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Synthesis and Structure of a Metal-Organic Solid Having the Cadmium(II) Sulfate Net

Published online by Cambridge University Press:  15 February 2011

O. M. Yaghi ,
Hailian Li  and
M. O'Keeffe
O. M. Yaghi
Affiliation:
Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering, Arizona State University, Tempe, AZ 85287–1604, oyaghi@asu.edu
Hailian Li
Affiliation:
Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering, Arizona State University, Tempe, AZ 85287–1604, oyaghi@asu.edu
M. O'Keeffe
Affiliation:
Department of Chemistry and Biochemistry, Goldwater Center for Science and Engineering, Arizona State University, Tempe, AZ 85287–1604, oyaghi@asu.edu
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Abstract

Reaction of silver(I) nitrate and hexamethylenetetramine (HMTA) gives crystals of Ag2(HMTA)(NO3)2, which was formulated by elemental microanalysis and a single crystal x-ray study. Its Ag2(HMTA) open-framework is the first example of a decorated CdSO4net. The relative orientation of the tetrahedral HMTA building blocks in this structure point to numerous opportunities toward constructing novel chiral and polar porous frameworks.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 453: Symposium R – Solid State Chemistry of Inorganic Materials , 1996 , 127
Copyright
Copyright © Materials Research Society 1997

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References

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