Skip to main content
×
×
Home

Synthesis of Poly(Methylmethacrylate) Latex with Enhanced Rigidity through Surfactant Control

  • Alex Wu (a1), Kwun Lun Cho (a2), Irving Ian Liaw (a3), Hua Zhang (a4) and Robert Lamb (a5)...
Abstract

Water-based polymer latexes have attracted much attention since their invention in the early 1950s. Its advantages for both general health and the environment were recognized as they emit far less volatile organic compounds (VOCs) than their solvent-based counterparts.

The performance of latex paints and coatings is directly proportional to the ease of particle deformation. This is the main driving force for the paints and coatings industry to focus its research efforts towards understanding its mechanism.

In contrast, little has been published with respect to enhancing latex's resistance against deformation despite such needs in applications such as templating porous ceramics for catalysis and biomaterial engineering. Specifically, the latex's resistance to deformation is crucial to retain a network of uniform pores for applications relating to enzyme immobilization and materials reinforcement.

The current study reports increased heat-resistance observed in latexes when synthesized using a rigid surfactant, dimethyl siloxane – ethylene oxide block copolymer (PDMS-PEO). The film formation process for this latex was deduced using atomic force microscopy and subsequent roughness analysis. A comparative study using a non-ionic long-chain hydrocarbon surfactant, morpholine oleate, was also conducted.

Copyright
References
Hide All
1. Padget, J.C., J Coatings Technol., 66, 89 (1994)
2. Sivakumar, M., Panduranga, R.., J. Appl. Polym. Sci., 83, 3045 (2002)
3. Guo, T. et al., J Non-Crystalline Solids, 353, 2893 (2007)
4. Harkins, W. D., Stearns, R. S., J. Chem. Phys., 14, 215(1947)
5. Keddie, J.L, Mat. Sci. and. Eng., 21, 101 (1997)
6. Millipore, ™, Millipore – Product Detail, viewed 01 Nov 2008, http://www.millipore.com/catalogue/item/sims000ge
Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

MRS Online Proceedings Library (OPL)
  • ISSN: -
  • EISSN: 1946-4274
  • URL: /core/journals/mrs-online-proceedings-library-archive
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×

Keywords

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed