
Phuong-Truc T. Pham
Affiliation:
Department of Chemistry, The Pennsylvania State University, Hazleton, PA 18201
Angela Molli
Affiliation:
Department of Chemistry, The Pennsylvania State University, Hazleton, PA 18201
Justin Moser
Affiliation:
Department of Chemistry, The Pennsylvania State University, Hazleton, PA 18201
Kevin Meyres
Affiliation:
Department of Chemistry, The Pennsylvania State University, Hazleton, PA 18201
Leslie Albright
Affiliation:
Department of Chemistry, The Pennsylvania State University, Hazleton, PA 18201
Get access

Abstract

We report here our preliminary results on the synthesis and characterization of a new family of metal-containing polymers incorporating 8-hydroxyquinoline. These polymers have the following structural features: a metal center, a chromophore, and a flexible spacer group with variable length. These structural features allow us to have an appreciable degree of control over various physical properties of these materials. We report on three different types of polymers: polyethers, polyesters, and polyamides. The chromophores in these polymers were incorporated in the backbone and in one case as a side chain of polyesters.

Information

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 561: Symposium F – Organic Nonlinear Optical Materials and Devices , 1999 , 93
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

[1] (a) Sheats, C. E., Pittman, C. U., Zeldin, M., Currell, B., Eds. Inorganic and Metal-Containing Polymeric Materials, Plenum, New York, 1990; (b) D. R. Kanis, P. G. Lacroix, M. A. Ratner, T. J. Marks, J. Amer. Chem. Soc.116, p. 10089, 1994 and references therein.Google Scholar
[2] (a) Horowitz, E., Perros, T. P., J Inorg. Nucl. Chem., 26, p. 26, 1964; (b) J. S. Oh, J. C. Bailar, Jr., J. Inorg. Nucl. Chem., 24, p. 1225, 1962; (c) V. V. Korshak, S. V. Vinogradova, T. M. Babchinister, Polym. Sci. (USSR) Engl. Transl., 2, p. 344, 1960.Google Scholar
[3] Berg, E. W., Alam, A., Anal. Chim Acta, 27, p. 27, 1962.Google Scholar
[4] Eichhorn, G. L., Marchand, N. D., J. Amer. Chem. Soc.78, p. 78, 1956.Google Scholar
[5] Bader, M. M., Hamada, T., Kakuta, A., J. Amer. Chem. Soc. 114, p. 114, 1992; M. M. Bader, SPIE Proc. 3473, p.112, 1998Google Scholar
[6] (a) Tang, C. W., Van, S. A. Slyke, Appl. Phys. Lett., 51, p. 51, 1987; (b) C. W. Tang, S. A. Van Slyke, J. Appl. Phys., 65, p. 3610, 1989; (c) C. Aachi, S. Tokito, M. Morikawa, T. Tsutsui, S. Saito, Springer Proc. In Phys., 38, p. 358, 1989.Google Scholar
[7] Bader, M. M., Phosphorous, Sulfur and Silicon, 116, p. 116, 1996.Google Scholar
[8] Charles, R. G., Langer, A., J. Phys. Chem, 63, p. 63, 1959.Google Scholar