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Synthesis and Microwave Characterization of Polypyrrole-PVC Blends

Published online by Cambridge University Press:  25 February 2011

F. Jousse
Affiliation:
Commissariat à L'Energie Atomique Centre d'Etudes du Ripault B.p. 16 37260 Monts - France
P. Hourquebie
Affiliation:
Commissariat à L'Energie Atomique Centre d'Etudes du Ripault B.p. 16 37260 Monts - France
C. Deleuze
Affiliation:
Commissariat à L'Energie Atomique Centre d'Etudes du Ripault B.p. 16 37260 Monts - France
L. Olmedo
Affiliation:
Commissariat à L'Energie Atomique Centre d'Etudes du Ripault B.p. 16 37260 Monts - France
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Abstract

ABSTRACT.: Thermoplastic blends have been created by in situ growth of polypyrrole in an insulating PVC matrix. This type of synthesis gives a level of conductivity of the order of 10−5 to 1 S/cm for concentrations of less than 15% (in weight). A study of the synthetic conditions shows that the reaction parameters (solvent, nature of oxidizing agent) control the eventual properties of the blend (structure, conductivity level). The microwave characterization of these materials has allowed us to establish a direct link between the method of processing and the radioelectric properties.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

[1] Ueno, T. et al., J. Photopolymer Sci. Technol. (1988), 1, 338345 Google Scholar
[2] Paoli, M., Woltman, R. J., Diaz, A. F., and Bargon, J., J. Polymer Sci., Polymer Chem. Educ. (1985), 23, 1687 Google Scholar
[3] Myers, R. E., U. S. p. 4680 236Google Scholar
[4] Myers, R. E., U. S. p. 4617 353Google Scholar
[5] Myers, R. E., J. Electron. Mater. (1986), 2, 61 Google Scholar
[6] Rapi, S., Bocchi, V., and Gardini, G. P., Synth. Met. (1988) 24, 217- 221Google Scholar
[7] Legros, F. and Fourrier-Lamer, A., Math. Res. Bull (1984), 19, 11091117 Google Scholar
[8] Javadi, H. H. S. et al., Mol. Cryst. Lia. Cryst. (1988), 160, 225233 Google Scholar
[9] Javadi, H. H. S. et al., Synth. Met. (1989), E 409 - E 416Google Scholar
[10] Epstein, A. J. and Macdiarmid, A. G. in ‘Science and Applications of Conductive Polymers’, Adam HILGER (1991)Google Scholar
[11] Drago, R. S. and Percell, K. K., in ‘Non-Aqueous Solvent Systems’, Academic Press (1965), 211249 Google Scholar
[12] Kang, E. T., Neoh, K. G., and Ong, Y. K., Synth. Met. (1990), 39, 6980 Google Scholar
[13] Slama, M., Thesis, Paris, 1989 Google Scholar
[14] Hourquebie, P., Olmedo, L., and Deleuze, C., ANTEC'91, 774778 Google Scholar
[15] Wessling, B., Nimtz, G., et al., to be published in Synth. Met.Google Scholar