Hostname: page-component-8448b6f56d-wq2xx Total loading time: 0 Render date: 2024-04-24T07:01:56.167Z Has data issue: false hasContentIssue false

Synthesis and Properties of Molecular Fragments of Metal Chalcogenides

Published online by Cambridge University Press:  15 February 2011

Michael L. Steigerwald*
Affiliation:
AT&T Bell Laboratories, 600 Mountain Avenue, Murray Hill, NJ 07974
Get access

Abstract

In this manuscript we describe several approaches to the preparation of molecule-sized fragments of inorganic solids. The first is the arrested precipitation of metal selenides in reverse micelles; the second is the arrested pyrolysis of molecular precursors to II–VI compounds; and the third is the chemical moderation of molecules-to-solids reactions.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Steigerwald, M. L. and Brus, L. E., Ann. Rev. Mat. Sci., 19, 471 (1989).Google Scholar
2. Bawendi, M. G., Steigerwald, M. L. and Brus, L. E., Ann. Rev. Phys. Chem., 41, 477 (1990).CrossRefGoogle Scholar
3. Steigerwald, M. L., Alivisatos, A. P., Gibson, J. M., Harris, T. D., Kortan, R., Muller, A. J., Thayer, A. M., Duncan, T. M., Douglass, D. C. and Brus, L. E., J. Amer. Chem. Soc., 110, 3046 (1988).CrossRefGoogle Scholar
4. (a) Brennan, J. G., Siegist, T., Carroll, P. J., Stuczynski, S. M., Brus, L. E. and Steigerwald, M. L., J. Amer. Chem. Soc., 111, 4141 (1989). (b) J. G. Brennan, T. Siegrist, P. J. Carroll, S. M. Stuczynski, P. Reynders, L. E. Brus and M. L. Steigerwald, Chem. Mater., 2, 403 (1990).CrossRefGoogle Scholar
5. (a) Thayer, A. M., Steigerwald, M. L., Duncan, T. M., Douglass, D. C., Phys. Rev. Lett., 60. 2673 (1988). (b) A. P. Alivisatos, A. L. Harris, N. J. Levinos, M. L. Steigerwald and L. E. Brus, J. Chem. Phys., 89, 4001 (1988). (c) A. P. Alivisatos, T. D. Harris, P. J. Carroll, M. L. Steigerwald and L. E. Brus, J. Chem. Phys., 90, 3463 (1989). (d) M. G. Bawendi, A. R. Kortan, M. L. Steigerwald and L. E. Brus, J. Chem. Phys., 91, 7282 (1989).Google Scholar
6. Brennan, J. G., Siegrist, T., Stuczynski, S. M. and Steigerwald, M. L., J. Amer. Chem. Soc., 112, 9233, (1990).CrossRefGoogle Scholar
7. Stuczynski, S. M. and Steigerwald, M. L., unpublished results.Google Scholar
8. (a) Steigerwald, M. L., Siegrist, T. and Stuczynski, S. M., Inorg. Chem., 30, 2256 (1991). (b) M. L. Steigerwald, T. Siegrist and S. M. Stuczynski, Inorg. Chem., 30,4940 (1991).Google Scholar
9. Brennan, J. G., Siegrist, T., Stuczynski, S. M. and Steigerwald, M. L., J. Amer. Chem. Soc., 111 9240 (1989).CrossRefGoogle Scholar
10. Nomikou, Z., Schubert, B., Hoffmann, R. and Steigerwald, M. L., Inorg. Chem., 31, 2201 (1992).Google Scholar