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Transport of Toluene in Microporous Vycor Class

Published online by Cambridge University Press:  28 February 2011

Ben Abeles ,
L. F. Chen ,
J. W. Johnson  and
J. M. Drake
Ben Abeles
Affiliation:
Exxon Research and Engineering Co., Route 22 East, Annandale, NJ 08801
L. F. Chen
Affiliation:
Exxon Research and Engineering Co., Route 22 East, Annandale, NJ 08801
J. W. Johnson
Affiliation:
Exxon Research and Engineering Co., Route 22 East, Annandale, NJ 08801
J. M. Drake
Affiliation:
Exxon Research and Engineering Co., Route 22 East, Annandale, NJ 08801
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Abstract

A quasi-equilibrium model is developed for capillary condensation flow, in which surfacediffusion is included. The model is in excellent agreement with the experimental data for the flow of toluene in untreated Vycor glass and in Vycor glass whose pores were derivatized with C18H38. The observed increase in viscosity with decreasing pore size is ascribed to a stagnant monolayer adsorbed to the pore walls. The surface diffusion coefficient at 22ºC is 5 x 10-5 cm2/secfor both the derivatized and untreated samples.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 195: Symposium S – Physical Phenomena in Granular Materials , 1990 , 491
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Tamon, H., Okazaki, M. and Toei, R., AIChE Journal 21, 271 (1981).Google Scholar
2. Krisher, O., Die Wissenshaftliche Grundlagen Der Troknungstechnik Springer, Berlin (1963).Google Scholar
3. Asaeda, M., Du, L.D. and Ushijima, M., Proc. of 4th Int. Drying Sympo., 712 (1984).Google Scholar
4. Asaeda, M., Du, L.D., J. Chem. Eng., Jap. 19, 72 (1986).Google Scholar
5. Adamson, A.W., Physical Chemistry of Surfaces, John Wiley (1982).Google Scholar
6. Leenaars, A.F.M. and Burggraaf, A.J., J. Membrane Science 24, 145 (1985).Google Scholar
7. Keizer, K., Uhlhorn, R.J.R., Vuren, R.J. Van and Burggraaf, A.J., J. Membrane Science 39, 285 (1988).Google Scholar
8. Debye, P., Cleland, R.L., J. of App. Phys. 30, 843 (1959).Google Scholar