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Transient Structural Relaxation and Melting Temperature of Amorphous Silicon

Published online by Cambridge University Press:  26 February 2011

W. C. Sinke
Affiliation:
Central Research Laboratory, Hitachi Ltd., P.O. Box 2, Kokubunji, Tokyo 185, Japan.
T. Warabisako
Affiliation:
Central Research Laboratory, Hitachi Ltd., P.O. Box 2, Kokubunji, Tokyo 185, Japan.
M. Miyao
Affiliation:
Central Research Laboratory, Hitachi Ltd., P.O. Box 2, Kokubunji, Tokyo 185, Japan.
T. Tokuyama
Affiliation:
Central Research Laboratory, Hitachi Ltd., P.O. Box 2, Kokubunji, Tokyo 185, Japan.
S. Roorda
Affiliation:
FOM-Institute for Atomic- and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands.
F. W. Saris
Affiliation:
FOM-Institute for Atomic- and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands.
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Abstract

The structure of ion-implanted a-Si has been studied using Raman spectroscopy. It is shown that the average bond-angle distortion and the strain energy stored in the random network vary drastically upon annealing. Relaxation is enhanced in the case of heating by laser irradiation. The results imply that the apparent melting temperature of a-Si may vary from one experiment to another, depending on the heating rate and -method.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

[1] Bagley, B.G. and Chen, H.S. in Laser-Solid Interactions and Laser Processing – 1978, edited by Ferris, S.D., Leamy, H.J. and Poate, J.M. (AIP Conf. Proc. No. 5D, New York, 1979), pp. 97101.Google Scholar
[2] Spaepen, F. and Turnbull, D., Laser-Solid Interactions and Laser Processing – 1978, edited by Ferris, S.D., Leamy, H.J. and Poate, J.M. (AIP Conf. Proc. No. 5D, New York, 1979) [1], pp. 7383.Google Scholar
[3] Baeri, P., Foti, G., Poate, J.M. and Cullis, A.G., Phys. Rev. Lett. 45, 2036 (1980) and in Laser and Electron-Beam Solid Interactions and Materials Processine, edited by J.F. Gibbons, L.D. Hess and T.W. Sigmon (MRS Symp. Proc. 1, North Holland, New York, 1981) pp. 39–44.Google Scholar
[4] Kokorowski, S.A., Olson, G.L., Roth, J.A. and Hess, L.D., Phys. Rev. Lett. 48, 498 (1982) and in Laser and Electron-Beam Interactions with Solids, edited by B.R. Appleton and C.K. Celler (MRS Symp. Proc. 4. North-Holland, New York, 1982), pp.195–202.CrossRefGoogle Scholar
[5] Thompson, M.O., Galvin, G.J., Mayer, J.W., Peercy, P.S., Poate, J.M., Jacobson, D.C., Cullis, A.G. and Chew, N.G., Phys. Rev. Lett. 52, 2360 (1984).Google Scholar
[6] Olson, G.L., Kokorowski, S.A., Roth, J.A. and Hess, L.D. in Laser-Solid Interactions and Transient Thermal Processing of Materials, edited by Narayan, J., Brown, W.L. and Lemons, R.A. (MRS Symp. Proc. 13, North-Holland, New York, 1983), pp. 141154.Google Scholar
[7] Olson, G.L., Roth, J.A., Nygren, E., Pogany, A.P. and Williams, J.S. in Beam-Solid Interactions and Transient Processes. edited by Thompson, M.O., Picraux, S.T. and Williams, J.S. (MRS Symp. Proc. 74, MRS, Pittsburgh, Pennsylvania, 1987), pp. 109115.Google Scholar
[8] Donovan, E.P., Spaepen, F., Turnbull, D., Poate, J.M. and Jacobson, D.C., J. Appl. Phys. 57, 1795 (1985).CrossRefGoogle Scholar
[9] Beeman, D., Tsu, R. and Thorpe, M.F., Phys. Rev. D 32, 874 (1985).Google Scholar
[10] Tsu, R., Gonzalez-Hemandez, J. and Pollak, F.H., J. Non-Cryst. Sol., 66 109 (1984) and Solid State Commun. 54, 447 (1985).CrossRefGoogle Scholar
[11] Sinke, W., Warabisako, T., Miyao, M., Tokuyama, T., Roorda, S. and Saris, F.W., (a) to be published in the Proc. of the E-MRS Meeting, Strasbourg, 1987 and (b) to be published in the J. Non-Cryst. Sol..Google Scholar
[12] Tsu, R., Gonzalez-Hernandez, J., Doehler, J. and Ovshinski, S.R., Solid State Commun. 46, 79 (1983).Google Scholar
[13] Ishii, N., Kumeda, M. and Shimizu, T., Solid State Commun. 50, 367 (1984).Google Scholar
[14] Wong, C.K. and Lucovski, G. in Materials Issues in Amorohous-Semiconductor Technology, edited by Adler, D., Hamakawa, Y. and Madan, A. (MRS Symp. Proc. 70, MRS, Pittsburg, Pennsylvania, 1986), p. 7782.Google Scholar
[15] Okada, T., Iwaki, T., Kasahara, H. and Yamamoto, K., Jpn. J. Appl. Phys. 24, 161 (1985).Google Scholar
[16] Saito, T., Karasawa, T. and Ohdomari, I., J. Non-Cryst. Sol. 50, 271 (1982).Google Scholar
[17] The expression for ΔΘ2 vs. Λ/2 (formula 1) and that for UΘ vs. Δb (formula 2) used in this paper differ from those given by Tsu et al. [10]. These differences are due to an uncertainty in the relation between the Raman spectrum and the degree of disorder in a-Si and to different estimates of the elastic constant f3W. e feel that the expressions used here yield more realistic values of the strain energy than the expressions in [10].Google Scholar
[18] Smith, J.E. Jr, Brodsky, M.H., Crowder, B.L. and Nathan, M.I., J. Non-Cryst. Sol. 8–10, 179 (1972).Google Scholar
[19] Wautelet, M., Quenon, P. and Jadin, A., to be published in Semicond. Sci. Technol. (1987).Google Scholar