Hostname: page-component-7bb8b95d7b-s9k8s Total loading time: 0 Render date: 2024-09-20T00:36:23.860Z Has data issue: false hasContentIssue false
  • English
  • Français

Theories of Corrosion as Applied to Preservation of Archaeological Ceramics

Published online by Cambridge University Press:  28 February 2011

R.L. Schulz ,
D.E. Clark  and
D.C. Folz
R.L. Schulz
Affiliation:
University of Florida Department of Materials Science & Engineering Gainesville, FL 32611
D.E. Clark
Affiliation:
University of Florida Department of Materials Science & Engineering Gainesville, FL 32611
D.C. Folz
Affiliation:
University of Florida Department of Materials Science & Engineering Gainesville, FL 32611
Get access

Abstract

An understanding of corrosion processes is beneficial in the preservation of ancient ceramic artifacts. A wealth of information is available on this topic in the materials science and engineering literature. Significant contributions to the corrosion literature have been made over the last 15 years due to the extensive research performed on nuclear wasteform systems. This paper will review the current state of understanding of aqueous corrosion of glasses. We will discuss how this information can be applied to some of the current issues in preservation of archaeological ceramics.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 267: Symposium J – Materials Issues in Art and Archaeology III , 1992 , 1015
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Wicks, G.G. and Bickford, D., Technology Review, pp. 51–58, Nov-Dec. (1989).Google Scholar
2. Wicks, G.G. “Nuclear Waste Glasses: Corrosion Behavior and Field Tests,” in Corrosionof Glass, Ceramics and Ceramic Superconductors, pp. 218–268 (Clark, D.E. and Zoitos, B.K., eds.) Noyes Publications, Park Ridge, NJ (1992).Google Scholar
3. Clark, D.E. and Zoitos, B.K., “Corrosion Testing and Characterization,” in Corrosion ofGlass, Ceramics and Ceramic Superconductors, pp. 51–102 (Clark, D.E. and Zoitos, B.K., eds.) Noyes Publications, Park Ridge, NJ (1992).Google Scholar
4. Lodding, A.R., “Characterization of Corroded Ceramics by SIMS,” in Corrosion of Glass, Ceramics and Ceramic Superconductors, pp. 103–122 (Clark, D.E. and Zoitos, B.K., eds.) Noyes Publications, Park Ridge, NJ (1992).Google Scholar
5. Lodding, A.R., Engstrom, E.U., Zoitos, B.K., Clark, D.E. and Wicks, G.G., “Elemental Depth Profiling of Nuclear Waste Glasses after Two Years Burial in a Salt Geology,"to be published in J. Am. Cer. Soc., (1992)Google Scholar
6. Schulz, R.L., Clark, D.E., Wicks, G.G. and Lodding, A.R., “Long Term Field Leaching Studies of Simulated Nuclear Waste Glass in Granite and Salt,” Scientific Basis for Nuclear Waste Management XV, Vol 257, (1992).Google Scholar
7. Tait, J.C., Hocking, W.H., Betteridge, J.S. and Bart, G., “Field Burial Results and SIMSAnalysis of the Chalk River Glass Blocks” Advances in Ceramics, Vol. 20; Nuclear Waste Management II, pp. 559–566, (Clark, D.E., White, W.B. and Machiels, A.J., eds.) American Ceramic Society (1986).Google Scholar
8. Lodding, A.R., Engstrom, E.U., Clark, D.E., Werme, L.O., and Wicks, G.G., “SIMSAnalysis of Leached Layers Formed on SRL Glasses During Burial,” Advances inCeramics, Vol. 20; Nuclear Waste Management II, pp. 559–566, (Clark, D.E., White, W.B. and Machiels, A.J., eds.) American Ceramic Society (1986).Google Scholar
9. Clark, D.E., Zhu, B.F., Robinson, R.S. and Wicks, G.G., “Preliminary Report on a Glass Burial Experiment in Granite,” Advances in Ceramics, Vol. 8; Nuclear Waste Management (Wicks, G.G. and Ross, W.A., eds.) pp. 324–336, American Ceramic Society (1984).Google Scholar
10. Hench, L.L., Zhu, B.F., Lodding, A.R., and Werme, L, “Stripa Burial: Time Dependence of Leaching,” in Advances in Ceramics, Vol. 20; Nuclear Waste Management II, pp. 583–590, (Clark, D.E., White, W.B. and Machiels, A.J., eds.) American Ceramic Society (1986).Google Scholar
11. Zhu, B.F., Clark, D.E., Lodding, A.R. and Wicks, G.G., Two-Year Leaching Behaviorof Three SRL Nuclear Waste Glasses in Granite,” in Advances in Ceramics, Vol. 20; Nuclear Waste Management II, pp. 591–600, (Clark, D.E., White, W.B. and Machiels, A.J., eds.) American Ceramic Society (1986).Google Scholar
12. Wicks, G.G. and Molecke, M.A. “WIPP/SRL In-Situ Testing Program,” in Advancesin Ceramics, Vol. 20; Nuclear Waste Management II, pp. 657–667, (Clark, D.E., White, W.B. and Machiels, A.J., eds.) American Ceramic Society (1986).Google Scholar
13. Lodding, A.R., Engstrom, E.U., Clark, D.E. and Wicks, G.G., “Quantitative Concentration Profiling and Element Balance in SRL Glass after Two Years inWIPP,” in Ceramic Transactions, Vol. 9, Nuclear Waste Management III, pp. 317–333, (Mellinger, G.B., ed.) bAmerican Ceramic Society (1990).Google Scholar
14. Ramsey, W.G. and Wicks, G.G., “WIPP/SRL In-Situ Tests; Compositional Correlations of MIIT Waste Glasses in Ceramic Transactions, Vol. 9, Nuclear Waste Management III, pp. 257–270, (Mellinger, G.B., ed.) American Ceramic Society (1990).Google Scholar
15. Van Iseghem, P., Timmermans, W., Debruyn, W., Dresselaers, J. and Neerdael, B., “In-Situ Testing of Nuclear Waste Forms in an Underground Laboratory in Clay,’ in Advances in Ceramics, Vol. 20; Nuclear Waste Management II, pp. 649–656, (Clark, D.E., White, W.B. and Machiels, A.J., eds.) American Ceramic Society (1986).Google Scholar
16. Wallace, R.M. and Wicks, G.G., “Leaching Chemistry of Defense Borosilicate Glass,” in Mat. Res. Soc. Symp. Proc., Vol. 15, pp. 23–28, Elsevier Science Publishing Co., Inc. (1983).Google Scholar
17. Grambow, B., “Geochemical Approach to Glass Dissolution,” in Corrosion of Glass, Ceramics and Ceramic Superconductors, pp. 124–152 (Clark, D.E. and Zoitos, B.K., eds.) Noyes Publications, Park Ridge, NJ (1992).Google Scholar
18. Grambow, B. and Strachan, D.M., “Leach Testing of Waste Glasses Under Near-Saturation Conditions,” Mat. Res. Soc. Symp. Proc., Vol. 26, pp. 623–634, Elsevier Science Publishing Co., Inc. (1984).Google Scholar
19. Grambow, B., Hermansson, H.P., Bjomer, I.K. and Christensen, H., “Reaction of Nuclear Waste Glass with Slowly Flowing Solutions,” Advances in Ceramics, Vol. 20: Nuclear Waste Management II, pp. 465–474, American Ceramic Society, Westerville, OH (1986).Google Scholar
20. Jantzen, C.M., ‘Thermodynamic Approach to Glass Corrosion,” in Corrosion of Glass, Ceramics and Ceramic Superconductors, pp. 153–215 (Clark, D.E. and Zoitos, B.K., eds.) Noyes Publications, Park Ridge, NJ (1992).Google Scholar
21. Jantzen, C.M. and Plodinec, M.J., ‘Thermodynamic Model of Natural, Medieval and Nuclear Waste Glass Durability,” J. Non-Cryst. Solids, 67, pp. 207–233 (1984).Google Scholar
22. Clark, D.E. A Durability Evaluation of Soda-Lime-Silica Glasses Using Electron Microprobe Analysis, Infrared Reflection Spectroscopy and Other Techniques, PhDDissertation, University of Florida, 1976.Google Scholar
23. Vandiver, P.B., “Corrosion and Conservation of Ancient Glass and Ceramics,” in Corrosion of Glass, Ceramics and Ceramic Superconductors, pp. 393–430 (Clarkand, D.E. Zoitos, B.K., eds.) Noyes Publications, Park Ridge, NJ (1992).Google Scholar
24. Oppenheim, L.A., Glass and Glassmaking in Ancient Mesopotamia, Corning Museum of Glass Press, Corning, NY (1970).Google Scholar